Conference Abstracts

All Abstracts were presented at the Groundwater Conferences

Displaying 701 - 750 of 795 results

Title	Presenter Name	Presenter Surname	Conference year	Keywords
Geochemical Behaviour Of Arsenic In Contact With Dolomite	Johan	Fourie	2017	Arsenic, geochemical, dolomites
Abstract Arsenic is a common contaminant typically found in effluent from gold mine operations and copper smelters throughout the world. The geochemical behaviour of arsenic in contact with dolomite underlying an arsenic containing waste rock pile was investigated. The interaction between the arsenic and the dolomite is an important control in the subsequent transport of the arsenic in the dolomitic aquifer. Rocks with varying dolomite content were tested to investigate the interaction between the arsenic and dolomite. From the modelling and test results it was estimated that in the aquifer, between 60 - 90% of arsenic is present in the solid phase under oxidation conditions at >50 mV. At 50 to -25 mV about 40 - 60% of the arsenic is estimated to be present in the solid phase and below -25 mV about 0 - 10% of arsenic will be present in the solid phase. Although some arsenic is removed by the dolomite in the aquifer the arsenic would still be present above acceptable guidelines for drinking water. The arsenic in the solid phase will be in equilibrium with the aquifer water and could be remobilised 1) under more reducing conditions or 2) with a decrease in arsenic in the aquifer.
An Approach To Determining The Most Suitable Combination Of Groundwater Impact Mitigation Measures With The Use Of A Gold Tailings Case Study	Pieter F	Labuschagne	2019	impact mitigation measures
Abstract The mitigation of groundwater impacts related to gold mining tailings disposal within the Orkney-Klerksdorp region was assessed and presented as a case study. The most pressing concern for the facility owners is the potential for pollution of water resources in the vicinity of the mines, especially after mine closure. The key focus of this paper is to describe how methods were applied to characterise the aquifer and keeping the source-pathway-receptor principles in mind. Characterisation also involves lessons learn by comparing pre-tailings deposition and post-tailings deposition aquifer bahviour. Ultimately the process followed in this paper has led to the development of a logical approach to estimate groundwater liability costs in a typical tailings environment. The link between hydrogeology, geotechnical engineering and civil engineering was identified as a critical foundation for the development of a successful groundwater management strategy
Reliability of laboratory testing of groundwater samples	Venetia	Mitchell	2015
Abstract Resources required for groundwater sampling includes but not limited to pumping equipment, trained manpower and technical resources specific to the sampling function. Bearing these expenses in mind, choosing a laboratory for testing the water samples collected should be a carefully considered purchase. Choosing a testing facility that cannot deliver an efficient, reliable and technically sound service could render the sampling futile. Water samples submitted to a laboratory for testing are received from third party sources more than ninety percent (90%) of the time and sampling techniques and sample integrity cannot be verified by the laboratory. However, the validity, reliability and integrity of the laboratory testing are within the control of the testing facility. These aspects of a laboratory are usually controlled within a quality management system where established policies and procedures form the basis of such a system. This system maintains a foundation for technical competence and customer service at the laboratory. There are numerous testing facilities available to Consultants requiring chemical and microbiological groundwater testing, each with varying levels of integrity and technical ability. It is imperative to maintain confidence in the validity of results of analyses from a laboratory and this assurance can be understood through an examination of a facility's management system. An established quality management system would comprise a policy statement, associated technical methods and technical and administrative procedures. This system would be formally documented and audited as part of the on-going laboratory's management system. In some instances, laboratories formalise this into an accreditation of the laboratory to an international standard, such as ISO 17025:2005. The assurance that the results of analyses from any laboratory are of sound technical integrity would depend on factors such as - personnel training, - accommodation and environmental conditions under which the tests are carried out, - validation of the methodology applied (including the uncertainty of measurement), - the calibration and maintenance of the equipment used, - understanding the traceability of and measurement undertaken, - handling and preservation of the sample on receipt and while in the laboratory. Each of these factors plays a critical role in the integrity of results of analyses and should be interrogated when trying to understand the reliability and competence of the laboratory of choice.{List only- not presented}
A predictive study to better protect groundwater at Underground Coal Gasification site	Venessa	Aphane	2015	underground coal gasification
Abstract Underground coal gasification (UCG) is considered a cleaner energy source as its known effect on the environment is minimal; it is cheaper and a lesser contributor to greenhouse gas emissions when compared to conventional coal mining. It has various potential impacts but the subsidence of the surface as well as the potential groundwater contamination is the biggest concerns. Subsidence caused by UCG processes will impact on the groundwater flow and levels due to potential artificial groundwater recharge. The geochemistry of the gasifier is strongly depended upon site specific conditions such as coal composition/type and groundwater chemistry. Independent of the coal rank, the most characteristic organic components of the condensates is phenols, naphthalene and benzene. In the selection of inorganic constituents, ammonia, sulphates and selected metals and metalloids such as mercury, arsenic, and selenium, are identified as the dominant environmental phases. The constituents of concern are generated during the pyrolysis and after gasification as dispersion and penetration of the pyrolysis take place, emission and dispersion of gas products, migration by leaching and penetration of groundwater. A laboratory-based predictive study was conducted using a high pressure thermimetric gasification analyser (HPTGA) to simulate UCG processes where syngas is produced. The HPTGA allows for simulation of the actual operational gasifier pressure on the coal seam and the use of the groundwater sample consumed during gasification. A gasification residue was produced by gasifying the coal sample at 800 °C temperature and by using air as the input gas. The gasification residue was leached using the high temperature experimental leaching procedure to identify the soluble phases of the gasified sample. The leachate analysis is used to determine the proportion of constituents present after gasification which will be removed by leaching as it is exposed to external forces and how it will affect the environment. The loading to groundwater for the whole gasifier is then determined by applying the leachate chemistry and rock-water ratio to the gasifier mine plan and volumes of coal consumed.
The Management of Groundwater resources using GIS/Cartography splay)	Freda	Jonck	2015
Abstract The Department of Water Affairs and Sanitation is the custodian of the Water Resource in South Africa. The Western Cape Regional Office, Geotechnical Service Sub Directorate, is responsible for management of groundwater resources in two Water Management Areas (WMA), Olifants Doorn-Berg and Breede-Gouritz. Twenty-nine monitoring routes comprising 800 sites in total are monitored across the Western Cape Region. The purpose of this paper is to create awareness of groundwater related databases and the type of information products used in assessing the status of data bases and groundwater resources. This is to assist and support the scientists, technicians, managers, external stakeholders and/or general public. The main question that needs to be answer is: "What is the current groundwater data management situation in the Regional office?" With the GIS as platform, geographical information was generated from existing data bases to answer questions such as, what is being monitored, where is it being monitored, who is monitoring it, why is it being monitored and when is it being monitored? These questions are applicable to the Region, Water Management Areas, the monitoring route and geosites. Graphical time-series information generated from available data, in combination with the generated geographical information, showed the gaps, hot spots and what is still needed for all the facets of groundwater management (from data acquisition to information dissemination) processes. The result showed the status of data bases, need for data in areas of possible neglect, training gaps, inadequate structure and capacity, instrumentation challenges, need for improvement of commitment and discipline, as well as many other issues. The information generated proves to be an easy tool for Scientists, Technicians and Data Administrators to assist them to be on top of the groundwater resource management in their area of responsibility. The expansion of the use of GIS as a groundwater management tool is highly recommended. This will ensure better understanding of the resource: "The Hidden Treasure".
A Decision Support System to Assess Climate Change Impacts on Rural Communities	Musiiwa	Luruli	2015
Abstract Climate change contributes to the way in which people live. Natural resources such as groundwater, wood and surface water form a great part of livelihood in rural communities and are used extensively in rural areas where basic services have not yet been provided. The effect of climate change to all these natural resource may impact the lives of those in rural communities. Climate change is already starting to affect some of the poor and most vulnerable communities around the world. The aim of the dissertation is to develop a framework to assess the vulnerability of rural communities to climate change, with a specific focus groundwater and issues relating to gender. A questionnaire and interviews were used to collect data about rural communities' level of awareness climate change, their attitudes toward coping with climate change impact, level of education, income scale and how does this affect their security. Hyrodocensus was taken around the village to determine the rivers, dams, boreholes, abandoned boreholes and wells. Water samples were collected and analysed. The response rate was higher in females than in male's stakeholders (54% vs 46%).the results show that woman were mostly doing the hard work to complete daily basic activities. Education was found to be of high school level and incomes were low. The framework was developed with basic need showed that the area was at risk of poverty .Boreholes was found and water quality was analysed to be adequate for drinking water purpose. More information will be discussed on presentation.
The Colenso Fault System - What Recent Geohydrological Investigations Taught Us	Nicolette	Vermaak	2019	investigations
Abstract A large number of groundwater investigations have been carried out in the Western Cape over the last decade or so. Most of them were related to water supply options for individuals, agriculture, businesses, industries, government departments and municipalities. Some of these developments have confirmed what we already knew about the groundwater characteristics and aquifers of the Western Cape, while others provided us with surprises - surprises so significant that we may have to re-write what we thought we knew. This paper will not be able to cover all the interventions and groundwater studies that have been done. Two case studies linked to the major geological structure in the Western Cape, namely the Colenso Fault (also known as the Franschhoek-Saldanha Fault), will therefore be used as an illustration of the lessons that were learnt by comparing them with our historical understanding of the associated groundwater characteristics. It will also show that there is a need for updated groundwater maps on smaller scale and a reassessment of the aquifers status.
