Conference Abstracts

Abstract

The generation of acid mine drainage (AMD), as a result of mining activities, has led to the degradation of groundwater quality in many parts of the world. Coal mining, in particular, contributes to the production of AMD to a large extent in South Africa. Although a vast number of remediation methods exist to reduce the impacts of AMD on groundwater quality, the use of a coal fly ash monolith to act as a reactive and hydraulic barrier has not been extensively explored. This study, therefore, aims to investigate how different ways of packing ash affect the hydraulic conductivity of ash and influence leachate quality when acid-mine drainage filters through the ash. Coal ash is highly alkaline due to the existence of free lime on the surface of the ash particles. Previous studies that investigated alternative uses of coal ash, particularly in AMD treatment, suggest that coal ash has the potential to neutralise pH in acid water and remediate acidic soils. To test the effects of different packing methods of coal ash on the hydraulic conductivity and quality of acid mine leachate flowing through it, several Darcy column tests will be conducted. During the course of these experiments, the following parameters will be measured, electrical conductivity, pH discharge, lime (CaCO3) and selected elements of environmental concern.

Abstract

LNAPL present in a monitoring well forms part of the broader groundwater system and is effectively influenced by hydrogeological conditions, which are always changing. Monitoring of LNAPL is therefore of utmost importance to identify and assess the LNAPL hydrogeological conditions. Both groundwater and LNAPL can exist as unconfined and confined. Groundwater is unconfined when the upper boundary is the water table and is confined as a result of the presence of a confining layer with a relatively low vertical hydraulic conductivity that inhibits the flow of all liquids. LNAPL becomes unconfined when the apparent free product thickness increases with a decreasing groundwater elevation and confined when apparent free product thickness increases with an increasing groundwater elevation. The LNAPL is confined as a result of the difference between the capillary properties of the mobile LNAPL zone and its confining layer. Specifically, LNAPL is confined when it cannot overcome the pore entry pressure of the confining unit. Consequently, LNAPL may be confined when groundwater is not. The paper attempts to describe the hydrogeological conditions in case histories of both primary and fractured aquifers and illustrate how to identify and assess the conditions. Data such as free phase and groundwater level monitoring, well logs, sieving of soil and LNAPL bail tests are used as assessment tools. The additional required data is gathered and integrated in the conceptual site model, followed by a revision of the CSM and a refinement of decision goals over time. Thus the CSM matures and enables an improved understanding of the site characteristics and the re-adjustment of decision criteria. {List only- not presented}

Abstract

The SADC Grey Data archive http://www.bgs.ac.uk/sadc/ provides a chronology of groundwater development within the constituent countries of the SADC region. Early reports show how groundwater development progressed from obtaining water by well digging to the mechanical drilling of boreholes for provision of water for irrigation, township development, transport networks and rural settlement. During the 1930s steam driven drilling rigs were supplanted by petrol engine driven cable tool percussion drilling. Dixey (1931), in his manual on how to develop groundwater resources based on experiences in colonial geological surveys in eastern and southern Africa, describes aquifer properties, groundwater occurrence and resources as well as water quality and groundwater abstraction methods. Frommurze (1937) provides an initial assessment of aquifer properties in South Africa with Bond (1945) describing their groundwater chemistry. South African engineers transferred geophysical surveying skills to the desert campaign during World War II. Paver (1945) described the application of these methods to various geological environments in South Africa, Rhodesia and British colonial territories in eastern and central Africa. Test pumping methods using electric dippers were also developed for the assessment of groundwater resources. Enslin and others developed DC resistivity meters, replacing early Meggar systems, produced data that when analysed, using slide rules with graphs plotted by hand, identified water bearing fractures and deeply weathered zones. Tentative maps were drawn using interpretation of aerial photographs and heights generated using aneroid altimeters. The problems faced by hydrogeologists remain the same today as they were then, even though the technology has greatly improved in the computer era. Modern techniques range from a variety of geophysical surveying methods, automated rest level recorders with data loggers to GPS location systems and a whole host of remotely sensed data gathering methods. Worryingly, using such automated procedures reduces the ability of hydrogeologists to understand data limitations. The available collection of water level time series data are surprisingly small. Surrogate data need to be recognised and used to indicate effects of over abstraction as demand grows. As the numbers of boreholes drilled per year increases the number of detailed hydrogeological surveys undertaken still remains seriously small. Has our knowledge of hydrogeological systems advanced all that much from what was known in the 1980s? Case histories from Malawi, Zimbabwe and Tanzania illustrate a need for groundwater research with well-judged sustainability assessments to underpin safe long-term groundwater supply for the groundwater dependent communities in the region.

Abstract

The Table Mountain Group (TMG) Formation in the Uitenhage region, in the Eastern Province of South Africa, has many groundwater users, which could result in the over-exploitation of the underlying aquifer. Consequently, several investigations have been conducted to help in the planning and management of groundwater resources within the region. Traditionally, these investigations have considered groundwater and surface water as separate entities, and have been investigated separately. Environmental isotopes, hydrochemistry and feacal colifom bacteria techniques have proved to be useful in the formulation of interrelationships and for the understanding of groundwater and surface water interaction. The field survey and sampling of the springs, Swartkops River and the surrounding boreholes in the Uitenhage area have been conducted. After full analysis of the study, it is anticipated that the data from the spring, Swartkops River and the surrounding boreholes show interannual variation in the isotope values, indicating large variation in the degree of mixing, as well as to determine the origin and circulation time of different water bodies. ?D and ?18O value for the spring ranges from ?18.9? to ?7.4?, and 5.25? to 4.82?, respectively, while ?D values for borehole samples range from ?23.5? to ?20.0? and ?18O values range from ?5.67? to ?5.06?. In the river sample, ?D values ranges from ?12.1? to ?4.2?, ?18O from ?3.7? to ?1.13?, respectively. The entrobacter aerogen and E.Coli bacteria were detected in the samples. E. coli population for spring and the artesian boreholes indicated low value while the shallow boreholes had higher values are relatively closer to those of the middle ridges of the Swartkops River. The EC values for the spring samples averages at 14 mS/m, borehole samples ranges from 21 mS/m to 1402 mS/m, and surface water ranges from 19 mS/m to 195 mS/m. Swartkops River is an ephemeral, therefore it is expected that diffuse recharge occurs into the shallow aquifer.

Abstract

Groundwater in South Africa is the most important source of potable water for rural communities, farms and towns. Supplying sufficient water to communities in South Africa becomes a difficult task. This is especially true in the semi-arid and arid central regions of South Africa where surface water resources are limited or absent and the communities are only depended on groundwater resources. Due to a growing population, surface water resources are almost entirely being exploited to their limits. These factors, therefore, increases the demand for groundwater resources and a more efficient management plan for water usage. For these reasons, the relation between the geology and geohydrology of South Africa becomes an important tool in locating groundwater resources that can provide sustainable quantities of water for South Africans. It was therefore decided to compile a document that provides valuable geohydrological information on the geological formations of the whole of South Africa. The information was gathered by means of interviews with experienced South African geohydrologists and reviewing of reports and articles of geohydrological studies. After gathering the relevant information, each major geological unit of South Africa together with its geohydrological characteristics was discussed separately. These characteristics include rock/aquifer parameters and behaviour, aquifer types (primary of secondary), groundwater quality, borehole yields and expected striking depths, and geological target features and the geophysical method used to locate these targets. Due to the fact that 90 % of South Africa's aquifers are classified as secondary aquifer systems, groundwater occurrence within the rocks of South Africa is mainly controlled by secondary fractures systems; therefore, understanding the geology and geological processes (faulting, folding, intrusive dyke/sills & weathering) responsible for their development and how they relate is important. However, the primary aquifers of South Africa (Coastal Cenozoic Deposits) should not be neglected as these aquifers can produce significant amounts of groundwater, such as the aquifer units of the Sandveld Group, Western Cape Province. Drilling success rates and possibility of striking higher yielding boreholes can be improved dramatically when an evaluation of the structural geology and geohydrological conditions of an area together with a suitable geophysical method is applied. The ability to locate groundwater has been originally considered (even today) a heavenly gift and can be dated back to the Biblical story of Moses striking the rock to get water: "behold, I will stand there before thee there upon the rocks thou shalt smite the rock and there shall come water out of it" (Exodus 17:6).

