The occurrence of emerging organic contaminants (EOCs) in the aquatic environment is of no surprise since these are applied for various purposes daily. This study investigated the changes in EOCs concentrations in the water between 2019 and 2020. During rainy seasons, samples were collected from dams and surrounding boreholes in the Eastern Basin of the Witwatersrand Goldfields. During the first and second laboratory analyses, 24 and 11 analytes were screened in the water samples. The findings indicated that in 2020, compounds such as caffeine, sulfamethoxazole, atrazine and metolachlor displayed detection frequency exceeding 2019. This indicates that the occurrence of these compounds in the aquatic system has increased within a year. Whilst carbamazepine was still traced in 12 sites as previously observed in 2019, compounds estradiol, estrone, bisphenol A and ibuprofen were traced in fewer sites than they were detected in 2019. Compounds 4-nonylphenol, methylparaben, caffeine and atrazine were detected in all the samples analysed for 2019 and 2020, respectively. Antiretrovirals (ARVs) were analysed once and were detected in most sites, with efavirenz registering the highest (12/18) detection frequency. Assessing the occurrence of EOCs in boreholes according to the depth indicated that bisphenol A and estrone were traced in greater concentrations in deep than shallow aquifers, whilst the opposite was observed for atrazine. This study showed groundwater susceptibility to contamination by EOCs, with concentrations of most compounds increasing with time due to their high usage and improper sewer systems in the area.
Presenter Name
L
Presenter Surname
Ligavha-Mbelengwa1
Area
Witwatersrand Goldfields, Eastern Basin
Conference year
2023