The Value Of Monitoring: Case Study Of An Artesian Borehole	Neville	Paxton	2019	Monitoring
Abstract Groundwater monitoring, especially from the end users' point of view, is often considered an add-on, or even unnecessary overhead cost to developing a borehole. Simply measuring groundwater level over time can however tell a story on seasonal rainfall fluctuations as well as the response of an aquifer to the removal of an abstracted volume of water. In this case an artesian borehole of high yield and exceptional quality was drilled in an area of minimal groundwater use because of known poor quality and low yields. The borehole was drilled in two stages with the deeper drilling resulting in significantly higher yields and the artesian flow. Sediment free water, deep artesian water strikes and a lack of flow around the casing led to the conclusion that capping at surface would control the visible artesian flow of 4 L/s. A slight drop in pressure indicated that subsurface leakage may however be occurring. Neighbouring boreholes with automated water level monitoring provided data showing a correlation of drop in water level to the second deeper drilling event. The artesian borehole was yield tested and this too was visible in the water level monitoring data. Hereafter it became apparent that each activity performed at the artesian borehole had an impact on the monitoring boreholes, and that a subsurface leak was causing local depressurization of a semi-confined to confined aquifer. An initial attempt to save the artesian borehole was unsuccessful, resulting in the necessary blocking and abandonment of a high yielding, superior quality borehole. If monitoring data was not available the local drop in water level would never have been noticed with disastrous effect and no evidence for the cause. Simple water level monitoring has averted this and kept neighbourly relations and ground water levels intact
Dewatering Impacts of a South African Underground Coal Mine	Paul JH	Lourens	2017	coal mine, hydrocensus, dolerite contact zones, Monitoring, over-abstraction
Abstract The University of the Free State investigated the possible dewatering of boreholes situated on the farm properties in the vicinity of an underground coal mine. The investigation consisted of three phases. Phase one was a hydrocensus on the farm properties. Phase two consisted of borehole yield determination by conducting pumping tests on the boreholes (where possible) identified in the hydrocensus phase. Phase three included a visit to the underground mine workings, where water samples were collected at different groundwater inflow locations (especially water flowing in at the ventilation shaft). The monthly groundwater monitoring data of the underground coal mine was also incorporated for interpretation purposes. It appears that the water levels of the boreholes outside the mining boundaries are not affected. The water levels of the monthly monitored boreholes stabilized or even started recovering over the last few years. It also seems as though the larger streams in the area drains the groundwater as most of the deeper water level areas coincides with the presence of the streams. Most of the boreholes have typical borehole yields that is to be expected from Karoo formations i.e. between 0.5 and 1.5 L/s. An interesting observation is that a number of the boreholes with deep water levels are situated along dolerite contact zones at the western side of the mine. This may also be a geological structure resulting from the impact of a meteorite? From the available data it appears that the boreholes along this structure have the same chemical character as the water flowing down the ventilation shaft, strengthening the belief that the water from the shaft originates from this structure (or structures). To determine the origin of the water flowing down the ventilation shaft, a detailed study of the structure to the west of the shaft is recommended. The farmers in the area should carefully monitor their water use in the boreholes, as over-abstraction can result in total failure of some of the boreholes.
Variability In Borehole Responses During Yield Testing: Case Studies Deviating From Ideal Drawdown Curves.	Reuben	Lazarus	2019	yield-testing, theory vs practice, realistic aquifers
Abstract The expectation that during yield tests, a borehole will react within the expected framework of the existing numerical models, is often not met within real-world scenarios. This is mainly due to the observation that the Theis solution for confined aquifers, Neuman solution for unconfined aquifer and Barker Generalised Radial Flow Model for hydraulic tests in fractured rocks all include idealised assumptions regarding the physical aspects of a hypothetical. In order to interpret the data from a yield test these methods, along with the Flow Characteristic method for sustainable yield estimates, are commonly used. However, as these assumptions are not always met, the analysis is usually focused on time periods within the test that approximate these solutions. In some cases, the extent to which these assumptions are not met can produce drawdown data that is not well described by the usual analytical models used to analyse this data. This study addresses some of the shortcomings experienced during testing in non-ideal aquifers, as well as briefly describing some tests where small budgets, short deadlines, a lack of information and/or unforeseen circumstances resulted in similar challenges to analyses. This study does not present new solutions to drawdown data analyses, but rather discusses how the mentioned solutions were used during testing to accommodate for the shortcomings experienced.
Establishing A Groundwater Baseline For Unconventional Gas Projects In South Africa	M	Lourens	2017	Unconventional gas, hydraulic fracturing, Methodology, geological structures, baseline, Fracking
Abstract A standard methodology for establishing a groundwater baseline for unconventional gas projects in South Africa did not exist at the time the current study was undertaken. The study was therefore aimed at filling this gap, specifically focusing on hydraulic fracturing and underground coal gasification (UCG) operations. An extensive literature review was conducted to establish the baseline methodology. The latest literature on hydraulic fracturing and UCG was reviewed to determine how these activities may potentially impact on the groundwater environment. The literature review further examined the role that geological structures, such as dolerite intrusives, may be play in the migration of contaminants associated with unconventional gas projects. The literature review then focused on questions such as what size the study area should be, what geological and hydrogeological investigations need to be conducted before embarking on the sampling events, which chemical parameters need to be included in the groundwater analyses, whether the drilling of dedicated boreholes are required to collect representative groundwater samples, and how to collect representative samples for these different chemical parameters. In this paper, the proposed methodology is presented in the form of a flow diagram to be used to guide future groundwater baseline projects in South Africa.
Evaluating Groundwater Availability Based on Land Cover and Local Hydrogeology - A Groundwater Balance Approach	Hendrik	Botha	2019	land cover, water balance
Abstract The main purpose of this paper is to present a case study where a water balance concept was applied to describe the expected groundwater safe yield on a sub-catchment scale. The balance considers effective recharge based on local hydrogeology and land cover types, basic human needs, groundwater contribution to baseflow, existing abstraction and evaporation. Data is derived from public datasets, including the WRC 90 Water Resources of South Africa 2012 Study, 2013-2014 South African (SA) National Land Cover and Groundwater Resource Assessment Ver. 2 (GRAII) datasets. The result is an attempt to guide a new groundwater user regarding the volume of groundwater that can be abstracted sustainably over the long-term.
Ground Water Management in South Africa: Challenges and Constraints	Courage	Mlambo	2015
Abstract Water scarcity is a growing issue in South Africa. The consumption of water is rising and as such, water is becoming a scarce and valuable resource. Given the circumstances that South Africa is facing, improving the use of ground water could help tackle water scarcity in South Africa. Groundwater has been an important source of water and it can bring socio-economic benefits if properly used. Studies have proved that groundwater resources play a fundamental role in the security and sustainability of livelihoods and regional economies throughout the world. However, in South Africa, groundwater still remains a poorly managed resource and this hinders socio-economic development. This paper examines the current state of ground water management in South Africa. The paper also examines how ground water in South Africa is currently allocated and used, and explores some of the consequences of current water management arrangements. {List only- not presented}
The connectedness of transboundary groundwater researchers: from network analysis to network-building	A	Fernald	2023	network analysis, network-of-networks, transboundary groundwater
Abstract The Transboundary Groundwater Resilience (TGR) Network-of-Networks project brings together researchers from multiple countries to address the challenges of groundwater scarcity and continuing depletion. Improving groundwater resilience through international research collaborations and engaging professionals from hydrology, social science, data science, and related fields is a crucial strategy enabling better decision-making at the transboundary level. As a component of the underlying data infrastructure, the TGR project applies visual analytics and graph-theoretical approaches to explore the international academic network of transboundary groundwater research. This enables the identification of research clusters around specific topic areas within transboundary groundwater research, understanding how the network evolved over the years, and finding partners with matching or complementary research interests. Novel online software for analysing co-authorship networks, built on the online SuAVE (Survey Analysis via Visual Exploration, suave.sdsc.edu) visual analytics platform, will be demonstrated. The application uses OpenAlex, a new open-access bibliographic data source, to extract publications that mention transboundary aquifers or transboundary groundwater and automatically tag them with groundwater-specific keywords and names of studied aquifers. The analytics platform includes a series of data views and maps to help the user view the entire academic landscape of transboundary groundwater research, compute network fragmentation characteristics, focus on individual clusters or authors, view individual researchers’ profiles and publications, and determine their centrality and network role using betweenness, eigenvector centrality, key player fragmentation, and other network measures. This information helps guide the project’s data-driven international networking, making it more comprehensive and efficient.