Abstract

Globally, a growing concern have been that the heavy metal contents of soil are increasing as the result of industrial, mining, agricultural and domestic activities. While certain heavy metals are essential for plant growth as micronutrients, it may become toxic at higher concentrations. Additionally, as the toxic metals load of the soil increases, the risk of non-localized pollution due to the metals leaching into groundwater increases. The total soil metal content alone is not a good measure of risk, and thus not a very useful tool to determine potential risks to soil and water contamination. The tendency of a contaminant to seep into the groundwater is determined by its solubility and by the ratio between the concentration of the contaminant sorbed by the soil and the concentration remaining in solution. This ratio is commonly known as the soil partitioning or distribution coefficient (Kd). A higher Kd value indicate stronger attraction to the soil solids and lower susceptibility to leaching. Studies indicate that the Kd for a given constituent may vary widely depending on the nature of the soil in which the constituent occurs. The Kd of a soil represents the net effect of several soil sorption processes acting upon the contaminant under a certain set of conditions. Soil properties such as the pH, clay content, organic carbon content and the amount of Mn and Fe oxides, have an immense influence on the Kd value of a soil. Kds for Cu, Pb and V for various typical South African soil horizons were calculated from sorption graphs. In most cases there were contrasting Kd values especially when the cations, Cu and Pb, had high contamination levels, the value for V was low. There is large variation between the Kds stipulated in the Framework for the Management of Contaminated land (as drafted by the Department of Environmental Affairs) and the values obtained experimentally in this study. The results further indicate that a single Kd for an element/metal cannot be used for all soil types/horizons due to the effect of soil properties on the Kd. The results for Cu and Pb indicated that the Kds can range in the order of 10 to 10 000 L/kg for Cu and 10 to 100 000 L/kg for Pb. The variation in V Kd was not as extensive ranging from approximately 10 to 1 000 L/kg. {List only- not presented}

Abstract

Groundwater monitoring, especially from the end users' point of view, is often considered an add-on, or even unnecessary overhead cost to developing a borehole. Simply measuring groundwater level over time can however tell a story on seasonal rainfall fluctuations as well as the response of an aquifer to the removal of an abstracted volume of water. In this case an artesian borehole of high yield and exceptional quality was drilled in an area of minimal groundwater use because of known poor quality and low yields. The borehole was drilled in two stages with the deeper drilling resulting in significantly higher yields and the artesian flow. Sediment free water, deep artesian water strikes and a lack of flow around the casing led to the conclusion that capping at surface would control the visible artesian flow of 4 L/s. A slight drop in pressure indicated that subsurface leakage may however be occurring. Neighbouring boreholes with automated water level monitoring provided data showing a correlation of drop in water level to the second deeper drilling event. The artesian borehole was yield tested and this too was visible in the water level monitoring data. Hereafter it became apparent that each activity performed at the artesian borehole had an impact on the monitoring boreholes, and that a subsurface leak was causing local depressurization of a semi-confined to confined aquifer. An initial attempt to save the artesian borehole was unsuccessful, resulting in the necessary blocking and abandonment of a high yielding, superior quality borehole. If monitoring data was not available the local drop in water level would never have been noticed with disastrous effect and no evidence for the cause. Simple water level monitoring has averted this and kept neighbourly relations and ground water levels intact

Abstract

POSTER About 97% of the earth's freshwater fraction is groundwater, excluding the amount locked in ice caps (Turton et al 2007) and is often the only source of water in arid and semi-arid regions and plays a critical role in agriculture, this dependency results in over-exploitation, depletion and pollution (Turton et al 2007). Groundwater governance helps prevent these issues. CSIR defines governance as the process of informed decision making that enables trade between competing users of a given resource, as to balance protection and use in such a way as to mitigate conflicts, enhance security, ensure sustainability and hold government officials accountable for their actions (Turton et al 2007). Realising the issues of groundwater governance is a requirement for developing policy recommendations for both national and trans-boundary groundwater governance. Groundwater level decline has led to depletion in storage in both confined and unconfined aquifer systems (Theesfeld 2010). There are about six institutional aspects, namely voluntary compliance, traditional and mental models, administrative responsibility and bureaucratic inertia, conflict resolution mechanisms, political economy and information deficits (Theesfeld 2010). Each of these aspects represents institutional challenges for national and international policy implementation. Traditional local practices should not be disregarded when new management schemes or technological innovations are implemented. The types of policies that impact governance include regulatory instruments, economic instruments and voluntary/advisory instruments. Regulatory or command and control policy instruments such as ownership and property right assignments and regulations for water use are compulsory. Economic policy instruments make use of financial reasons such as groundwater pricing, trading water right or pollution permits, subsidies and taxes. Voluntary /advisory policy instruments are those that influence voluntary actions or behavioural change without agreement or direct financial incentives. These are ideal types though no policy option ever relies purely on one type of instrument. The aim of these policies is to have an impact on governance structures (Theesfeld 2010). The national water act (1998) of the Republic of South Africa is not widely recognized as the most comprehensive water law in the world even though it is the highlight of socio-political events; socially it is still recent in most sites although the law was implemented 15 years ago (Schreiner and Koppen 2002). Regulations for use include quantity limitations, drilling permits and licensing, use licenses, special zone of conservation and reporting and registering requirement. In general when drilling and well construction are done commercially they increasingly fall under the scope of regulatory legislation. This paper will focus mostly on traditional and mental models; procedures that a certain community is dependent on should be taken into account before replacing with technological advanced tools. Consultation of the public can cause conflicts which lead to poor groundwater management.

Keywords: Groundwater governance, policy, policy instruments.

Abstract

A large number of groundwater investigations have been carried out in the Western Cape over the last decade or so. Most of them were related to water supply options for individuals, agriculture, businesses, industries, government departments and municipalities. Some of these developments have confirmed what we already knew about the groundwater characteristics and aquifers of the Western Cape, while others provided us with surprises - surprises so significant that we may have to re-write what we thought we knew. This paper will not be able to cover all the interventions and groundwater studies that have been done. Two case studies linked to the major geological structure in the Western Cape, namely the Colenso Fault (also known as the Franschhoek-Saldanha Fault), will therefore be used as an illustration of the lessons that were learnt by comparing them with our historical understanding of the associated groundwater characteristics. It will also show that there is a need for updated groundwater maps on smaller scale and a reassessment of the aquifers status.

Abstract

POSTER As the National Water Act has evolved to provide for more effective and sustainable management of our water resources, there has been a shift in focus to more strategic management practices. With this shift come new difficulties relating to the presentation of sensitivity issues within a spatial context. To this end it is necessary to integrate existing significant spatial layers into one map that retains the context, enables simple interpretation and interrogation and facilitates decision making. This project shows the steps taken to map and identify key groundwater characteristics in the Karoo using Geographic Information Systems (GIS) techniques. Two types of GIS-based groundwater maps have been produced to assist with interpretation of existing data on Karoo Aquifer Systems in turn informing the management of groundwater risks within Shell's applications for shale gas exploration. Aquifer Attribute and Vulnerability maps were produced to assist in the decision making process. The former is an aquifer classification methodology developed by the project team, while the latter uses the well-known DRASTIC methodology. The overlay analysis tool of ESRI's ArcGIS 10.1 software was used, enabling the assessment and spatial integration of extensive volumes of data, without losing the original detail, and combining them into a single output. This process allows for optimal site selection of suitable exploration target areas. Weightings were applied to differentiate the relative importance of the input criteria. For the Attributes maps ten key attributes were agreed by the project team to be the most significant in contributing to groundwater/aquifer characteristics in the Karoo. This work culminated in the production of a series of GIS-based groundwater attributes maps to form the Karoo Groundwater Atlas which can be used to guide groundwater risk management for a number of purposes. The DRASTIC model uses seven key hydrogeological parameters to characterise the hydrogeological setting and evaluate aquifer vulnerability, defined as the tendency or likelihood for general contaminants to reach the watertable after introduction at ground surface.

Abstract

The main purpose of this paper is to present a case study where a water balance concept was applied to describe the expected groundwater safe yield on a sub-catchment scale. The balance considers effective recharge based on local hydrogeology and land cover types, basic human needs, groundwater contribution to baseflow, existing abstraction and evaporation. Data is derived from public datasets, including the WRC 90 Water Resources of South Africa 2012 Study, 2013-2014 South African (SA) National Land Cover and Groundwater Resource Assessment Ver. 2 (GRAII) datasets. The result is an attempt to guide a new groundwater user regarding the volume of groundwater that can be abstracted sustainably over the long-term.

Abstract

An understanding of the movement of moisture fluxes in the unsaturated zone of waste disposal sites play a critical role in terms of potential groundwater contamination. Increasing attention is being given to the unsaturated or vadose zone where much of the subsurface contamination originates, passes through, or can be eliminated before it contaminates surface and subsurface water resources. As the transport of contaminants is closely linked with the water ?ux in through the unsaturated zone, any quantitative analysis of contaminant transport must ?rst evaluate water ?uxes into and through the this region. Mathematical models have often been used as critical tools for the optimal quantification of site-speci?c subsurface water ?ow and solute transport processes so as to enable the implementation of management practices that minimize both surface and groundwater pollution. For instance, numerical models have been used in the simulation of water and solute movement in the subsurface for a variety of applications, including the characterization of unsaturated zone solute transport in waste disposal sites and landfills. In this study, HYDRUS 2D numerical simulation was used to simulate water and salt movement in the unsaturated zone at a dry coal ash disposal site in Mpumalanga, South Africa. The main objective of this work was to determine the flux dynamics within the unsaturated zone of the coal ash medium, so as to develop a conceptual model that explains solute transport through the unsaturated zone of the coal ash medium for a period of approximately 10 year intervals. Field experiments were carried out to determine the model input parameters and the initial conditions, through the determination of average moisture content, average bulk density and the saturated hydraulic conductivity of the medium. A two dimensional finite-element mesh of 100m x 45m model was used to represent cross section of the ash dump. Two dimensional time lapse models showing the migration of moisture fluxes and salt plumes were produced for the coal ash medium. An explanation on the variation of moisture content and cumulative fluxes in the ash dump was done with reference to preexisting ash dump data as well as the soil physical characteristics of the ash medium.
{List only- not presented}

Abstract

Vapour intrusion (VI) is the term used to define the encroachment of vapour phase contaminants from subsurface sources into structures such as buildings and basements. It is widely recognized that VI often forms the principal risk of exposure to receptors at petroleum release sites. Petroleum VI (PVI) generally occurs where a release of petroleum hydrocarbon product migrates from its source (e.g. from a leaking underground storage tank) to the groundwater table at which point, given favourable conditions, the hydrocarbon plume may migrate laterally beneath an adjacent building or structure. Subsequent volatilisation of the petroleum product results in the upward diffusion of vapours towards the surface where the vapours may enter into the building or structure at concentrations which may be harmful to human health. The subject of PVI with regards to its fate and transport mechanisms, as well as associated mitigation measures is rapidly gaining attention on a global scale, although to date this exposure pathway remains largely un-assessed in South Africa, with no regulatory guidance currently available. In the late 1990's and early 2000's focus was placed on the development of VI screening criteria by which sites could be screened with respect to their hydrogeological conditions and contamination status so as to determine whether VI could be a potential exposure pathway of concern, with much of the early work being completed by the United States Environmental Protection Agency. For the past decade the majority of the available screening criteria and guidance has had a partially incomplete understanding of hydrocarbon vapour fate and transport processes associated with VI, which has led to doubt over the application of such screening criteria in many cases. Furthermore, recent research conducted abroad has highlighted the importance of the role of oxygen in the vadose zone in the natural attenuation of petroleum hydrocarbon vapours as they diffuse through the soil profile. This research is pointing towards the notion that currently applied screening criteria may be overly conservative, leading to many unnecessary PVI investigations being conducted to the disruption of occupants of the buildings, and at great cost. Over the last two years ERM has compiled a dataset of PVI results from numerous investigations it has conducted throughout Southern Africa and in this paper the authors present data that supports the growing global trend towards recognizing the role that oxygen plays in attenuating petroleum hydrocarbon vapours in the vadose zone. The data also supports the notion that confirmed cases of PVI into buildings have generally been found to be the exception to the rule and not the norm.

