Approximately 982 km3 /annum of the world’s groundwater reserve is abstracted, providing almost half of all drinking water worldwide. Globally, 70% is used for agricultural purposes while 38% for irrigation.
Most water resources of South Africa are threatened by contamination caused by industrial, agricultural, and commercial activities, and many parts of the country face ongoing drought with an urgent need to find alternative freshwater sources, such as groundwater. Groundwater constitutes approximately 15% of the total volume consumed, hence it is an important resource that supplements insufficient surface water supplies across South Africa.
Very little attention has been afforded to understanding the anthropogenically altered vadose zone as a potential source or buffer to groundwater contamination. This is evident from few research studies that has applied multiple isotopic tracers to characterise this zone. Most subsurface systems in South Africa are characterised by fractures, whereby flow and transport are concentrated along preferential flow paths.
This study aims to evaluate the performance of different tracer classes (environmental and artificial) with one another, and create a better understanding of the hydraulic properties, mean residence time and transport mechanisms of these tracers. The influence of unsaturated zone thickness on recharge mechanisms will also be evaluated.
Site visits will be conducted for the proposed study areas, and the neighbouring sources of contamination will be assessed. The matric potential and unsaturated hydraulic conductivities will be measured using various techniques. Water samples will be collected and analysed for the various tracers from the vadose zone using gravity lysimeters including suction cups. Several tracers will also be injected into boreholes where samples will be collected to calculate tracer residence times (BTC’s) and further constrain the hydraulic properties of the vadose zone. All samples will be analysed, interpreted, and simulated using the numerical finite-element modelling code SPRING, developed by delta h. The software derives quantitative results for groundwater flow and transport problems in the saturated and unsaturated zones of an aquifer.
The research is expected to provide more insight into the selection and use of environmental and artificial tracers as markers for detecting, understanding the transport processes and pathways of contaminants in typical altered South African subsurface environments. The impact derived improved characterisation of the pathways, transport, and migration processes of contaminants, leading to groundwater protection strategies and appropriate conceptual and numerical models. The output from this study will determine the vertical and horizontal flux for both saturated and unsaturated conditions.