Estimation of Groundwater Recharge Response from Rainfall Events in a Semi-Arid Fractured Aquifer: Case study	Phathutshedzo	Nemaxwi	2015
Abstract Estimating groundwater recharge response from rainfall remains a major challenge especially in arid and semi-arid areas where recharge is difficult to quantify because of uncertainties of hydraulic parameters and lack of historical data. In this study, Chloride Mass Balance (CMB) method and Extended model for Aquifer Recharge and soil moisture Transport through unsaturated Hardrock (EARTH) model were used to estimate groundwater recharge rates. Groundwater chemistry data was acquired from the Department of Water and Sanitation (DWS) and Global Project Management consultants, while groundwater samples were collected to fill-in the identified gaps. These were sent to Council for Geoscience laboratory for geochemical analysis. Rainfall samples were also collected and sent for geochemical analysis. An average value of rainfall chloride concentration, average groundwater chloride concentration and mean annual precipitation (MAP) were used to estimate recharge rate at a regional scale. Local scale recharge was also calculated using chloride concentration at each borehole. The results were integrated in ArcGIS software to develop a recharge distribution map of the entire area. For EARTH model, long term rainfall and groundwater levels data were acquired from the South Africa Weather Services and DWS, respectively. Soil samples were collected at selected sites and analysed. These were used to determine representative values of specific yield to use on EARTH model. 60% of the groundwater levels data for 5 boreholes was used for model calibration while the remaining 40% was used for model validation. The model performance was evaluated using coefficient of determination (R2), correlation coefficient (R), Root Mean Square Error (RMSE) and Mean square error (MSE). Regional recharge rates of 12.1 mm/a (equivalent to 1.84% of 656 mm/a MAP) and 30.1 mm/a (equivalent to 4.6% MAP) were calculated using rainfall chloride concentrations of 0.36 and 0.9 mg/L, respectively. The estimated local recharge rates ranged from 0.9-30.2 mm/a (0.14 - 4.6%) and 2 - 75 mm/a (0.3 - 11.4%) using chloride concentration of 0.9 and 0.36 mg/L, respectively. The average recharge rate estimated using EARTH model is 6.12% of the MAP (40.1 mm/a). CMB results were found to fall within the same range with those obtained in other studies within the vicinity of the study area. The results of EARTH model and CMB method were comparable. The computed R2, R, RMSE and MSE ranged from 0.47-0.87, 0.68-0.94, 0.04-0.34, 0.16-3.16, and 0.50-0.79, 0.68-0.89, 0.07-0.68, 0.15-8.78 for calibration and validation, respectively. This showed reasonable and acceptable model performance. The study found that there is poor response of groundwater levels during rainy season which is likely to be due to lack of preferential flows between surface water and groundwater systems. This has resulted in poor relationship between estimated and observed groundwater levels during rainfall season. Key words: ArcGIS, CMB, EARTH, Groundwater recharge, rainfall
Decision making with web-based geo-spatial databases coupled to groundwater models	John	Wise	2015
Abstract Model calibration and scenario evaluations of 2D and 3D groundwater simulations are often computationally expensive due to dense meshes and the high number of iterations required before finding acceptable results. Furthermore, due to the diversity of modelling scenarios, a standardised presentation of modelling results to a general audience is complicated by different levels of technical expertise. Reducing computational time In this presentation we look briefly at the use of Reduced Order Models (ROM's), which is one of the recent developments in groundwater modelling. The method allows significant speed-up times in model calibration and scenario evaluation studies. In saturated flow for example, these approaches show speed-up times of >1000 when compared to full models created with Finite Element of Finite Difference methods. These methods are demonstrated to a case study in the Table Mountain Group, in which we show a simplified parameter calibration and scenario evaluation study. Standardising presentation In order to present the results to as wide an audience as possible, the use of a web-browser as a GUI is proposed, where the web-page is coupled to a geo-spatial database and data is presented in a spatial and numeric format. The use of the spatial database manager PostgreSQL with PostGIS is proposed. Through a browser interface, users can run modelling scenarios using the ROM, which is evaluated in near real-time. Following the evaluation of the model, we show how PostGIS can spatially present data on a base-map such as google maps. In keeping with the current trends in online map customisation, viewers can interactively choose to overlay the base-map with a data-type (such as pressure or hydraulic head contours or flow direction) that is most intuitive for their level of familiarity with the data. Conclusion In using advanced modelling techniques and a simplified browser based presentation of results, high-level decisions in water resource management can be significantly accelerated with the use of interactive scenario evaluations. Furthermore, by reaching a broader audience, public participation will be significantly enhanced.
Comparative use of groundwater by invasive alien PROSOPIS SPP and co-occurring indigenous V. Karoo in a semi-arid catchment	Sebinasi	Dzikiti	2015
Abstract Groundwater is a vital source of water for many communities in South Africa and elsewhere. Besides the changing climate, rapidly spreading invasive alien plants with deep roots e.g. Prosopis spp, pose a serious threat to this water source. Dense impenetrable thickets of Prosopis occur in the drier parts of the country mainly along river channels in the Northern, Eastern and Western Cape Provinces. Few studies have quantified the actual water use by this species outside of the USA where it is native. Consequently the impacts of Prosopis invasions on groundwater resources are not well documented in South Africa. The aim of this study was to quantify the actual volumes of water used by Prosopis invasions and to establish the effects on groundwater. Because deep rooted indigenous trees that normally replace Prosopis once it has been cleared also use groundwater, we sought to quantify the incremental water use by Prosopis over and above that used by indigenous trees in order to determine the true impacts on groundwater. The study was conducted at a site densely invaded by Prosopis at Brandkop farm near the groundwater dependent town of Nieuwoudtville in the Northern Cape. One in seven trees at the site is the Vachellia karroo (formerly A. karroo) which is the dominant deep rooted indigenous tree species. Actual transpiration rates by five Prosopis and five V. karroo are being measured using the heat pulse velocity (HPV) sap flow technique. Additional HPV sensors were installed on the tap and lateral roots to study the water uptake dynamics of the trees. Groundwater levels are being monitored in four boreholes drilled across the site while sources of water used by the trees (i.e. whether soil or groundwater) is being determined using O/H stable isotopes. For similar size trees, V. karroo had higher transpiration rates than Prosopis because of the larger sapwood to heartwood ratio in V. karroo than in Prosopis. However, at the stand level Prosopis consumed significantly larger amounts of water than V. karroo. This is because Prosopis invasions had a much higher tree density than V. karroo. From August 2013 to July 2014, annual stand transpiration for Prosopis (~ 372 mm) was more than 4 times higher than that of V. karroo (~ 84 mm). Tree water uptake was correlated to changes in groundwater levels (R2 ~ 0.42) with groundwater abstractions of ~ 2600 m3/ha/y by Prosopis compared to ~ 610 m3/ha/y for V. karroo. In addition, Prosopis showed evidence of hydraulic redistribution of groundwater wherein groundwater was deposited in the shallow soil layers while V. karroo did not. Results of this study suggest that clearing of Prosopis to salvage groundwater should target dense stands while less dense stands should be prevented from getting dense. {List only- not presented}
Stampriet Transboundary Aquifer System	Kwazikwakhe	Majola	2015

Post Mining Aquifer Testing At A South African Coal Mine	Marnus	du Toit	2017	coal mine, dewatering, geochemistry, pumping test, analytical mocels
Abstract Mining site remnants are everlasting and impact the groundwater regime on a long term scale. An integrated approach to geoscience is necessary due to the complexity of nature and the unknown relationships that must be discovered to further the understanding of impacts on the natural environment. Furthermore, groundwater resources are negatively impacted by mining activities affecting the groundwater quality and quantity. Underground coal mining can be accompanied by roof failure events. This may change the matrix which subsequently alters the flow regime; leads to variations within the water chemistry, provided there is inter- aquifer connectivity; and alters the recharge rate. Dewatered mine voids are in direct contact with oxygen initiating oxidation reactions, depending on the geology of the specific site. A change in water chemistry was analyzed, and this coincides with a roof failure event as interpreted from water level measurements. Concentrations of Mg, Ca, and alkalinity indicate anomalous changes that are still in effect, five to six years after the majority of water levels had stabilized. The changes in the system coincides with and correlates to events of roof failure and different parameters. The latter changes are applied as extra tools when interpreting different site specific anthropogenic induced impacts on the system. Also within this study, constant rate pumping tests were conducted for the interest of the hydraulic properties, using three farming boreholes. The results put forward a range of 0.21 – 0.44L/s and 6.5 – 11.5m2 /d, for sustainable yield and transmissivity, respectively. Furthermore, it is recommended that a better understanding can be gained on system behaviors if chemistry correlations can be gathered through certain events causing specific systems to be in disequilibrium. It is also recommended that additional pumping tests will allow more insightful interpretation and delineation between the abovementioned chemical and water level changes. Finally, the combination of parameters during events can aid in deciding the most appropriate analytical models used for further analysis.
High Resolution Site Characterisation Assessment Of A Chlorinated Solvent Plume In A Shallow Unconfined Aquifer	Kate	Naude	2015
Abstract Identifying and characterising the vertical and horizontal extent of chlorinated volatile organic compound (CVOC) plumes can be a complex undertaking and subject to a high degree of uncertainty as dense non-aqueous phase liquid (DNAPL) movement in the subsurface is governed most notably by geologic heterogeneities. These heterogeneities influence hydraulic conductivity allowing for preferential flow in areas of higher conductivity and potential pooling or accumulation in areas of lower conductivity. This coupled with the density-induced sinking behaviour of DNAPL itself and the effects of groundwater recharge in the aquifer result in significant challenges in assessing the distribution and extent of CVOC plumes in the subsurface. It has been recognized that high resolution site characterization (HRSC) can provide the necessary level of information to allow for appropriate solutions to be implemented to mitigate the effects of subsurface contamination. Although the initial cost of HRSC is higher, the long-term costs can be substantially reduced and the remedial benefits far greater by obtaining a better understanding of the plume characteristics upfront. The authors will discuss a case study site in South Africa, where ERM has conducted HRSC of a CVOC plume to characterise the distribution of the source area and plume architecture in order to assess the potential risk to receptors on and off-site. The source of impact resulted from the use of a tetrachloroethene (PCE)-based solvent in an on-site workshop. The following methods of characterization were employed: - Conducting a passive soil gas survey to identify and characterise potential source zones and groundwater impacts; - Vertical characterisation of the hydrostratigraphy, contaminant distribution and speciation in real time using a Waterloo Advanced Profiling System (APS) with a mobile on-site laboratory; - Using the Waterloo APS data to design and install groundwater monitoring wells to delineate the vertical and lateral extent of contamination; and - Conducting a vapour intrusion investigation including sub-slab soil gas, indoor and outdoor air sampling to estimate current risk to on-site employees. In less than a year, the risk at the site is now largely understood and the strategies for mitigating the effects of the contamination can be targeted and optimised based on the information gained during the HRSC assessment.