Abstract

Water is integral to our economy, the health of our environment, and our survival as a species. Much of this water is accessed from surface sources, mostly rivers, which are now under increased threat due to over use and the resulting hydro-political forces. Yet, groundwater exists as a viable option in many countries facing these mounting challenges. Knowledge of our deeper groundwater systems, although increasing, is still quite limited due to our propensity to focus efforts in the lower cost, lower risk, near- surface environment. However, accessibility to shallower groundwater is tightening due to increasing use, changing regulatory requirements, and climate change.

The use of classical geophysics to explore for groundwater resources, such as seismic, gravity, magnetics, and resistivity, has been the industry standard for many decades. These technologies have proven quite effective both in the shallow and medium depth environments. However, newer remote sensing and ground-based technologies are now emerging with the ability to significantly reduce costs and time, and increase success for groundwater exploration and development programs. Quantum Direct Matter Indicator (QDMI) technologies, or applied methods of Quantum Geoelectrophysics (QGEP), are poised to enhance the hydrogeophysical industry, much like electro-magnetic (EM) and electrical resistivity tomography (ERT) did years ago. QDMI utilizes resonant frequency remote and direct sensing technologies that detect perturbations in the earth’s natural electric, magnetic and electromagnetic fields. Controlled source electromagnetic pulse methods with electromagnetic spectrum spectroscopy are used to identify aquifers, including thickness, water quality (fresh or saline) and temperature, to depths of 1000 m or more accurately. With multiple successes around the world, the deployment of this inventive and effective approach to groundwater exploration is poised to advance exploration geophysics globally.

Abstract

POSTER Aquifer stress arising from urbanization and agricultural activities, these two factors affect aquifer properties when prolonged. Increase in urbanization especially those situated on top unconfined or semi-confined aquifer results in pressure on natural resources, this includes water resources, and changes of land use for agricultural purposes with high economic benefits has an effect on groundwater quality to due to application of Nitrogen- fertilizers during crop rotation and this is largely experienced in developing countries. The effects ranges from groundwater quality to aquifer storage as prolonged aquifer withdrawals due to irrigation, construction, manufacturing affects groundwater storage. Assessment of urbanization and agricultural effects on groundwater requires a complex analysis as integration approaches needs to be discovered for a better analysis of the two more specially when assessing groundwater pollution. The study was conducted to assess the impacts of urbanization and agricultural activities on aquifer storage and groundwater quality: by (a) determining the relationship between the occurrence of contamination due to urbanization by assessing contaminants present in the study area (b) develop groundwater protection, and if any offer recommendation for groundwater management. Multiple-well tests were conducted observing the behavior of drawdown and recovery for assessing groundwater storage. Two aquifer properties were observed to yield information about any changes in aquifer storage (transmissivity and storage coefficient) and groundwater quality lab test focusing on TDS, nitrate and pH were conducted. Historical results reflect that before industrial and urban revolution the groundwater contained small amounts of TDS compared with the present results. Increase in nitrate and pH concentrations observed in location closer to agricultural areas. Prolonged aquifer withdrawals increases expansion of cone of depression and therefore increases aquifer vulnerability and the risk of aquifer being polluted, and this increases storage coefficient. This study can be used to formulate protection zones for water resources and practice towards groundwater management.

Abstract

Preventing the spread of seepage from tailings storage facilities (TSF's) in groundwater is necessary as it often contains toxic contaminants. Experience has shown that seepage from TSFs is inevitable and that zero seepage remains difficult even with complex liner systems. Multiple seepage control methods are often required to minimise seepage to ensure that environmental regulations are met. Control methods can be grouped into either barrier or collection systems. Barrier systems are used to hinder seepage whereas collection systems are used to intercept seepage. A blast curtain, which is the focus of this article, is a type of collection system that is still at a conceptual level but has seen little or no application worldwide. It works in principle, similarly to a curtain drain, but is typically extended to greater depths depending on the aquifer vulnerability. Numerical modeling has shown that this mitigation measure could add another line of defence for seepage control. The depth and effectiveness of the curtain can be optimized with a numerical model to ensure optimal interception of contaminated seepage around the TSF. Depths of up to 30 m in fractured aquifers have been simulated in this study. A blast curtain is constructed by drilling a set of boreholes around a TSF in close proximity to one another and then fracturing the rock using either explosives or fracking methods to create a more permeable zone. This is then combined with a series of scavenger wells or natural seepage to abstract the contaminated water. Numerical simulation has shown that blast curtains are effective especially if groundwater flow is horizontal. The effectiveness decreases if the vertical flow component is significant. A blast curtain can result in the lowering of the water table, however, local depression is a less of a concern than potential groundwater contamination. {List only- not presented}

Abstract

Globally, cumulative plastic production since 1950 is estimated to have reached 2500 Mt of plastic. It is estimated up 60% of this plastic is either resting in landfills or the natural environment, including groundwater settings. Microplastics are small pieces of plastic ranging between 1μm – 5mm in size and have been found in every ecosystem and environment on the planet. Much of the available literature on microplastics is focused on marine environments with few in comparison focused on freshwater environments, and even fewer on groundwater settings.

The aim of this study is therefore to investigate the attenuation process responsible for influencing microplastic transport in saturated sands. This research will adapt colloid transport theory and experiments to better understand the movement of microplastics through sandy media. Saturated aquifer conditions will be set up and simulated using modified Darcy column experiments adapted from Freeze & Cherry (1979). Modified microplastics will be injected into the columns as tracers and the effluent concentrations measured by Fourier-transform infrared spectroscopy (FTIR). Breakthrough curves will then be plotted using the effluent concentrations to determine the attachment efficiency (α). It is expected the attachment efficiency will vary by microplastic type and size range. The Ionic strength of the solution flowing through the column and the surface charges of both microplastics and sandy surfaces are likely to influence the degree of attenuation observed. The relationship between different types of microplastics and collector surfaces from a charge perspective and their influence on the degree of attenuation will be evaluated.

Given the lack of literature, its ubiquitous presence and postulated effects on human health, this research is significant. Through this research, the transport and attenuation of microplastics through sandy aquifers can be better understood, and in the process inform future research and water resource management.

Abstract

The groundwater quality of the Orange Water Management Area (OWMA) was assessed to determine the current groundwater status. Groundwater is of major importance in the Orange Basin and constitutes the only source of water over large areas. Groundwater in the OWMA is mainly used for domestic supply, stock watering, irrigation, and mining activities. Increase in mining and agricultural activities place a demand for the assessment of groundwater quality. The groundwater quality was assessed by collecting groundwater samples from farm boreholes, household boreholes, and mine boreholes. Physical parameters such as pH, temperature and Electrical Conductivity (EC) were measured in-situ using an Aquameter instrument. The groundwater chemistry of samples were analysed using Inductively Coupled Plasma Mass Spectrometry, Ion Chromatography, and Spectrophotometer for cations, anions and alkalinity respectively. The analyses were done at Council for Geoscience laboratory. The results obtained indicated high concentration of Nitrate (NO3), EC, sulphate (SO4), Iron (Fe), and dissolved metals (Chromium, Nickel, Copper, Zinc, and Lead). The concentrations were higher than the South African National Standards (SANS) 241 (2006) drinking water required guideline. The OWMA is characterised by the rocks of the Karoo Supergroup, Ventersdorp Supergroup, Transvaal Supergroup, Namaqua and Natal Metamorphic Province, Gariep Supergroup, and Kalahari Group. Groundwater is found in the sandstones of the Beaufort Group. Salt Mining occurs in the Namaqua Group, hence the high concentration of EC observed. High EC was also found in the Dwyka Group. The salt obtained from the pans underlain by the Dwyka Group rocks has relatively high sodium sulphate content, this probably results from oxidation of iron sulphate to sulphate. Therefore, high concentration of SO4 is due to the geology of the area. High concentration of NO3 is due to agricultural activities, whereas high concentration of EC, Fe, SO4 and dissolved metals is due to mining activities.

