Hydrogeochemical Footprint As A Result Of Mining Activities In The Johannesburg Area

The water quality in the crystalline rocks of the Johannesburg and its environs has been severely altered by the mining activity. Due to freshwater scarcity and dependency of the people on the groundwater, it is important to understand the extent of hydrogeochemical footprint in the area. The water quality characteristic has been thoroughly assessed in the crystalline aquifers based on the input from hydrogeochemical characteristics and environmental isotopes. The results show that the calculated dilution factor for acid-mine decant is in the range of 68% as a result of interaction with surrounding fresh water. The SO4/Cl ratio has a wide range of values that falls between 0 and 306.37, while that of Fe/Ca ratio falls between 0 and 5.59. High SO4/Cl values potentially indicate the interference of acid-mine decant with the groundwater system traced through sulphate concentration. Similarly, a high Fe/Ca ratio also indicates the impact of acid-mine decant on the groundwater system where iron is traced with respect to calcium concentration. In this regard the ratios above 0,25 (with the assumption of 1 to 4 natural abundance for Fe:Ca in water in the area) could potentially represent acid-mine decant source.The results confirm that most of the water- supply wells have heterogeneous chemistry with distinctive hydrogeochemical footprint represented by abnormally high Fe, SO4 and Si as a result of acid-mine decant.