Transport and attenuation of microplastics in saturated sands	Sabastian	Stenzl	2021	Microplastics
Abstract Globally, cumulative plastic production since 1950 is estimated to have reached 2500 Mt of plastic. It is estimated up 60% of this plastic is either resting in landfills or the natural environment, including groundwater settings. Microplastics are small pieces of plastic ranging between 1μm – 5mm in size and have been found in every ecosystem and environment on the planet. Much of the available literature on microplastics is focused on marine environments with few in comparison focused on freshwater environments, and even fewer on groundwater settings. The aim of this study is therefore to investigate the attenuation process responsible for influencing microplastic transport in saturated sands. This research will adapt colloid transport theory and experiments to better understand the movement of microplastics through sandy media. Saturated aquifer conditions will be set up and simulated using modified Darcy column experiments adapted from Freeze & Cherry (1979). Modified microplastics will be injected into the columns as tracers and the effluent concentrations measured by Fourier-transform infrared spectroscopy (FTIR). Breakthrough curves will then be plotted using the effluent concentrations to determine the attachment efficiency (α). It is expected the attachment efficiency will vary by microplastic type and size range. The Ionic strength of the solution flowing through the column and the surface charges of both microplastics and sandy surfaces are likely to influence the degree of attenuation observed. The relationship between different types of microplastics and collector surfaces from a charge perspective and their influence on the degree of attenuation will be evaluated. Given the lack of literature, its ubiquitous presence and postulated effects on human health, this research is significant. Through this research, the transport and attenuation of microplastics through sandy aquifers can be better understood, and in the process inform future research and water resource management.
The use Vegetable Oil Substrate's in the treatment of contaminated groundwater	Michelle	Pienaar	2015
Abstract Edible vegetable oil (EVO) substrates have been successfully used to stimulate the in situ anaerobic biodegradation of groundwater contaminated chlorinated solvents as well as numerous other anaerobically biodegradable contaminants like nitrates and perchlorates at a many commercial, industrial and military sites throughout the United States of America and Europe. EVO substrates are classified as a slow release fluid substrate, and comprise of food grade vegetable oil such as canola or soya bean oil. The EVO substrate serves as an easily biodegradable source of carbon (energy) used to create a geochemically favorable environment for the anaerobic microbial communities to degrade specific contaminants of concern. EVO substrate's can either be introduced into the subsurface environment as pure oil, in the form of light non aqueous phase or as an oil/water emulsion. The emulsified vegetable oil substrates holds several benefits over non-emulsified vegetable oil as the fine oil droplet size of the commercially manufactured emulsified oils can more easily penetrate the heterogeneous pore and fracture spaces of the aquifer matrix. The use of this technology to stimulate in situ biodegradation of groundwater contaminants is still relatively unknown in South Africa. This paper will give an overview of the EVO technology and its application, specifically looking at the advantages of using this relatively inexpensive, innocuous substrate based technology to remediate contaminated groundwater within fractured rock environments commonly encountered in South Africa. {List only- not presented}
Groundwater Assessment using Borehole Magnetic Resonance	Benjamin	Birt	2019	magnetic resonance
Abstract Hydraulic behaviour of an aquifer is defined in terms of the volumes of water present, both producible and not (specific yield and specific retention), and the productivity of the water (hydraulic conductivity). These parameters are typically evaluated using pumping tests, which provide zonal average properties, or more rarely on core samples, which provide discrete point measurements. Both methods can be costly and time-consuming, potentially limiting the amount of characterisation that can be conducted on a given project, and a significant measurement scale difference exists between the two. Borehole magnetic resonance has been applied in the oil and gas industry for the evaluation of bound and free fluid volumes, analogous to specific retention and specific yield, and permeability, analogous to hydraulic conductivity, for over twenty years. These quantities are evaluated continuously, allowing for cost-effective characterisation, and at a measurement scale that is intermediate between that of core and pumping tests, providing a convenient framework for the integration of all measurements. The role of borehole magnetic resonance measurements in hydrogeological characterisation is illustrated as part of a larger hydrogeological study of aquifer modeling. Borehole magnetic resonance has been used for aquifer and aquitard identification, and to provide continuous estimates of hydraulic properties. These results have been compared and reconciled with pumping test and core data, considering the scale differences between measurements. Finally, an integrated hydrogeological description of the target rock units has been developed.
#GWD: The use of social media for science communication	Tercia	Strydom	2015
Abstract For a long time, professionals regarded social media as a superficial, unprofessional platform where internet users would submerge themselves in a virtual world, detached from real-life issues. Slowly, the myths and stigmas surrounding the use of social media has faded as more and more professionals and scientists have realized that these social platforms could be positively exploited in a professional manner which could be beneficial. In a digital age where information at our fingertips is the norm, professionals should co-evolve and ensure that their work is just as accessible and appealing, without the unnecessary jargon. Currently, science is mostly restricted to a very particular audience and conveyed in one direction only. Using a social media platform such as Twitter-which limits messages to only 140 characters-challenges scientists to convey their work in a very concise manner using simpler terminology. Furthermore, it dismisses the usual one-way form of communication by opening dialogue with fellow Twitter users. At conferences, Twitter can serve as a useful tool for active engagement which will not only "break the ice" between delegates but also ensure that important information is communicated to a much wider audience than only those in attendance. This idea was tested at the 2014 Savanna Science Network Meeting held in Skukuza, Kruger National Park, where the hashtag #SSNM was used. More than 63% of the Twitter users who participated in the #SSNM hashtag were actually not present at the conference. These external "delegates" were interested individuals from five different continents and in different professions besides Science. This highlights how social media can be exploited at conferences to ensure that key messages are conveyed beyond the immediate audience at the event.
Characterising surface water-groundwater interactions in the Vo?lvlei (Agulhas Plain), using a multi-disciplinary approach	Nabuweya	Noordien	2015
Abstract Coastal wetlands are complex hydrogeological systems in which groundwater have a significant influence on both its water balance and hydrochemistry. Differences in groundwater flow and groundwater chemistry associated with complex hydrogeologic settings have been shown to affect the diversity and composition of plant communities in wetland systems. A number of wetlands can be found across the flat terrain of the Agulhas Plain, of which the most notable is the Soetendalsvlei and the Vo?lvlei. Despite the ecological and social importance of the Vo?lvlei, the extent to which local, intermediate and regional groundwater flow systems influences the Vo?lvlei is poorly understood. The aim of this work is to characterize the spatial and temporal variations in surface water and groundwater interactions in order to demonstrate the influence of groundwater flow systems on the hydrology of the Vo?lvlei. The specific objectives of the study are; 1) to establish a geological framework of the lake sub-surface, 2) to determine the physical hydrological characteristics of the Vo?lvlei and 3) to determine the physical-chemical and isotopic characteristics of groundwater and surface water. Data collection will be done over the period of a year. Methods to be used will include the use of geophysical (electrical resistivity) to determine high water bearing areas surrounding the wetland, a drilling investigation (the installation of piezometers at 5-10m depths and boreholes at 30m depth, sediment analysis (grain size analysis, colour and texture), hydraulic (slug testing to determine hydraulic properties; hydraulic conductivity and transmissivity), hydrological (to estimate groundwater discharge; Darcy flux and hydraulic head difference between groundwater level and lake level), physical-chemical (electrical conductivity, temperature and pH) and stable environmental isotopic (oxygen and hydrogen) analysis of surface water and groundwater, to determine flow paths and identify processes. Thus far, results obtained for the geophysical survey has revealed that the sub-surface of this wetland system is highly variable. Three traverses were done on the South-Western, South-Eastern and Northern side of the wetland (See Figure 1). In VOEL1 (South west), the upper couple of meters show areas of very low resistivity, which is associated with clays, poor water quality and water which has high dissolved salts. The changing of medium to high resistivity values on the North-eastern side is usually indicative of weathered sandstone (Table Mountain Group). VOEL2 (South eastern), indicates that the subsurface is of low resistivity. These low values are the result of noticeable salt grains in the sand. VOEL3 (Northern), indicated upper layers of low resistivity, while the lower depth indicate areas of high resistivity. It is expected that the results of this study will provide a conceptual understanding of surface water-groundwater interactions and the processes which control these interactions, in order to facilitate the effective management and conservation of this unique lacustrine wetland.
Hydraulic tests of strong artesian boreholes; wellhead construction and test design	Kornelius	Riemann	2015
Abstract Artesian boreholes are a common feature worldwide in confined aquifers, but the hydraulic testing of these boreholes, and estimation of aquifer properties from such tests, still poses a challenge for hydrogeologists. Common hydraulic tests, such as step-drawdown or constant-discharge rate tests require a static water level at the start of the test, and the measurement of drawdown (increasing over time) and abstraction rate (fixed for a period of time). Usually, when undertaking a pumping test in an artesian borehole, the drawdown is measured from ground level, and the drop in hydraulic head between static pressure and ground level is often ignored. This procedure also implies that the starting time of the test is not at the static water level. A constant-head test, set at ground level, is the other option. However, the decrease in flow rate is not only dependent on the hydraulic properties of the aquifer, but also masked by pipe hydraulic effects within the well. This kind of test would also limit the available drawdown to be utilized for the test. Hence, it was required to develop a method for undertaking hydraulic tests in strong artesian boreholes, allowing for the drawdown to fluctuate between levels both above and below ground and avoiding the pitfalls described above. The solution is a specially designed and constructed wellhead for the installation of the pump and monitoring equipment prior to the hydraulic test. The standard tests are slightly modified and are only undertaken after sealing the wellhead and reaching static hydraulic pressure. The recommended wellhead construction and subsequent hydraulic tests were implemented at a strong artesian borehole in the Blossoms Wellfield, south of Oudtshoorn in the Western Cape province of South Africa.