Abstract

This study explores some of the principle issues associated with quantifying surface and groundwater interactions and the practical application of models in a data scarce region such as South Africa. The linkages between the various interdependent components of the water cycle are not well understood, especially in those regions that suffer problems of data scarcity and there remain urgent requirements for regional water resource assessments. Hydrology (both surface and groundwater hydrology) is a difficult science; it aims to represent highly variable and non-stationary processes which occur in catchment systems, many of which are unable to be measured at the scales of interest (Beven, 2012). The conceptual representations of these processes are translated into mathematical form in a model. Different process interpretations together with different mathematical representations results in the development of diverse model structures. These structural uncertainties are difficult to resolve due to the lack of relevant data. Further uncertainty is introduced when parameterising a model, as the more complex the model, the greater the possibility that many different parameter sets within the model structure might give equally acceptable results when compared with observations. Incomplete and often flawed input data are then used to drive the models and generate quantitative information. Approximate implementations (model structures and parameter sets), driven by approximate input data will necessarily produce approximate results. Most model developers aim to represent reality as far as possible, and as our understanding of hydrological processes has improved, models have tended to become more complex. Beven (2002) highlighted the need for a better philosophy toward modelling than just a more explicit representation of reality and argues that the true level of uncertainty in model predictions is not widely appreciated. Model testing has limited power as it is difficult to differentiate between the uncertainties within different model structures, different sets of alternative parameter values and in the input data used to run a model. A number of South African case studies are used to examine the types of data typically available and explore the extent to which a model is able to be validated considering the difficulty in differentiating between the various sources of uncertainty. While it is difficult to separate input data, parameter and structural uncertainty, the study found that it should be possible to at least partly identify the uncertainty by a careful examination of the evidence for specific processes compared with the conceptual structure of a specific model. While the lack of appropriate data means there will always be considerable uncertainty surrounding model validation, it can be argued that improved process understanding in an environment can be used to validate model outcomes to a degree, by assessing whether a model is getting the right results for the right reasons.

Abstract

The advent of the 'Big Data' age has fast tracked advances in automated data analytics, with significant breakthroughs in the application of artificial intelligence (AI). Machine learning (ML), a branch of AI, brings together statistics and computer science, enabling computers to learn how to complete given tasks without the need for explicit programming. ML algorithms learn to recognize and describe complex patterns and relationships in data - making them useful tools for prediction and data-driven discovery. The fields of environmental sciences, water resources and geosciences have seen a proliferation of the use of AI and ML techniques. Yet, despite practical and commercial successes, ML remains a niche field with many under-explored research opportunities in the hydrogeological sciences. Currently physical-process based models are widely applied for groundwater research and management, being the dominant tool for describing and understanding processes governing groundwater flow and transport. However, they are limited in terms of the high data requirements, costly development and run time. By comparison, ML algorithms are data-driven models that establish relationships between an input (e.g. climate data) and an output (e.g. groundwater level) without the need to understand the underlying physical process, making them most suitable for cases in which data is plentiful but the underlying processes are poorly understood. Combining data-driven and process-based models can provide opportunities to compensate for the limitations of each of these methodologies. We present applications of ML algorithms as knowledge discovery tools and explore the potential and limitations of ML to fill in data gaps and forecast groundwater levels based on climate data and predictions. Results represent the first step in on-going work applying ML as an additional tool in the study and management of groundwater resources, alongside and enhancing conventional techniques such as numerical modelling.

Abstract

The hydrogeological setting of a proposed mine site can significantly influence the viability of the mining venture. The management of groundwater inflows, costs of the dewatering technology, construction and maintenance of storage facilities, discharge strategies and anticipated environmental impacts are vital factors for consideration. It is fundamental to assess the hydrogeological setting at an early stage of the mine life cycle and should involve the collection of sufficient hydrogeological data, conceptualisation of the hydrogeological setting and an assessment of planned mine operations and anticipated impacts. Ambient hydrogeological conditions at the deposit area may be identified by conducting a hydrocensus and utilising existing ore exploration drilling data. Information from the hydrocensus and ore exploration drilling can provide valuable preliminary data on groundwater risks, dewatering and available groundwater resources. Potential groundwater/surface water interactions and receptors sensitive to environmental impacts can be identified during a hydrocensus. Similarly, water strikes and fracture density recorded during exploration drilling provide valuable insight to the subterranean environment. It is also possible to obtain aquifer hydraulic properties through packer testing of exploration boreholes. Geochemical test work on exploration borehole-cores could provide valuable information regarding contamination risks from ore deposit and waste material storage. The installation of piezometers within available and accessible exploration holes that extend below the regional groundwater level can pioneer the collection of monitoring data crucial for consideration during the mine life cycle and provide an understanding of the interaction between hydrogeological units and recharge characteristics. Ultimately, mine operations and associated potential impacts on the surrounding groundwater environment can be simulated with the application of numerical hydrogeological flow and contaminant transport models. The numerical models can simulate the regional groundwater flow system and complexities of the mine environment, the accuracy of which is influenced by the type, spatial and temporal distribution of the data collected. It is accordingly suggested that the collection of hydrogeological data and information during the exploration phase would facilitate the timely conceptualisation of potential groundwater risks and effective planning of hydrogeological investigations required during upcoming phases while assisting in the budget optimisation of these future studies.

Abstract

It has become increasingly apparent that understanding fractured rock mechanics as well as the interactions and exchanges between groundwater and surface water systems are crucial considering the increase in demand of each in recent years. Especially in a time where long term sustainability is of great importance for many water management agencies, groundwater professionals and the average water users. Previous callow experience has shown that there is a misunderstanding in the correct interpretation and analyses of pumping test data. The fracture characterisation (FC) method software provides a most useful tool in the overall understanding of a fractured rock aquifer, quantification of the aquifer’s hydraulic (flow regime and flow boundary conditions) and physical properties, only if the time-drawdown relationships are correctly interpreted and when the theoretical application principles are applied. Interpretation is not simply a copy and paste of the aquifer test data into the software to get a quick answer (especially when project time constraints are considered), however, recent experiences with numerous field examples, required intricate understanding of the geological environment, intended use and abstraction schedules coupled with the academic applications on which the software was based for correct interpretation.

Through the application of correct interpretation principles, a plethora of flow information becomes available, of which examples will be provided in the presentation itself. By achieving this, flow can be conceptualised for inputs into a conservative scale three-dimensional numerical flow model and calibrated based on measurable data in a fraction of the time of a conventional regional model. Although higher confidence levels are achieved with these practical solutions, monitoring programmes are still required to provide better insight of the aquifer responses to long-term abstraction and recovery.

Abstract

Water management is a difficult and complex business requiring appropriate institutional arrangements as well as guidance and support from government, which is often unable to act effectively to address day-to-day water resource management (WRM) issues. Theoretically, water as a 'common pool resource' is best managed by users self-organised at a local level and within a basin framework. Water users and other stakeholders have detailed and up-to-date local knowledge as well as an interest in ensuring effective management to share water equitably between different users and to control pollution. This approach is supported by South Africa's National Water Act (NWA), which provides for the establishment of Catchment Management Agencies (CMAs) to perform a range of WRM activities within the framework of a National Water Resource Strategy (NWRS).
Hence, water resource management in general and conjunctive use in particular requires cross sector and cross level cooperative governance. Relevant institutions include the DWA at national and regional level, the CMA, if established, provincial departments that might impact on the water resources, water user associations, water services authorities, water services providers, water boards, and individual water users. These institutions are responsible for various activities and often require some level of inter- and intra-institutional cooperation. Ideally, multiple organisations, policies, legislation, plans, strategies and perspectives should be involved in water-related decision-making, which in turns creates complex leadership challenges. Globally, the lack of sustainable groundwater management can be ascribed to poor governance provisions. These include, but are not limited to, institutional arrangements and political will, including fragmented and overlapping jurisdictions and responsibilities, competing priorities, traditional approaches, rights and water pricing systems, diverging opinions, incomplete knowledge, data as well as uncoordinated information systems. Adding the poor operational and maintenance issues, decision-makers often view groundwater as an unreliable resource and are hesitant to make significant investments in groundwater infrastructure and capacity.
The recent Worldbank and WRC report on groundwater governance in South Africa revealed that the technical, legal, institutional and operational governance provisions were found to be reasonable at the national level but weak concerning cross-sector policy coordination. At the local level, basic technical provisions such as hydrogeological maps and aquifer delineation with classified typology are in place but other governance provisions such as institutional capacity, provisions to control groundwater abstraction and pollution, cross-sector policy coordination and the existence and implementation of groundwater management action plans are weak or non-existent.
It appears from this review that the major hindrances for sustainable groundwater governance and more so for integrated water resource management and conjunctive use scenarios are the discrepancy between groundwater and surface water provisions in the relevant legislation, associated guidelines and their implementation at regional and local, and the lack of skills and clear responsibilities for implementing water resource management actions at municipal level. This is demonstrated with several case studies.

