An end-member mixing analysis has been conducted for the hydrogeological system of the endorheic catchment of the Fuente de Piedra lagoon (Malaga, Southern Spain). Three end-members have been considered because of the three main groundwater types related to the different kinds of aquifers found in the catchment. The model’s objective is to help understand the distribution of the organic contaminants (including contaminants of emerging concern [CECs]) detected in groundwater samples from the catchment. Results suggest that some contaminants can be related to long groundwater residence time fluxes, where contaminant attenuation can be limited due to low oxygen levels and microbial activity. The three main aquifer types are: (i) unconfined carbonate aquifers with low mineralized water corresponding to two mountain ranges with no human activities over theirs surface; (ii) an unconfined porous aquifer formed by Quaternary and Miocene deposits, exposed to pollution from anthropogenic activities (agriculture and urban sources); and (iii) a karstic-type aquifer formed by blocks of limestones and dolostones confined by a clayey, marly and evaporite matrix from Upper Triassic. The groundwater monitoring campaign for the analysis of organic contaminants was carried out in March 2018. Target organic contaminants included pharmaceuticals, personal care products, polyaromatic hydrocarbons, pesticides, flame retardants and plasticizers. For the mixing model, a dataset was built with the hydrochemistry and isotopic results (δ2 H, δ18O) from the monitoring campaign conducted in March 2018 and from campaigns carried out in previous years and retrieved from the literature.
Presenter Name
M
Presenter Surname
Llamas
Area
Southern Spain
Conference year
2023
Keywords