Estimating groundwater availability at catchment scale using streamflow recession and instream flow requirements of rivers	Girma Yimer	Ebrahim	2015	streamflow, RDM
Abstract Groundwater is an important resource for multiple uses in South Africa. Hence, setting limits to its sustainable abstraction while assuring basic human needs is required. Due to prevalent data scarcity related to groundwater replenishment, which is the traditional basis for estimating groundwater availability, the present article presents a novel method for determining allocatable groundwater in quaternary catchments through information on streamflow. Using established methodologies for assessing baseflow, recession flow, and instream ecological flow requirement, the methodology develops a combined stepwise methodology to determine annual groundwater storage volume using linear reservoir theory, essentially linking low flows proportionally to upstream groundwater storages. The approach was trialled for twenty-one perennial and relatively undisturbed quaternary catchments with longterm and reliable streamflow records. Using the Desktop Reserve Model, maintenance low instream flow requirements necessary to meet present ecological state of the streams were determined, and baseflows in excess of these flows were converted into allocatable groundwater storages on an annual basis. Results show that groundwater development potential exists in nineteen of the catchments, with upper limits to allocatable groundwater volumes (including present uses) ranging from 0.02 to 2.60 Mm3/a over the catchments. With a secured availability of these volumes 75% of the years, variability between years is assumed to be manageable. A significant (R2 = 0.86) correlation between baseflow index and the drainage time scale for the catchments underscores the physical basis of the methodology and also enables the reduction of the procedure by one step, omitting recession flow analysis. The method serves as an important complementary tool for the assessment of the groundwater part of the Reserve and the Groundwater Resource Directed Measures in South Africa.
Starting From The Problem And Working Backwards	John	Doherty	2019	model calibration, decision-support
Abstract Many groundwater models are commissioned and built under the premise that real world systems can be accurately simulated on a computer - especially if the simulator has been "calibrated" against historical behavior of that system. This premise ignores the fact that natural processes are complex at every level, and that the properties of systems that host them are heterogeneous at every scale. Models are, in fact, defective simulators of natural processes. Furthermore, the information content of datasets against which they are calibrated is generally low. The laws of uncertainty tell us that a model cannot tell us what will happen in the future. It can only tell us what will NOT happen in the future. The ability of a model to accomplish even this task is compromised by a myriad of imperfections that accompany all attempts to simulate natural systems, regardless of the superficial complexity with which a model is endowed. This does not preclude the use of groundwater models in decision-support. However it does require smarter use of models than that which prevails at the present time. It is argued that, as an industry, we need to lift our game as far as decision-support modeling is concerned. We must learn to consider models as receptacles for environmental information rather than as simulators of environmental systems. At the same time, we must acknowledge the defective nature of models as simulators of natural processes, and refrain from deploying them in a way that assumes simulation integrity. We must foster the development of modelling strategies that encapsulate prediction-specific complexity supported by complexity-enabling simplicity. Lastly, modelers must be educated in the mathematics and practice of inversion, uncertainty analysis, data processing, management optimization, and other numerical methodologies so that they can design and implement modeling strategies that process environmental data in the service of optimal environmental management.
Questions Of Scale And Measurements	Nicolette	Vermaak	2019	scale
Abstract Until 1998 groundwater was managed separately from surface water and was seen as a private resource. The National Water Act of 1998 (Act 36 of 1998) (NWA) was forward thinking in that it saw groundwater as an integrated part of the water resource system and as a common resource to be managed by the Department of Water and Sanitation (DWS) as custodian. Various tools had been provided to manage the water resources equitably, sustainably and efficiently. A limited understanding of groundwater and the prevalence to revert to engineering principles when managing water resources had led to an Act that is mostly written with surface water in mind. The tools and principles that had been tested for surface water was used directly for groundwater without considering the practicalities in applying and enforcing the NWA. This did not provide too many problems, as groundwater was not considered a viable, sustainable water resource, and the use of groundwater was mostly limited to private use for garden irrigation, in agriculture for irrigation and for bulk supply in a number of small towns where surface water was not available. This has changed drastically during the recent drought that affected the whole country, but especially the Western Cape. Groundwater was suddenly seen as the solution to the problem of water availability. The problem was that the understanding of groundwater has not increase sufficiently over the years, and water resources management is still skewed to hydrology principles that apply to surface water. Groundwater sustainability is at the heart of the questions of scale and measurements. The Department has been flooded by the large number of water use licence applications that have been submitted by municipalities, industries and agriculture as a result of the drought. This article will look at groundwater resource assessment and allocation methodology in a South African context.
Review of Groundwater Use in Varying Climatic Conditions	Lindelani	Lalumbe	2019	Poster, Climate
Abstract Groundwater levels in E33F quaternary catchment are at their lowest level ever. The impact of climatic variation and increasing abstraction were determined to be the main factor. There are 115 registered groundwater users in E33F and the monthly abstraction volumes are not being measured. There is a need to use land use activities as well as the population to estimate groundwater use. The main objective is to use non-groundwater monitoring data to estimate groundwater use in order to protect the aquifer and ecosystem in general in varying climatic condition. Land use activities information was used to estimate groundwater use in E33F quaternary catchment. The estimated groundwater use volumes were compared to allocated and measured volumes. For domestic groundwater use estimation, population data and an estimation 100 litre per person per day were used. The water requirements for the types of crops being cultivated together with the area (m2) were used to estimate groundwater use volumes for irrigation. The number and type of live stocks were used with the water requirements for each livestock type to estimate the groundwater use volumes. 96 % of groundwater users are using groundwater for irrigation purposes with 9 966 105 m3/a allocated for irrigation. Mining, industries, domestic and livestock are allocated 100 200 m3/a. The estimated groundwater use volume for irrigation is 30 960 000 m3/a, which is three times higher than the allocated volume. Groundwater use volume for domestic use is estimated to be 38 225 m3/a which is higher than the 31 000 m3/a allocated. The total estimated groundwater use volume in E33F is estimated to be 30 998 225 m3/a, which is three times higher than the allocated groundwater use volume of 10 066 305 m3/a. This estimation could be higher as only registered boreholes were used and estimations from mining, Industries and live stocks were excluded due to lack of data
The National State of Water in South Africa - the Annual Reporting	Kwazikwakhe	Majola	2015
Abstract POSTER The Department of Water and Sanitation (DWS) is the custodian of South Africa's water and thus is imperative that it reports on its state as the National Water Act of 1998 requires regular reporting to Parliament by the Minister. Hence, the annual compilation of report entitled "The National State of Water in South Africa." This report aims to give an overview of the status and trends of water quality and quantity, further assisting with international water reporting obligations to SADC Region, African Continent, and Globally e.g. the United Nations Commission on Sustainable Development. This information empowers the public and provides knowledge to water managers for informed decision-making. The main purpose is to enhance quality, accessibility and relevance of data and information relating to the goal of Integrated Water Resource Management towards attaining holistic Integrated Water Management, and Integrated Water Cycle Management in future. Three distinct requirements for collecting data by DWS are: (i) assessing and comparing the status and trends for both quantity and quality; (ii) monitoring for water use and (iii) monitoring for compliance to licence conditions. Such information is further used to assess the effectiveness of policies implemented and identify the existing gaps. Various challenges to the country's water demand proper integrated water resources planning and management. The report is divided into Themes such as, Resource Management, Water Services/Delivery, Water Development and Finance, based on selected indicators. The indicators are strategically selected to provide a representative picture of the state, as well as the changes over time to the drivers, pressures, impacts and responses related to the chosen themes. These Indicators include: Climatic Conditions, Water Availability, Water Use, Water Protection, Water Quality, Water Service Delivery, Water Infrastructure, Water Finance, and Sanitation. The report for Hydrological Year 2013/2014 has been completed and it shows that the amount of water available varies greatly between different places and seasons, and from one year to another. The average total storage was around 85% of full supply capacity in September 2014. Surface water quality is generally facing a threat from eutrophication and microbial pollution emanating mainly from mismanaged water (and waste) treatment plants and related landuse activities. Groundwater quality is generally good except in some localised areas where mining and industrial activities are prevalent. With regards to infrastructure; vandalism, lack of maintenance & management skills reflect on/as non-revenue water, highlighting the need for more funding towards maintenance, especially in groundwater which is normally wrongly deemed as an unreliable resource. In the past 20 years, water services delivery to communities has improved as the Millennium Development Goals have been met and surpassed, while the sanitation access goals were likely to be met.
Characterising The Hydrological Regime Of The Rietvlei Wetland: Implications For Ecohydrology	Nathasha R	Gariremo	2019	Poster, ecohydrology
Abstract In the following study, the soil and groundwater regime of the Rietvlei wetland near Cape Town are characterised. This has been done by means of logging the subsurface material during the construction of 8 shallow wells, complimented with field observations, and surveying the dug wells. The water stemming from these wells was sampled and analysed for Oxygen 18 and Deterium. Downhole salinity logs of the wells were also undertaken and rainfall samples were analysed for the aforementioned stable isotopes. Results indicate a distinct relationship between elevation and soil structure. Through the use of the water table method, it was found that the relationship between elevation and soil moisture had a direct impact on spatially distributed groundwater recharge on an event basis. Furthermore, higher salinities were found with depth in groundwater in the same wells which had higher recharge values. Isotopic results indicate that groundwater all stems from rainfall, with the exception of Well 8 is influenced by the river due to its proximity to the surface water body. The various water chemistries and soil profiles have a direct impact on the type of flora and its distribution throughout the study area. This study managed to conceptualize the relationship between groundwater, soil profiles and the various plant types surviving in the Rietvlei wetland. Future studies can focus on computer based approaches in order to predict how changes in groundwater characteristics caused by natural or anthropogenic factors would affect other ecohydrological processes within the wetland. These findings can be incorporated in decision making processes concerning groundwater management.