Abstract

Mt. Fuji is the iconic centrepiece of a large, tectonically active volcanic watershed (100 km2 ), which plays a vital role in supplying safe drinking water to millions of people through groundwater and numerous freshwater springs. Situated at the top of the sole known continental triple-trench junction, the Fuji watershed experiences significant tectonic instability and pictures complex geology. Recently, the conventional understanding of Mt. Fuji catchment being conceptually simple, laminar groundwater flow system with three isolated aquifers was challenged: the combined use of noble gases, vanadium, and microbial eDNA as measured in different waters around Fuji revealed the presence of substantial deep groundwater water upwelling along Japan’s tectonically most active fault system, the Fujikawa Kako Fault Zone [1]. These findings call for even deeper investigations of the hydrogeology and the mixing dynamics within large-scale volcanic watersheds, typically characterized by complex geologies and extensive networks of fractures and faults. In our current study, we approach these questions by integrating existing and emerging methodologies, such as continuous, high-resolution monitoring of dissolved gases (GE-MIMS [2]) and microbes [3], eDNA, trace elements, and integrated 3-D hydrogeological modelling [4]. The collected tracer time series and hydraulic and seismic observations are used to develop an integrated SW-GW flow model of the Mt. Fuji watershed. Climate change projections will further inform predictive modelling and facilitate the design of resilient and sustainable water resource management strategies in tectonically active volcanic regions

Abstract

Decades of monitoring, characterising, and assessing nitrate concentration distribution and behaviour in the soil profile and it's pathway into groundwater have resulted in a good understanding of its distribution in the country. While the national distribution is of great importance, site specific conditions determine fate, transport, and ultimately concentration in a specific area. Field experimental work included installation of a barrier containing a cheaply available carbon source to treat groundwater. The "reactor"/ tank with dimensions- 1,37m height, 2.15m diameter used for the experiment was slotted for its entire circumference by marking and grinding through the 5mm thick plastic material. The top section was left open to allow for filling and occasional checking of filled material during the experiment. The tank was packed with Eucalyptus globulus woodchips which was freely available at the site. Concentrations of groundwater nitrate at the site were well over what could be expected in any naturally occurring groundwater systems, and would result only by major anthropogenic activities in unconfined aquifer areas of South Africa. The changes in parameter concentrations with time were measured in order to determine the efficiency and life span of the carbon source used for the experiment. This paper considers 35 months of monitoring at a site where a low technology method was implemented. Field implementation was tested at a site which previously experienced some NH4NO3 spills. Main results from the field work showed that nitrate was totally removed at the treatment zone and surrounding boreholes, and even sulphate and NH4+ were removed during the experiment. This shows that the woodchips were successful in affecting denitrification for 35 months. Data also shows that boreholes further downstream from the tank had reduced NO3-, SO42- and NH4+ levels. Using the available biodegradable carbon for the woodchips based on its composition, a barrier lifespan could be determined. The results of calculations showed that the barrier would be effective for at least another 6.9 years from the period of the last sampling date. A total lifespan of about 10 years can thus be estimated.

Abstract

Water monitoring is a key aspect in the mining industry, in terms of gathering baseline data during the pre-construction stage, identifying potential areas of concern and mitigating source pollutants during the operational stage. A proper water monitoring program assists in the monitoring of plume development and water level rebound during the closure phase. The data made available through consistent long term monitoring should not be underestimated. Monitoring the effect that coal mine operations have on the water quality and quantity of surface and groundwater resources is a complex and multidisciplinary task. Numerous methodologies exist for monitoring of this kind. This paper will supply an overview of the water- rock chemistry associated with coal mine environments and the key indicator elements that should be focused on for water monitoring as well a review of the Best Practice Guidelines requirements in terms of water monitoring. Two case studies of coal mines in KwaZulu Natal will be reviewed, the key challenges outlined and mitigation measures implemented. The impact of requirements such as those set out by the Department of Water and Sanitation in terms of strict water quality limits for water containment and waste facilities as specified by Water Use Licences has also created unrealistic non-compliance conditions. The initial approach to creating a water monitoring programme should involve first identifying gaps in previous datasets and delineating potential sources of contamination. The sampling frequency will depend primarily on the water resource being monitored and the water quality analysis will depend on the type of facility. The facilities required for a specific situation will depend on the type and amount of waste generated, potential for leachate formation, vulnerability of groundwater resources and potential for water usage or resource sensitivity.

Abstract

A coal mine in South Africa had reached decant levels after mine flooding, where suspected mine water was discharging on the ground surface. Initial investigations had indicted a low-risk of decant, but when ash-backfilling was performed in the defunct underground mine, decant occurred. Ash-backfilling was immediately suspended as it was thought to have over-pressurised the system and caused decant. Contrariwise, a number of years later decant was still occurring even though ash-backfilling had been terminated. An investigation was launched to determine whether it was the ash-backfilling which had solely caused decant, or if additional contributing factors existed. Understanding the mine water decant is further complicated by the presence of underlying dolomites which when intersected during mining produced significant inflows into the underground mine workings. Furthermore, substantial subsidence has taken place over the underground mine area. These factors combined with the inherent difficulty of understanding unseen groundwater, produced a proverbial 1000-piece puzzle. Numerical groundwater modelling was a natural choice for evaluating the complex system of inter-related processes. A pre-mining model simulated the water table at the ground surface near the currently decanting area, suggesting this area was naturally susceptible for seepage conditions. The formation of a pathway from the mine to the ground surface combined with the natural susceptibility of the system may have resulted in the mine water decant. This hypothesis advocates that mine water was going to decant in this area, regardless of ash backfilling. The numerical groundwater flow model builds a case for this hypothesis from 1) the simulated upward flow in the pre-mining model and 2) the groundwater level is simulated above the surface near the currently decanting area. A mining model was then utilised to run four scenarios, investigating the flux from the dolomites, subsidence, ash-backfilling and a fault within the opencast mine. The ash-backfilling scenario model results led to the formation of the hypothesis that completing the ash-backfilling could potentially reduce the current decant volumes, which is seemingly counterintuitive. The numerical model suggested that the current ash-backfill areas reduce the groundwater velocity and could potentially reduce the decant volumes; in spite of its initial contribution to the mine water decant which is attributed to incorrect water abstraction methods. In conclusion, the application of numerical models to improve the understanding of complex systems is essential, because the result of interactions within a complex system are not intuitive and in many cases require mathematical simulation to be fully understood.

Abstract

Currently limited progress is made in South Africa (and Africa) on the protection of groundwater used for drinking water. To achieve the objective of water for growth and development and to provide socio-economic and environmental benefits of communities using groundwater, significant aquifers and well fields must be adequately protected. Groundwater protection zoning is seen as an important step in this regard. Till today, limited case studies of groundwater protection zoning exists in Africa. A case study at the Rawsonville research site is conducted in this research project. Generic protection zones can be delineated at the site using published reports and database data. However, due to the complexity of the fractured rock at the research site, these would be of limited value and would not provide adequate protection for the well field Baseline data was collected by conducting a hydro census and through aquifer tests. An inventory of the activities that can potentially impact water quality was done and aquifer characteristics such as transmissivity and hydraulic conductivity were determined through various types of aquifer testing. Fracture positions were identified using fluid logging and fracture flow rates were also measured using fluid logging data. A conceptual model and preliminary 3D numerical model were created to try to understand groundwater movement at the research site. The knowledge gained will be used to guide information gathering and monitoring that can be used to build a more detailed numerical model and implement a trustworthy groundwater protection plan at a later stage. The expected results will have applicability to groundwater management in general. The protection plan developed during this project can be used as a case study to update and improve policy implementation. {List only- not presented}

Abstract

Groundwater levels in E33F quaternary catchment are at their lowest level ever. The impact of climatic variation and increasing abstraction were determined to be the main factor. There are 115 registered groundwater users in E33F and the monthly abstraction volumes are not being measured. There is a need to use land use activities as well as the population to estimate groundwater use. The main objective is to use non-groundwater monitoring data to estimate groundwater use in order to protect the aquifer and ecosystem in general in varying climatic condition. Land use activities information was used to estimate groundwater use in E33F quaternary catchment. The estimated groundwater use volumes were compared to allocated and measured volumes. For domestic groundwater use estimation, population data and an estimation 100 litre per person per day were used. The water requirements for the types of crops being cultivated together with the area (m2) were used to estimate groundwater use volumes for irrigation. The number and type of live stocks were used with the water requirements for each livestock type to estimate the groundwater use volumes. 96 % of groundwater users are using groundwater for irrigation purposes with 9 966 105 m3/a allocated for irrigation. Mining, industries, domestic and livestock are allocated 100 200 m3/a. The estimated groundwater use volume for irrigation is 30 960 000 m3/a, which is three times higher than the allocated volume. Groundwater use volume for domestic use is estimated to be 38 225 m3/a which is higher than the 31 000 m3/a allocated. The total estimated groundwater use volume in E33F is estimated to be 30 998 225 m3/a, which is three times higher than the allocated groundwater use volume of 10 066 305 m3/a. This estimation could be higher as only registered boreholes were used and estimations from mining, Industries and live stocks were excluded due to lack of data

Abstract

In the following study, the soil and groundwater regime of the Rietvlei wetland near Cape Town are characterised. This has been done by means of logging the subsurface material during the construction of 8 shallow wells, complimented with field observations, and surveying the dug wells. The water stemming from these wells was sampled and analysed for Oxygen 18 and Deterium. Downhole salinity logs of the wells were also undertaken and rainfall samples were analysed for the aforementioned stable isotopes. Results indicate a distinct relationship between elevation and soil structure. Through the use of the water table method, it was found that the relationship between elevation and soil moisture had a direct impact on spatially distributed groundwater recharge on an event basis. Furthermore, higher salinities were found with depth in groundwater in the same wells which had higher recharge values. Isotopic results indicate that groundwater all stems from rainfall, with the exception of Well 8 is influenced by the river due to its proximity to the surface water body. The various water chemistries and soil profiles have a direct impact on the type of flora and its distribution throughout the study area. This study managed to conceptualize the relationship between groundwater, soil profiles and the various plant types surviving in the Rietvlei wetland. Future studies can focus on computer based approaches in order to predict how changes in groundwater characteristics caused by natural or anthropogenic factors would affect other ecohydrological processes within the wetland. These findings can be incorporated in decision making processes concerning groundwater management.

