Interannual variability in rainfall isotope composition as a tracer of spring water flow.

Table Mountain reaches 1086m elevation, the upper half of which comprises Table Mountain Group (TMG) quartzite with extensive fracture porosity. The lower half of the mountain comprises a mixture of Cape Granite intruded into Malmesbury Group metapelites, both of which are poor aquifers, but are in places overlain by scree slopes predominantly composed of TMG quartzite boulders. The region experiences a Mediterranean climate with warm, dry summers and cold, wet winters, with rainfall ranging from 600-1600mm/a depending largely on proximity to the mountain. Several springs issue from the slopes of the mountain, ranging in elevation from 15-410masl and in flow from non-perennial to 30L/s. Water chemistry reveals very little about spring water flow, as the waters have very low dissolved solids. Samples of 10 of these springs were taken twice per year for 3 years while rainwater was sampled at 120masl at the University of Cape Town (UCT) and at 1074masl at the Upper Cableway Station. These samples were analysed for oxygen and hydrogen stable isotope composition, mostly by mass spectrometer, but also by laser spectroscopy. The isotope results reveal an altitude gradient between the two rainfall stations of -0.075?/100m for ?D and -0.48?/100m for ?18O. Employing this isotope gradient, the average recharge altitude for the springs is 304masl, compared to an average discharge altitude of 156masl. Using this difference in altitude and the average slope of the terrain, a typical flow path of 1km from recharge to discharge point can be derived. Additionally, there are shifts in the weighted annual mean isotope composition of rainfall at UCT. For the years 2010-2012, the shifts are paralleled by similar shifts in the mean isotope composition at the springs for each of those years. This suggests rainfall discharges in the same winter season it has been recharged. In combination with the evidence for long term reliability of some of the springs over the dry season and during droughts, this suggests a layered flow of groundwater in the scree aquifer, allowing both long term steady discharge of deeper groundwater, as well as short term discharge of recently recharged rain. In combination with the flow path derived above, hydraulic conductivities in the realm of 10-20m/d can be calculated for the scree aquifers.