Governance and Management of Water Resource in the SA Context - A Review	Kornelius	Riemann	2015
Abstract Water management is a difficult and complex business requiring appropriate institutional arrangements as well as guidance and support from government, which is often unable to act effectively to address day-to-day water resource management (WRM) issues. Theoretically, water as a 'common pool resource' is best managed by users self-organised at a local level and within a basin framework. Water users and other stakeholders have detailed and up-to-date local knowledge as well as an interest in ensuring effective management to share water equitably between different users and to control pollution. This approach is supported by South Africa's National Water Act (NWA), which provides for the establishment of Catchment Management Agencies (CMAs) to perform a range of WRM activities within the framework of a National Water Resource Strategy (NWRS). Hence, water resource management in general and conjunctive use in particular requires cross sector and cross level cooperative governance. Relevant institutions include the DWA at national and regional level, the CMA, if established, provincial departments that might impact on the water resources, water user associations, water services authorities, water services providers, water boards, and individual water users. These institutions are responsible for various activities and often require some level of inter- and intra-institutional cooperation. Ideally, multiple organisations, policies, legislation, plans, strategies and perspectives should be involved in water-related decision-making, which in turns creates complex leadership challenges. Globally, the lack of sustainable groundwater management can be ascribed to poor governance provisions. These include, but are not limited to, institutional arrangements and political will, including fragmented and overlapping jurisdictions and responsibilities, competing priorities, traditional approaches, rights and water pricing systems, diverging opinions, incomplete knowledge, data as well as uncoordinated information systems. Adding the poor operational and maintenance issues, decision-makers often view groundwater as an unreliable resource and are hesitant to make significant investments in groundwater infrastructure and capacity. The recent Worldbank and WRC report on groundwater governance in South Africa revealed that the technical, legal, institutional and operational governance provisions were found to be reasonable at the national level but weak concerning cross-sector policy coordination. At the local level, basic technical provisions such as hydrogeological maps and aquifer delineation with classified typology are in place but other governance provisions such as institutional capacity, provisions to control groundwater abstraction and pollution, cross-sector policy coordination and the existence and implementation of groundwater management action plans are weak or non-existent. It appears from this review that the major hindrances for sustainable groundwater governance and more so for integrated water resource management and conjunctive use scenarios are the discrepancy between groundwater and surface water provisions in the relevant legislation, associated guidelines and their implementation at regional and local, and the lack of skills and clear responsibilities for implementing water resource management actions at municipal level. This is demonstrated with several case studies.
A methodology for uncertainty quantification of dewatering volumes under the context of open-cast mining	C	Rivera Villarreyes	2023	FEFLOW, Groundwater Modelling, mining, PEST, PESTPP
Abstract Groundwater modelling at the mine sites involves assumptions from the geological model, mining stages, parametrization, and fractures, among others. Modelling work mainly focuses on calibrating against historical measurements before operations (pre-mining) or afterwards (transient calibration). Calibration is carried out mainly with gradient-based algorithms. However, the majorlimitation is the number of model runs, since the number of parameters can easily reach hundreds or more. PEST has become the common tool for parameter estimation. The Jacobin calculation required for the Levenberg Marquardt algorithm requires several model runs. This, a limited factor for the calibration and, subsequently, uncertainty quantification. The next generation of PEST, named PESTPP, is gained popularity in the groundwater community. The great advantage of PESTPP,, compared to the classical PEST, is its new module, Iterative Ensemble Smoother (IES). PESTPP-IES covers both parameter estimation and uncertainty quantification in one goal. Its empirical formulation of the Jacobian matrix reduces the number of runs; thus, the numerical bottleneck can be significantly reduced. PESTPP-IES has been extensively tested in an open-pit mine at the geological complex conditions in the Peruvian Andes. The work involves the task of model simplification, e.g., from a regional model to a detailed local pit model, calibration and uncertainty quantification of pit dewatering volumes. Detailed model was kept calibrated based on hydraulic-head measurements, and dewatering volumes were predicted. All these consider transient changes in the mining plan within the same FEFLOW model. Results validate the methodology and practicability in mining applications.
Hydrogeochemical processes in the shallow aquifer of the Lubumbashi river basin: multivariate statistical approach	Antoine	Lumu Moussa	2015
Abstract Understanding the hydrogeochemical processes that govern groundwater quality is important for sustainable management of the water resource. A study with the objective of identifying the hydrogeochemical processes and their relation with existing quality of groundwater was carried processes in the shallow aquifer of the Lubumbashi river basin. The study approach includes conventional graphical plots and multivariate analysis of the hydrochemical data to define the geochemical evaluation of aquifer system based on the ionic constituents, water types, hydrochemical facies and groundwater factors quality control. Water presents a spatial variability of chemical facies (HCO3- - Ca2+ - Mg2+, Cl- - Na+ + K+, Cl- - Ca2+ - Mg2+ , HCO3- - Na+ + K+ ) which is in relation to their interaction with the geological formation of the basin. The results suggest that different natural hydrogeochemical processes like simple dissolution, mixing, and ion exchange are the key factors. Limited reverse ion exchange has been noticed at few locations of the study. At most, factor analyses substantiate the findings of conventional graphical plots and provide greater confidence in data-interpretation. {List only- not presented}
Water resource management in tectonically active volcanic regions: Towards an in-depth understanding of Mt. Fuji’s hydrogeology	Stephanie	Musy	2023	SW-GW interactions; tracers; modelling
Abstract Mt. Fuji is the iconic centrepiece of a large, tectonically active volcanic watershed (100 km2 ), which plays a vital role in supplying safe drinking water to millions of people through groundwater and numerous freshwater springs. Situated at the top of the sole known continental triple-trench junction, the Fuji watershed experiences significant tectonic instability and pictures complex geology. Recently, the conventional understanding of Mt. Fuji catchment being conceptually simple, laminar groundwater flow system with three isolated aquifers was challenged: the combined use of noble gases, vanadium, and microbial eDNA as measured in different waters around Fuji revealed the presence of substantial deep groundwater water upwelling along Japan’s tectonically most active fault system, the Fujikawa Kako Fault Zone [1]. These findings call for even deeper investigations of the hydrogeology and the mixing dynamics within large-scale volcanic watersheds, typically characterized by complex geologies and extensive networks of fractures and faults. In our current study, we approach these questions by integrating existing and emerging methodologies, such as continuous, high-resolution monitoring of dissolved gases (GE-MIMS [2]) and microbes [3], eDNA, trace elements, and integrated 3-D hydrogeological modelling [4]. The collected tracer time series and hydraulic and seismic observations are used to develop an integrated SW-GW flow model of the Mt. Fuji watershed. Climate change projections will further inform predictive modelling and facilitate the design of resilient and sustainable water resource management strategies in tectonically active volcanic regions
Investigating the impact of fertilizer spills on groundwater quality	Jacobus Wilhelmus	Haumann	2015
Abstract A groundwater assessment was conducted to identify and predict the contamination and transport properties of a groundwater system. The motivation for the study was the rising concern of a farm owner about the deteriorating water quality of the aquifer system. An investigation of the surface and groundwater quality indicated that two fertilizer dumpsites were the sources of pollution. Water analyses revealed elevated concentrations of Ca, Mg, K, F, NO3, SO4, Mn and NH4 within boreholes near the pollution sources. The NH4 and NO3 concentrations were exceptionally high: 11 941 mg/L and 12 689 mg/L, respectively. These high concentrations were the direct result of the dumping of fertilizer. The rise in these concentrations may also have been catalysed by the nitrogen cycle and the presence of the Nitrosomonas bacterium species. Due to the high solubility of NO3, and because soils are largely unable to retain anions, NO3 may enter groundwater with ease, and could migrate over large distances from the source. Elevated NO3 in groundwater is a concern for drinking water because it can interfere with blood-oxygen levels in infants and cause methemoglobinemia (blue-baby syndrome). A geophysical study was undertaken within the area of investigation to gain insight on the underlying geological structures. The survey indicated preferential flow paths within the aquifer system along which rapid transport of contaminant is likely to occur. Key words: aquifer system, groundwater quality analyses, fertilizer, nitrogen cycle, Nitrosomonas species, geophysics.
Determination Of Water Retention For Ash Dumps And Implications On Groundwater Contamination	Gundo	Mathoho	2019	contamination
Abstract Burning of coal for electricity production has resulted in vast amounts of ash being deposited in ash dumps. Rain water and ash water conditioning results in the wetting of ash dumps and if the water retention capacity is exceeded there is a possibility of leaching to soil and underlying aquifers. In this study two different coal ash are used to determine the water retention as excess amount of process water at power stations ash dumps can lead to impeding the desired water balance, which can be critical for maintain various plant processes. The nonlinear relationship between soil water content and matrix suction of a porous material under unsaturated conditions is described by the soil water characteristic curve (SWCC). The SWCC for a given material represents the water storage capability enabling the determination of varying matric suction such as prediction of important unsaturated hydraulic processes including soil permeability, shear strength, volume change with respect to the water content changes. This paper presents an alternative, cost effective and rapid method for measuring and subsequent estimating of the soil-water characteristics of any soil type. Several methods are available to obtain the measurements required for defining soil-water characteristics. However, obtaining the required measurements for a SWCC is generally difficult since there is no laboratory or field instrument, capable of measuring a typical complete plant available water suction range accurately. Due to high methodological effort and associated costs of other methods, a simplified evaporation method which was implemented in the HYPROP (Hydraulic Property analyzer, UMS, 2012) becomes a possible alternative. It relies on the evaporation method initially proposed Schindler (1980). A typical work range for a HYPROP system is 0 to 100 KPa as read out from the two high capacity tensiometers installed at different heights within a saturated sample column. For a dry coal ash dump to be optimally used as sinks, input water applications should be matched with evaporation rates and capillary storage. This will ensure the moisture storage of the ash dump is not exceeded and consequently avert leachate generation at the base of the ash dump. The field capacity of waste materials is of critical importance in determining the formation of leachate in landfills which in this case is the coal ash dump facility. It is the field capacity limit when exceeded which give rise to leachate generation consequently promoting a downward movement of generated leachate.he study found that it is possible to use the Hyprop together with an empirical based fitting model to define a complete SWCC along a dewatering path. The study found the Brooks-Corey model as the suitable representative of the Hyprop measured data, confirmed by AICc and RMSE analysis. The Brooks-Corey estimated retention function parameters within +/- 1% error. A mean value of 35.3% was determined as the water retention or field capacity value for Matimba Coal ash. If the ash dump is operated in excess of this value, chances of groundwater pollution are high.