Abstract

Data acquisition and Management (DAM) is a group of activities relating to the planning, development, implementation and administration of systems for the acquisition, storage, security, retrieval, dissemination, archiving and disposal of data. Data is the life blood of an organization and the Department of Water and Sanitation (DWS) is mandated by the National Water Act (No 36 of 1998) as well as the Water Services Act (No 108 of 1997), to provide useful water related information to decision makers in a timely and efficient manner. In 2009 the DWS National Water Monitoring Committee (NWMC) established the DAM as its subcommittee. The purpose was to ensure coordination and collaboration in the acquisition and management of water related data in support of water monitoring programs. The DAM subcommittee has relatively been inactive over the years and this has led to many unresolved data issues. The data extracted from the DWS Data Acquisition and Management Systems (DAMS) is usually not stored in the same formats. As a result, most of the data is fragmented, disintegrated and not easily accessible, making it inefficient for water managers to use the data to make water related decisions. The lack of standardization of data collection, storage, archiving and dissemination methods as well as insufficient collaboration with external institutions in terms of data sharing, negatively affects the management water resources. Therefore, there is an urgent need to establish and implement a DAM Strategy for the DWS and water sector, in order to maintain and improve data quality, accuracy, availability, accessibility and security. The proposed DAM Strategy is composed of the six main implementation phases, viz. (1) Identification of stakeholders and role players as well as their roles and responsibilities in the DWS DAM. (2) Definition of the role of DAM in the data and information management value chain for the DWS. (3) Development of a strategy for communication of data needs and issues. (4) Development of a DAM life Cycle (DAMLC). (5) Review of existing DAMS in the DWS. (6) Review of current data quality standards. The proposed DAM Strategy is currently being implemented on the DWS Groundwater DAM. The purpose of this paper is to share the interesting results obtained thus far, and to seek feedback from the water sector community.

Abstract

Three dimensional numerical flow modelling has become one of the best tools to optimise and management wellfields across the world. This paper presents a case study of simulating an existing wellfield in an alluvial aquifer directly recharged by a major perennial river with fluctuating head stages. The wellfield was originally commissioned in 2010 to provide a supply of water to a nearby Mine. Ten large diameter boreholes capable of abstracting ±2 000 m3 /hour were initially installed in the wellfield. The numerical groundwater flow model was used to evaluate if an additional 500 m3 /hour could be sustainably abstract from the alluvial aquifer system. A probabilistic river flow assessment and surface water balance model was used to quantify low and average flow volumes for the river and used to determine water availability in the alluvial aquifer over time. Output generated indicated that the wellfield demand only exceeded the lowest 2% (98th percentile) of measured monthly river flow over a 59 year period, thereby proving sufficient water availability. Conceptual characterisation of the alluvial aquifer was based on previous feasibility studies and monitoring data from the existing hydrogeological system. Aquifer parameters was translated into the model discretisation grid based on the conceptual site model while the MODFLOW River package was used to represent the river. Actual river stage data was used in the calibration process in addition to water levels of monitoring boreholes and pump tests results. The input of fluctuating river water levels proved essential in obtaining a low model error (RMSE of 0.3). Scenario modelling was used to assess the assurance of supply of the alluvial aquifer for average and drought conditions with a high confidence and provided input into further engineering designs. Wellfield performance and cumulative drawdown were also assessed for the scenario with the projected additional yield demand. Scenario modelling was furthermore used to optimise the placement of new boreholes in the available wellfield concession area.

Abstract

Tailings storage facilities are significant contributors of dissolved solids to underlying aquifers and adjacent watercourses. Salt balances indicate estimated seepage loads of the order of 1 500 tonnes of chloride per year. Actual seepage loads will be determined by the hydraulic conductivity of the tailings and mechanisms of flow within the tailings. Field observations and sample analytical results from several platinum tailings facilities are presented. These indicate the development of lenses of clay sized material within coarser silty material and suggest a tortuous seepage flow path, perhaps characterised by zones of preferential flow. The implications of seepage modelling and geochemical data on the salt loads mobilised from tailings are discussed. Results suggest that tailings facilities are effective at retaining salts and that release of accumulated salts after closure may take place at long time scales. {List only- not presented}

Abstract

This study intent to share the legal and institutional analysis of the UNESCO IHP project "Groundwater Resources Governance in Transboundary Aquifers" (GGRETA) project for the Stampriet Transboundary aquifer. The Intergovernmental Council (IGC) of the UNESCO International Hydrological Programme (IHP) at its 20th Session requested the UNESCO-IHP to continue the Study and Assessment of Transboundary Aquifers and Groundwater Resources and encouraged UNESCO Member States to cooperate on the study of their transboundary aquifers, with the support of the IHP. The GGRETA project includes three case studies: the Trifinio aquifer in Central America, the Pretashkent aquifer in central Asia and the Stampriet aquifer in southern Africa. This study focuses on the Stampriet Transboundary Aquifer System that straddles the border between Botswana, Namibia and South Africa. The Stampriet system is an important strategic resource for the three countries. In Namibia the aquifer is the main source of water supply for agricultural development and urban centers in the region, in Botswana the aquifer supplies settlements and livestock while in South Africa the aquifer supplies livestock ranches and a game reserve. The project methodology is based on UNESCO's Shared Aquifer Resources Management (ISARM) guidelines and their multidisciplinary approach to transboundary aquifers governance and management, addressing hydrogeological, socio-economic, legal, institutional and environmental aspects. The GGRETA builds recognition of the shared nature of the resource, and mutual trust through joint fact finding and science based analysis and diagnostics. This began with collection and processing of legal and institutional data at the national level using a standardized set of variables developed by the International Groundwater Resources Assessment Center (IGRAC). This was followed by harmonization of the national data using common classifications, reference systems, language, formats and derive indicators from the variables. The harmonized data provided the basis for an integrated assessment of the Stampriet transboundary aquifer. The data assisted the case study countries to set priorities for further collaborative work on the aquifer and to reach consensus on the scope and content of multicountry consultation mechanism aimed at improving the sustainable management of the aquifer. The project also includes training for national representatives in international law applied to transboundary aquifers and methodology for improving inter-country cooperation. This methodology has been developed in the framework of UNESCO's Potential Conflict Cooperation Potential (PCCP) program. The on-going study also includes consultation with stakeholders to provide feedback on proposals for multicountry cooperation mechanisms. It is anticipated that upon completion of the study, a joint governance model shall have been drawn amongst the three countries sharing the aquifer to ensure a mutual resource management.

Abstract

A standard methodology for establishing a groundwater baseline for unconventional gas projects in South Africa did not exist at the time the current study was undertaken. The study was therefore aimed at filling this gap, specifically focusing on hydraulic fracturing and underground coal gasification (UCG) operations.

An extensive literature review was conducted to establish the baseline methodology. The latest literature on hydraulic fracturing and UCG was reviewed to determine how these activities may potentially impact on the groundwater environment. The literature review further examined the role that geological structures, such as dolerite intrusives, may be play in the migration of contaminants associated with unconventional gas projects. The literature review then focused on questions such as what size the study area should be, what geological and hydrogeological investigations need to be conducted before embarking on the sampling events, which chemical parameters need to be included in the groundwater analyses, whether the drilling of dedicated boreholes are required to collect representative groundwater samples, and how to collect representative samples for these different chemical parameters.

In this paper, the proposed methodology is presented in the form of a flow diagram to be used to guide future groundwater baseline projects in South Africa.

Abstract

This paper was presented at the GWD Central Branch Symposium, Potchefstroom in 2012

Numerical modelling of hydrogeological systems has progressed significantly with the evolution of technology and the development of a greater understanding of hydrogeology and the underlying mathematical principles. Hydrogeological modelling software can now include complex geological layers and models as well as allow the pinching out of geological features and layers. The effects of a complex geology on the hydraulic parameters determined by numerical modelling is investigated by means of the DHI-WASY FEFLOW and Aranz Geo Leapfrog modelling software packages.

The Campus Test Site (CTS) at the University of the Free State in Bloemfontein, South Africa was selected as the locale to be modelled. Being one of the most studied aquifers in the world, the CTS has had multiple research projects performed on it and as a result ample information is available to construct a hydrogeological model with a high complexity. The CTS consists primarily of stacked fluvial channel deposits of the Lower Beaufort Group, with the main waterstrike located on a bedding-plane fracture in the main sandstone aquifer.

The investigation was performed by creating three distinct hydrogeological models of the CTS, the first consists entirely of simplified geological strata modelled in FEFLOW by means of average layer thicknessand does not include the pinching out of any geological layers. The second model was created to be acopy of the first, however the bedding-plane fracture can pinch out where it is known to not occur. The third and final model consisted of a complex geological model created in Leapfrog Geo which was subsequently exported to FEFLOW for hydrogeological modelling.

Abstract

Vapour intrusion (VI) is recognized to drive human health risk at numerous sites that have been contaminated by petroleum products and other volatile contaminants. The risks related to VI are typically evaluated using direct measurement (vapour sampling) or modelling methods. ERM has developed a toolbox approach using a combination of exclusion distance criteria, direct measurement and modelling methods to assess risks and achieve closure. For direct measurement, samples of vapour are taken beneath the floor slab of buildings (sub-slab sampling) or from the air inside the buildings (indoor air sampling). Modelling methods are often used to estimate the partitioning of volatile contaminants from soil or groundwater sources into the vapour phase and the subsequent transport of vapours from the subsurface environment into habitable buildings. A limitation of modelling approaches is that they are designed to be conservative to be adequately protective of sensitive receptors. VI models also do not typically take into account the degradation of hydrocarbon vapours in the presence of oxygen, which has been found to be a significant process for petroleum hydrocarbons. The authors have compiled a dataset of petroleum vapour and groundwater results from over 50 petroleum release sites in southern Africa. These data were used to develop exclusion distance criteria for vapours emitted from contaminated groundwater sources (i.e. distance from the source at which sufficient aerobic attenuation has occurred for the VI risk to be negligible). A standard "lines of evidence" approach has been applied to the assessment of VI risk by firstly applying the exclusion distance criteria to sites with groundwater contaminant plumes beneath buildings, and if these are met, the sites are considered to have no unacceptable VI risk. Where exclusion screening criteria are not met, risk is estimated using modelling, and if a potential risk is predicted, then direct sub-slab measurements are taken to more accurately assess the risk. Lastly, where sub-slab assessment predicts a potential VI risk, indoor vapour measurement are taken to evaluate actual risk, taking into account interferences from other sources and background levels of contaminants. Mitigating measures can then be applied as appropriate. Various case studies will be presented including direct measurements at industrial and residential sites overlying contaminant plumes and modelling methods at residential properties adjacent to service station sites. A risk-based approach to the assessment of contaminated land provides a sustainable and cost effective methodology, and also avoids unnecessary remediation. The results show that VI risks can be adequately addressed with a toolbox approach using multiple lines of evidence.