Numerical Modelling Of a Coal Mine to Improve the Understanding of Mine Water Decant: A 1000-Piece Puzzle	Amy	Allwright	2017	coal ash, dolomites, Mining , numerical modelling
Abstract A coal mine in South Africa had reached decant levels after mine flooding, where suspected mine water was discharging on the ground surface. Initial investigations had indicted a low-risk of decant, but when ash-backfilling was performed in the defunct underground mine, decant occurred. Ash-backfilling was immediately suspended as it was thought to have over-pressurised the system and caused decant. Contrariwise, a number of years later decant was still occurring even though ash-backfilling had been terminated. An investigation was launched to determine whether it was the ash-backfilling which had solely caused decant, or if additional contributing factors existed. Understanding the mine water decant is further complicated by the presence of underlying dolomites which when intersected during mining produced significant inflows into the underground mine workings. Furthermore, substantial subsidence has taken place over the underground mine area. These factors combined with the inherent difficulty of understanding unseen groundwater, produced a proverbial 1000-piece puzzle. Numerical groundwater modelling was a natural choice for evaluating the complex system of inter-related processes. A pre-mining model simulated the water table at the ground surface near the currently decanting area, suggesting this area was naturally susceptible for seepage conditions. The formation of a pathway from the mine to the ground surface combined with the natural susceptibility of the system may have resulted in the mine water decant. This hypothesis advocates that mine water was going to decant in this area, regardless of ash backfilling. The numerical groundwater flow model builds a case for this hypothesis from 1) the simulated upward flow in the pre-mining model and 2) the groundwater level is simulated above the surface near the currently decanting area. A mining model was then utilised to run four scenarios, investigating the flux from the dolomites, subsidence, ash-backfilling and a fault within the opencast mine. The ash-backfilling scenario model results led to the formation of the hypothesis that completing the ash-backfilling could potentially reduce the current decant volumes, which is seemingly counterintuitive. The numerical model suggested that the current ash-backfill areas reduce the groundwater velocity and could potentially reduce the decant volumes; in spite of its initial contribution to the mine water decant which is attributed to incorrect water abstraction methods. In conclusion, the application of numerical models to improve the understanding of complex systems is essential, because the result of interactions within a complex system are not intuitive and in many cases require mathematical simulation to be fully understood.
A Study Of Interaction Between Groundwater And Surface Water Using Environmental Isotopes, Hydrochemistry And Feacal Coliform BA	Bongizenzo	Nyawo	2015
Abstract The Table Mountain Group (TMG) Formation in the Uitenhage region, in the Eastern Province of South Africa, has many groundwater users, which could result in the over-exploitation of the underlying aquifer. Consequently, several investigations have been conducted to help in the planning and management of groundwater resources within the region. Traditionally, these investigations have considered groundwater and surface water as separate entities, and have been investigated separately. Environmental isotopes, hydrochemistry and feacal colifom bacteria techniques have proved to be useful in the formulation of interrelationships and for the understanding of groundwater and surface water interaction. The field survey and sampling of the springs, Swartkops River and the surrounding boreholes in the Uitenhage area have been conducted. After full analysis of the study, it is anticipated that the data from the spring, Swartkops River and the surrounding boreholes show interannual variation in the isotope values, indicating large variation in the degree of mixing, as well as to determine the origin and circulation time of different water bodies. ?D and ?18O value for the spring ranges from ?18.9? to ?7.4?, and 5.25? to 4.82?, respectively, while ?D values for borehole samples range from ?23.5? to ?20.0? and ?18O values range from ?5.67? to ?5.06?. In the river sample, ?D values ranges from ?12.1? to ?4.2?, ?18O from ?3.7? to ?1.13?, respectively. The entrobacter aerogen and E.Coli bacteria were detected in the samples. E. coli population for spring and the artesian boreholes indicated low value while the shallow boreholes had higher values are relatively closer to those of the middle ridges of the Swartkops River. The EC values for the spring samples averages at 14 mS/m, borehole samples ranges from 21 mS/m to 1402 mS/m, and surface water ranges from 19 mS/m to 195 mS/m. Swartkops River is an ephemeral, therefore it is expected that diffuse recharge occurs into the shallow aquifer.
Study on the Relationship between Water Quality and Wetland Plant Community in Huixian Karst Wetland	L	Shen	2023	Huixian Karst Wetland, Water quality, Wetland Plant Community
Abstract Huixian Karst National Wetland Park is the most typical karst wetland in the middle and low latitudes of the world and has become an internationally important wetland. The relationship between water quality and aquatic organisms in Huixian Wetland is a hot research topic in wetland ecology. This article focuses on the relationship between the current water quality situation in Guilin Huixian Karst Wetland and the growth of wetland plants. Sixteen sampling points are set up in the wetland to monitor and analyze water quality in wet, normal, and dry seasons. The Kriging index interpolation method is used to obtain a comprehensive water quality interpolation map in the survey area during normal water periods and in combination with the wetland plant survey sample data and the landscape status. A comprehensive analysis of the relationship between wetland plant growth and water quality. The results show that the centre of Huixian Wetland receives recharge from surrounding groundwater, which is greatly affected by the surrounding water quality. The comprehensive water quality is relatively good in the dry season, relatively poor in the normal season, and the worst in the wet season. Agricultural production, non-point source pollution, rural domestic sewage, and human interference affect wetland water quality, which directly affects the structure and function of plant communities and the ecological service function of wetlands.
Hydraulic Fracturing Of Coal Bed Methane In The Springbok Flats	Gerrit	van Tonder	2015
Abstract It is estimated that the three coal layers in the Springbok Flats contain about 5 TCF of coal bed methane (CBM). Two sedimentary basins, namely the southern Tuinplaas basin and the northern Roedtan basin, exist with coal layers with a total thickness of 7m which occurs mainly in three mayor seams. The coal layers are located between 20 m to more than 600m. Farmers in the Flats are concerned about the environmental impact of fracking the coal beds. They are mostly worried about the risk of groundwater pollution; the drawdown of the water table and the producing of a bad quality water during the mining process. They set up an EPA for the Springbok Flats in 2010 and until now, they have stopped more than 6 companies to conducted exploration (stopped strictly on account of the different laws in SA that were not adhered too). On average, 1000 liters of water is produced for every 2000 cubic feet coal bed methane mined in the USA. The quality of the produced water is not good (with typical Na values of more than 5 000 mg/l) and cannot be used for irrigation purposes. It is thus expected that about 500 million m3 of bad quality water will be produced for every 1 TCF mined in the Flats. This groundwater will be removed from the system and it is expected that a drawdown of up to 30m will be evident at places in the Springbok Flats. There are also a large number of dykes and faults in the Flats which imply that the upward movement of methane and water will be very probable after abandonment of each coal methane well.
Observations on seepage from platinum tailings	Terry	Harck	2015	platinum tailings
Abstract Tailings storage facilities are significant contributors of dissolved solids to underlying aquifers and adjacent watercourses. Salt balances indicate estimated seepage loads of the order of 1 500 tonnes of chloride per year. Actual seepage loads will be determined by the hydraulic conductivity of the tailings and mechanisms of flow within the tailings. Field observations and sample analytical results from several platinum tailings facilities are presented. These indicate the development of lenses of clay sized material within coarser silty material and suggest a tortuous seepage flow path, perhaps characterised by zones of preferential flow. The implications of seepage modelling and geochemical data on the salt loads mobilised from tailings are discussed. Results suggest that tailings facilities are effective at retaining salts and that release of accumulated salts after closure may take place at long time scales. {List only- not presented}
Automation Of Interpretation Of Geoelectrical Resistivity Using Artificial Intelligence	Emmanuel	Sakala	2019	Resistivity, AI
Abstract Artificial Intelligence (AI) has been used in a variety of problems in the fields of science and engineering in particular automation of many processes due to their self-learning capabilities as well as their noise-immunity. In this paper, we describe a study of the applicability of one of the popular branch of AI (Artificial Neural Network (ANN)) as an alternative approach to automate modelling of one-dimensional geoelectrical resistivity sounding data. The methodology involves two ANNs; first one for curve type identification and the other one for model parameter estimation. A three-layer feedforward neural network that was trained from geoelectrical resistivity data taken at boreholes with geology logs was used to predict earth models from measured data without the need to guess the initial model parameters or use synthetic data as is done with most conventional inversion approaches. The motivation for using the ANN for geophysical inversion is that they are adaptive systems that perform a non-linear mapping between two sets of data from a given domain. For network training, we use the back-propagation algorithm. An example using data from southern Malawi shows that the ANN results outperforms the conventional approaches as the results after adequate training, produce reasonably accurate earth models which are in agreement with borehole log data.