Abstract

Arsenic is a common contaminant typically found in effluent from gold mine operations and copper smelters throughout the world. The geochemical behaviour of arsenic in contact with dolomite underlying an arsenic containing waste rock pile was investigated. The interaction between the arsenic and the dolomite is an important control in the subsequent transport of the arsenic in the dolomitic aquifer. Rocks with varying dolomite content were tested to investigate the interaction between the arsenic and dolomite. From the modelling and test results it was estimated that in the aquifer, between 60 - 90% of arsenic is present in the solid phase under oxidation conditions at >50 mV. At 50 to -25 mV about 40 - 60% of the arsenic is estimated to be present in the solid phase and below -25 mV about 0 - 10% of arsenic will be present in the solid phase. Although some arsenic is removed by the dolomite in the aquifer the arsenic would still be present above acceptable guidelines for drinking water. The arsenic in the solid phase will be in equilibrium with the aquifer water and could be remobilised 1) under more reducing conditions or 2) with a decrease in arsenic in the aquifer.

Abstract

Hydrogeological environments are commonly determined by the type of underlying geology; these environments may have a tremendous effect on the mobility and recovery of LNAPLs.  Hydrogeological environment include intergranular sediments and bedrocks of contrasting permeability and porosity. This paper synthesizes several case studies and conceptual models of different hydrological environments and illustrates how they affect the flow characteristics and rebound of LNAPLs.

Abstract

Pollution of underground water is fast becoming a global problem and South Africa is not immune to this problem. The principal objective of this paper is to investigate the effectiveness of laws and policies put in place to mitigate underground water pollution. The paper also seeks to examine the causes and types of underground water pollution followed by a closer look into the laws and policies in place to mitigate the pollution levels. Finally, the paper seeks to ascertain whether the current policies are properly implemented. The paper follows content analysis (desk research) to achieve the objectives. Policy recommendations are given based on the findings. {List only- not presented}

Abstract

Gold Mining activities the past 60 years at AngloGold Ashanti polluted the groundwater underlain by 4000 ha of land at the Vaal River and West Wits operations in South Africa. Sulphide material in Tailings Storage Facilities, Waste Rock Dumps and extraction plants produce Saline Mine Drainage with Sulphate, minor salts and metals that seep to the groundwater and ultimately into surface water resources. Water regulation requires mines to prevent, minimise/ reduce or eliminate pollution of water resources. The waste philosophy has matured from tolerate and transfer to treat and termination of pollution sources. The impact of the pollution was determined and possible technologies to treat the impact were evaluated. Source controls of proper water management by storm water management, clean dirty water separation, lined water conveyance structures and reduced deposition of water on waste facilities is crucial. The aquifer character determines the possible remediation technology. From the possible technologies phytoremediation, physical interception and re-use of this water was selected. In future possible treatment of the water would be considered. This paper explain the strategy and report on the phased implementation of these plans and the expected results. The establishment of 750 ha of woodlands as phytoremediation, interception trenches of 1250 m, 38 interception boreholes and infrastructure to re-use this water in 10 water management areas is planned. The total volume of 15 Ml/day would be abstracted for re-use from the boreholes and trenches. The woodlands can potentially attenuate and treat 5 ml/day. The established woodlands of 150 ha proof successful to intercept diffused seep over the area of establishment and reduce the water level and base flow. The 2 implemented trenches of 1000 m indicate a local decline in the water level with interception of shallow groundwater within 1-2 m from surface. The 2 production interception well fields abstracting 50 and 30 l/s respectively indicate a water level decline of between 2 to 14 m with regional cones of depression of a few hundred meters to intercept groundwater flow up to 20 meter. Predictions from groundwater modelling indicate that these schemes can minimise pollution during the operational phase and protect downstream water resources. Predictions from modelling indicate that the pollution sources need to be removed to ensure long term clean-up to return the land to save use. The gold and uranium prize is securing the removal of the sources through re-processing of the tailings and waste rock dumps. After removal of the sources of pollution the remediation schemes would have to be operated for 20 years to return the groundwater to an acceptable standard of stock watering and industrial water use. The water quality is observed by a monitoring network of approximately 100 observation boreholes.

Abstract

Quantification of groundwater is important as it should determine the maximum sustainable use of the resource. The SAMREC Code that is required for mineral resource quantification sets out minimum standards, guidelines and recommendations for public reporting of exploration results for mineral resources and reserves. The code serves as the basis for mineral asset valuation and provides quality assurance to the process and an understanding of the results. In groundwater far too often, various methods are used for resource quantification that leads to various results even should the same resource be investigated by two different hydrogeologists. In far too many cases, the resource is not quantified properly which leads to vast over or under estimations. The result is a lack of trust in groundwater resources. As has been done in the international arena, it is similarly proposed that a code be developed for South Africa to ensure that the sustainability of groundwater resources is determined and the impacts of utilization on the water Reserve and the environment be quantified at a minimum level and that basic hydrogeological principles are followed. A South African Groundwater Regulation Code for sustainable resource quantification and impact assessment (SAGREC) is developed that is proposed to guide groundwater investigations and development processes from planning to baseline assessments, drilling and aquifer testing to resource quantification and sustainability modeling. The aim is to ensure trust being built on groundwater as a resource due to projects that follow a formal process that quantifies the assurance of supply and determines the environmental impacts.

Abstract

Groundwater is a vital source of water for many communities in South Africa and elsewhere. Besides the changing climate, rapidly spreading invasive alien plants with deep roots e.g. Prosopis spp, pose a serious threat to this water source. Dense impenetrable thickets of Prosopis occur in the drier parts of the country mainly along river channels in the Northern, Eastern and Western Cape Provinces. Few studies have quantified the actual water use by this species outside of the USA where it is native. Consequently the impacts of Prosopis invasions on groundwater resources are not well documented in South Africa. The aim of this study was to quantify the actual volumes of water used by Prosopis invasions and to establish the effects on groundwater. Because deep rooted indigenous trees that normally replace Prosopis once it has been cleared also use groundwater, we sought to quantify the incremental water use by Prosopis over and above that used by indigenous trees in order to determine the true impacts on groundwater. The study was conducted at a site densely invaded by Prosopis at Brandkop farm near the groundwater dependent town of Nieuwoudtville in the Northern Cape. One in seven trees at the site is the Vachellia karroo (formerly A. karroo) which is the dominant deep rooted indigenous tree species. Actual transpiration rates by five Prosopis and five V. karroo are being measured using the heat pulse velocity (HPV) sap flow technique. Additional HPV sensors were installed on the tap and lateral roots to study the water uptake dynamics of the trees. Groundwater levels are being monitored in four boreholes drilled across the site while sources of water used by the trees (i.e. whether soil or groundwater) is being determined using O/H stable isotopes. For similar size trees, V. karroo had higher transpiration rates than Prosopis because of the larger sapwood to heartwood ratio in V. karroo than in Prosopis. However, at the stand level Prosopis consumed significantly larger amounts of water than V. karroo. This is because Prosopis invasions had a much higher tree density than V. karroo. From August 2013 to July 2014, annual stand transpiration for Prosopis (~ 372 mm) was more than 4 times higher than that of V. karroo (~ 84 mm). Tree water uptake was correlated to changes in groundwater levels (R2 ~ 0.42) with groundwater abstractions of ~ 2600 m3/ha/y by Prosopis compared to ~ 610 m3/ha/y for V. karroo. In addition, Prosopis showed evidence of hydraulic redistribution of groundwater wherein groundwater was deposited in the shallow soil layers while V. karroo did not. Results of this study suggest that clearing of Prosopis to salvage groundwater should target dense stands while less dense stands should be prevented from getting dense. {List only- not presented}

Abstract

Huixian Karst National Wetland Park is the most typical karst wetland in the middle and low latitudes of the world and has become an internationally important wetland. The relationship between water quality and aquatic organisms in Huixian Wetland is a hot research topic in wetland ecology. This article focuses on the relationship between the current water quality situation in Guilin Huixian Karst Wetland and the growth of wetland plants. Sixteen sampling points are set up in the wetland to monitor and analyze water quality in wet, normal, and dry seasons. The Kriging index interpolation method is used to obtain a comprehensive water quality interpolation map in the survey area during normal water periods and in combination with the wetland plant survey sample data and the landscape status. A comprehensive analysis of the relationship between wetland plant growth and water quality. The results show that the centre of Huixian Wetland receives recharge from surrounding groundwater, which is greatly affected by the surrounding water quality. The comprehensive water quality is relatively good in the dry season, relatively poor in the normal season, and the worst in the wet season. Agricultural production, non-point source pollution, rural domestic sewage, and human interference affect wetland water quality, which directly affects the structure and function of plant communities and the ecological service function of wetlands.