A fresh look at the National Water Balance	Andries	Wilke	2015
Abstract The national water balance is primarily based on the availability of surface water and the historic allocation thereof. The changes that are required the next 20 years to ensure sustainable development of the nation will be painful, but is unfortunately at present not part of the public discussion, it is essentially ignored in favour of more "popular water topics".This paper intends to look at a few core aspects, they include the current water allocation in the national water balance, the relative value of the utilisation, the position of groundwater resources in changing the current relative allocation and the current groundwater utilisation. The paper further intends to be a less formal presentation of these aspects with the required data, references and conclusions available for distribution afterwards.
Using electrical resistivity method for subsurface mapping of shallow aquifers in Heuningnes Catchment, South Africa	Kinsley	Manyama	2015
Abstract The current study investigated the subsurface of aquifers in Heuningnes Catchment focusing on aquifer characteristics for groundwater resource assessments. Surface geophysical resistivity method was adapted for mapping the shallow subsurface layers and hydrogeologic units at selected sites within the catchment. The aim was to provide a preliminary overview of the subsurface nature of aquifers within the study area, by establishing features such as geological layers, position of weathered zones, faults and water bearing layers. The multi-electrode ABEM SAS 1000 resistivity meter system, using the Wenner array, was used to obtain 2D resistivity data of the subsurface. The acquired data was processed and interpreted using Res2DINV software to produce the 2D resistivity models. The analysis of the resistivity models of the subsurface reveals maximum of four layers; sandstone, shale, poor clayed and brackish water saturated layer. On comparing the model results with the surficial geological formation of the catchment geological map, the identified layers were found to correspond with the geology of the area. The findings i) provide insights on sites that can be drilled for groundwater exploration, ii) show possible water-type variations in the subsurface. Although the results are not conclusive but they provide basis for further research work on quality and flow dynamics of groundwater. {List only- not presented} Key words: aquifer properties, hydrogeologic units, geo-electric model, electrical-resistivity method
Physico-Chemical Assessment of Groundwater in the Orange Water Management Area	Olma Tsakani	Makonto	2015
Abstract The groundwater quality of the Orange Water Management Area (OWMA) was assessed to determine the current groundwater status. Groundwater is of major importance in the Orange Basin and constitutes the only source of water over large areas. Groundwater in the OWMA is mainly used for domestic supply, stock watering, irrigation, and mining activities. Increase in mining and agricultural activities place a demand for the assessment of groundwater quality. The groundwater quality was assessed by collecting groundwater samples from farm boreholes, household boreholes, and mine boreholes. Physical parameters such as pH, temperature and Electrical Conductivity (EC) were measured in-situ using an Aquameter instrument. The groundwater chemistry of samples were analysed using Inductively Coupled Plasma Mass Spectrometry, Ion Chromatography, and Spectrophotometer for cations, anions and alkalinity respectively. The analyses were done at Council for Geoscience laboratory. The results obtained indicated high concentration of Nitrate (NO3), EC, sulphate (SO4), Iron (Fe), and dissolved metals (Chromium, Nickel, Copper, Zinc, and Lead). The concentrations were higher than the South African National Standards (SANS) 241 (2006) drinking water required guideline. The OWMA is characterised by the rocks of the Karoo Supergroup, Ventersdorp Supergroup, Transvaal Supergroup, Namaqua and Natal Metamorphic Province, Gariep Supergroup, and Kalahari Group. Groundwater is found in the sandstones of the Beaufort Group. Salt Mining occurs in the Namaqua Group, hence the high concentration of EC observed. High EC was also found in the Dwyka Group. The salt obtained from the pans underlain by the Dwyka Group rocks has relatively high sodium sulphate content, this probably results from oxidation of iron sulphate to sulphate. Therefore, high concentration of SO4 is due to the geology of the area. High concentration of NO3 is due to agricultural activities, whereas high concentration of EC, Fe, SO4 and dissolved metals is due to mining activities.
High Resolution Site Characterisation (HRSC) In South Africa: Challenges, Successes And Lessons Learned	Samuel D	Mohr	2015
Abstract Inadequate characterization of contaminated sites often leads to the development of poorly constructed conceptual site models and consequently, the design and implementation of inappropriate risk management strategies. As a result, the required remedial objectives are not achieved or are inefficient in addressing the identified risks. Unfortunately, it is all too common to find remedial intervention strategies that run for lengthy periods of time at great cost while generating little environmental benefit due to inadequate characterization of site conditions. High resolution site characterization (HRSC) can provide the necessary level of information to allow for development of rigorous conceptual site models, which can be used to develop and implement appropriate risk management solutions for environmental problems. At the outset, the HRSC approach generally has comparatively higher costs than traditional state-of-the-practice assessment methods. However, the project lifecycle costs can be substantially reduced due to development of optimal risk management strategies. In developing countries where there is a lack of legislation relating to soil and groundwater contamination or, a lack of enforcement of legislation which is present, the long-term liabilities related to contaminated sites are often not immediately apparent to the parties responsible for the sites. This often creates a reticence to employ HRSC techniques due to their increased cost, especially when much of the technology must be imported on a project specific basis from either Europe or the United States. The Authors provide information from several case studies conducted in South Africa where HRSC techniques have been employed to gain a greater understanding of subsurface conditions. Techniques employed have included surface-based geophysical techniques such as electrical resistivity tomography (ERT) and multi-channel analysis of seismic waves (MASW), passive soil gas surveys, deployment of Flexible Underground Technologies (FLUTe?) liners, diamond core drilling, fluid electrical conductivity profiling, downhole geophysical logging tools, the Waterloo Advanced Profiling System (APS), and the use of field laboratories. Several of the techniques required importing equipment and personnel from Europe or the US, and in several case studies, were a first to be employed in South Africa, or the continent of Africa for that matter. The Authors present data obtained using the HRSC techniques from the case studies and elaborate on how the information obtained was used to drive effective decision making in terms of managing long term environmental risks at the various sites, which has been positively embraced by local clients. The authors also highlight key challenges in conducting HRSC investigations in an emerging market context.
Geochemical Simulation of Drain Water Quality in Gold Tailings	Terry R	Harck	2017	geochemistry, modelling
Abstract This paper presents data obtained from sampling and geochemical analysis of gold tailings and associated pool and drain water. Inverse geochemical modelling using PHREEQC indicated geochemical processes operating in the tailings between the pool and drains. These included pyrite oxidation and dissolution of various minerals identified in the tailings. The processes were incorporated into an ensemble geochemical model to calculate post-closure sulphate concentration in tailings seepage. The ensemble model included a spreadsheet model to calculate oxygen flux at various depths in the tailings column, and a one-dimensional transport model in PHREEQC. The calculated oxygen flux was applied to each cell in the tailings column to determine the amount of sulphide oxidation and the release of acidity into the tailings pore water. The rate of vertical transport of pore water in the column was determined from physical characterisation of the tailings particle size and saturated hydraulic conductivity. The model results indicate elevated sulphate concentrations and acidity moving as a front from the top of the column downwards. The modelled sulphate concentration of 1 500 to 1 900 mg/L 8-16 years after closure compared well with measurements of drain water quality at a tailings dam decommissioned approximately 16 years ago. This provided some credibility to the modelled result of 2 300 mg/L sulphate up to 50 years post-closure. However, the tailings moisture content, infiltration rate, and pyrite oxidation rate in the model were based on literature values, rather than site-specific measurements.
Investigating the influence of fine ash leaching in a tailings dam on the underlying aquifers	Josepha	Zielke	2015
Abstract Fine ash is a by-product generated during coal combustion and gasification. It is often disposed of as slurry and stored on tailings dams over long periods of time, where it is exposed to weathering. Weathering causes soluble ions to go into solution and to be transported along preferred pathways through the tailings dam. This study was conducted to assess the leaching behaviour of fresh and weathered fine ash and to evaluate the impact on the underlying aquifers. A kinetic test was conducted over 21 weeks to analyse the leachate composition of progressively-aged fine ash and to calculate the release rates for major ions and trace metals of environmental concern. The leachate composition was compared to the groundwater composition of the underlying aquifers to assess the environmental impact of long term ash leaching. The study showed that the release rate of Ca decreased with increasing depth and age of the fine ash. The release rate of Mg, Na, K, Mo, V, Ba, Cr and Mo increased slightly between 22 m and 28 m in the tailings dam. Aluminium had a decreasing release rate from 28 m depth onwards. It was concluded that fine ash leaching influenced the water composition of the underlying aquifers because similarities were observed in the water type trend. The shallow aquifer south of the tailings dam contained Ca/Mg/SO4/Cl/NO3 water with a significant increase in Ca, Mg, Na, Cl and SO4 over time. These ions were expected to be found in the pollution plume due to their high release rate observed in the fine ash. The deeper aquifer northeast and south of the tailings dam showed a reverse trend of decreasing Ca, Mg and NO3 with time. This is possibly due to decreasing release rates in the aging fine ash and due to the cation exchange capacity (CEC) of the aquifer retarding the movement of Ca and Mg in the pollution plume. The shallower aquifer northwest of the tailings dam showed a decrease in Ca and Mg but an increase in K, while the water composition of the deeper aquifer increased in Ca, Mg, Na, K and Cl. This indicates that the pollution plume moved from the shallower to the deeper aquifer and that most of the Ca and Mg content in the fine ash has been leached from the tailings dam after more than 30 years of storage. The study confirmed that leaching of elements from the fine ash tailings dam had a negative influence on the underlying aquifers and that the clay lining was not sufficient in retaining the leachate.