Abstract

Underground coal gasification (UCG) is considered a cleaner energy source as its known effect on the environment is minimal; it is cheaper and a lesser contributor to greenhouse gas emissions when compared to conventional coal mining. It has various potential impacts but the subsidence of the surface as well as the potential groundwater contamination is the biggest concerns. Subsidence caused by UCG processes will impact on the groundwater flow and levels due to potential artificial groundwater recharge. The geochemistry of the gasifier is strongly depended upon site specific conditions such as coal composition/type and groundwater chemistry. Independent of the coal rank, the most characteristic organic components of the condensates is phenols, naphthalene and benzene. In the selection of inorganic constituents, ammonia, sulphates and selected metals and metalloids such as mercury, arsenic, and selenium, are identified as the dominant environmental phases. The constituents of concern are generated during the pyrolysis and after gasification as dispersion and penetration of the pyrolysis take place, emission and dispersion of gas products, migration by leaching and penetration of groundwater. A laboratory-based predictive study was conducted using a high pressure thermimetric gasification analyser (HPTGA) to simulate UCG processes where syngas is produced. The HPTGA allows for simulation of the actual operational gasifier pressure on the coal seam and the use of the groundwater sample consumed during gasification. A gasification residue was produced by gasifying the coal sample at 800 °C temperature and by using air as the input gas. The gasification residue was leached using the high temperature experimental leaching procedure to identify the soluble phases of the gasified sample. The leachate analysis is used to determine the proportion of constituents present after gasification which will be removed by leaching as it is exposed to external forces and how it will affect the environment. The loading to groundwater for the whole gasifier is then determined by applying the leachate chemistry and rock-water ratio to the gasifier mine plan and volumes of coal consumed. 

Abstract

The Department of Water Affairs and Sanitation is the custodian of the Water Resource in South Africa. The Western Cape Regional Office, Geotechnical Service Sub Directorate, is responsible for management of groundwater resources in two Water Management Areas (WMA), Olifants Doorn-Berg and Breede-Gouritz. Twenty-nine monitoring routes comprising 800 sites in total are monitored across the Western Cape Region. The purpose of this paper is to create awareness of groundwater related databases and the type of information products used in assessing the status of data bases and groundwater resources. This is to assist and support the scientists, technicians, managers, external stakeholders and/or general public. The main question that needs to be answer is: "What is the current groundwater data management situation in the Regional office?" With the GIS as platform, geographical information was generated from existing data bases to answer questions such as, what is being monitored, where is it being monitored, who is monitoring it, why is it being monitored and when is it being monitored? These questions are applicable to the Region, Water Management Areas, the monitoring route and geosites. Graphical time-series information generated from available data, in combination with the generated geographical information, showed the gaps, hot spots and what is still needed for all the facets of groundwater management (from data acquisition to information dissemination) processes. The result showed the status of data bases, need for data in areas of possible neglect, training gaps, inadequate structure and capacity, instrumentation challenges, need for improvement of commitment and discipline, as well as many other issues. The information generated proves to be an easy tool for Scientists, Technicians and Data Administrators to assist them to be on top of the groundwater resource management in their area of responsibility. The expansion of the use of GIS as a groundwater management tool is highly recommended. This will ensure better understanding of the resource: "The Hidden Treasure".

Abstract

Climate change contributes to the way in which people live. Natural resources such as groundwater, wood and surface water form a great part of livelihood in rural communities and are used extensively in rural areas where basic services have not yet been provided. The effect of climate change to all these natural resource may impact the lives of those in rural communities. Climate change is already starting to affect some of the poor and most vulnerable communities around the world. The aim of the dissertation is to develop a framework to assess the vulnerability of rural communities to climate change, with a specific focus groundwater and issues relating to gender. A questionnaire and interviews were used to collect data about rural communities' level of awareness climate change, their attitudes toward coping with climate change impact, level of education, income scale and how does this affect their security. Hyrodocensus was taken around the village to determine the rivers, dams, boreholes, abandoned boreholes and wells. Water samples were collected and analysed. The response rate was higher in females than in male's stakeholders (54% vs 46%).the results show that woman were mostly doing the hard work to complete daily basic activities. Education was found to be of high school level and incomes were low. The framework was developed with basic need showed that the area was at risk of poverty .Boreholes was found and water quality was analysed to be adequate for drinking water purpose. More information will be discussed on presentation.

Abstract

In the wake of the ongoing water restrictions in South Africa, the issue of groundwater potential for drought relief has been debated on many environmental and socio-economic platforms, nationally. Consequently, the development of groundwater and its related vulnerabilities has become a key topic to the decision makers and stakeholders. Currently, the recruitment of water professionals into government and private water sectors adds substantial value to understanding the importance of protecting this precious resource. This has allowed the monitoring of groundwater to gain ever increasing momentum. Groundwater monitoring has become an essential scientific tool for role-players to achieve robust and verifiable data used for modelling aquifer potential and vulnerability to pollution and over-abstraction. The data is generally sourced from various hydrogeological and environmental investigations which include groundwater development, vulnerability assessment and remediation projects. Groundwater and environmental consulting firms are tasked with imperative roles for implementing groundwater monitoring programmes to the ever growing industrial, commercial, agricultural and public sectors in South Africa. However, groundwater monitoring data, especially in the private sector, are reliable but remains mostly inaccessible due to confidentiality clauses. This does limit our accuracy and comprehensive understanding for determining aquifer potential and vulnerability risks at large. The conceptualisation and modelling of vast monitoring datasets has been recognised as an important contributing factor to enhance groundwater sustainability. This research emphasises the significance of groundwater monitoring for development, protection and remediation of aquifers. Comparing monitoring results from typical sites and methods, provides scientific validation to support good governance of water. Deterioration of groundwater potability in the sight of an existing drought can have irreversible environmental and economic implications for South Africa.

Abstract

This study was aimed at developing an integrated groundwater-surface water interaction (GSI) model for a selected stretch of the Modder River by considering the following five different aspects of the GSI: 1) the distribution of different aquifer systems (structural connectivity) along the river 2) the hydraulic connectivity between the aquifer systems, 3) the volumes of water abstracted from the aquifers by streamside vegetation, 4) the volumes of water replenished to the groundwater system through rainfall recharge, and 5) the exchange fluxes between the various components of the groundwater-surface water system. The distribution of the aquifer systems was investigated by means of a) geo-electrical surveys, and b) in situ slug tests while their hydraulic connectivity was investigated by hydrogeochemical routing. The volumes of water abstracted by streamside vegetation were estimated by the quantification of the transpiration from individual plants and the groundwater recharge was estimated by a root zone water balance. The water exchange fluxes between the groundwater and surface water were determined from a simple riparian zone groundwater budget. The results of the geo-electrical surveys and slug tests allowed the delineation of the riparian area aquifers (RAA) and the terrestrial area aquifers (TAA) on both the south-eastern and north-western sides of the river. Based on the results of hydrochemical analyses, saturation indices and inverse mass balance modelling, the GSI involves flow of water from the TAA to the RAA, and finally to the river on the south-eastern side while it involves flow from the river into the RAA with a limited exchange with the TAA on the south-eastern side. The dominant vegetation on the study area was found to be the Acacia karroo and Diospyros lycioides. The close similarities in isotope compositions of the xylem sap and the borehole water samples suggested that the Acacia karroo sourced its water from the groundwater storage while differences in isotope compositions suggested that the Diospyros lycioides did not source water from the groundwater storage at the time of measurement. The results of groundwater recharge estimation in the study area highlighted the fact that both the antecedent moisture and the rainfall amounts determine whether recharge to the groundwater system will take place. Finally, the results of baseflow estimation indicated that the river is a gaining stream along the south-eastern reach while acting as a losing stream along the north-western reach.

Abstract

Geochemical investigations for a planned coal mine indicated that the coal discard material that would be generated through coal processing would have a significant potential to generate acid rock drainage. A power station is planned to be developed in close proximity to the coal mine, and the potential for co-disposal of coal discard with fly-ash material required examination. Fly-ash is typically highly alkaline and has the potential to neutralise the acidic coal discard material. In order to investigate whether this was a viable option, the geochemical interaction between the coal discard and fly-ash was investigated. Geochemical data, including acid-base accounting, total chemical compositions, leach test data and kinetic test data, were available for the coal discard material and the fly-ash. Using these data as inputs, a geochemical model was developed using Phreeqci to predict the pH of leachate generated by mixing different ratios of coal discard and fly-ash. The ratio of coal discard to fly-ash was established that would result in a leachate of neutral pH. Using this prediction, a kinetic humidity cell test was run by a commercial laboratory for a total of 52 weeks using the optimal modelled ratio of discard and fly-ash. Although leachate pH from the kinetic test initially reflected a greater contribution from fly-ash, the pH gradually decreased to the near-neutral range within the first 20 weeks, and then remained near-neutral for the remainder of the 52-week test. During this period, sulphate and metal concentrations also decreased to concentrations below those generated by either the fly-ash or coal discard individually. The addition of fly-ash to the coal discard material provided sufficient neutralising capacity to maintain the near-neutral pH of the co-disposal mixture until the readily available sulphide minerals were oxidized, and the oxidation rates decreased. At the end of the test, sufficient neutralising potential remained in the humidity cell to neutralise any remaining sulphide material. The results of this investigation suggested that, under optimal conditions, co-disposal of fly-ash with coal discard is a viable option that can result in reduced environmental impacts compared to what would be experienced if the two waste materials were disposed of separately.