Hydrocarbon groundwater analyses: a Karoo case study

The South African government is considering shale gas extraction in the Karoo basin, South Africa. To protect groundwater resources, there is an urgent need to do a groundwater baseline in possible gas extraction areas. Various groundwater samples have therefore been taken at a borehole and 2 soekor wells in the Northern Cape, from 2016 to 2021. The groundwater samples were analysed for dissolved gasses, specifically focussing on methane. As laboratories became more efficient ethane was also included in later analyses. From the analyses we found that drought might influence the dissolved gas concentrations in the groundwater via pressure influences on the groundwater flow and the dissolved gas flow towards the shallow aquifers. Artesian conditions at this site are helping with the flow of dissolved gasses from deep to shallow aquifers via preferential pathways. The possibility of shallow-deep groundwater interconnections and the migration of deep methane to shallow aquifers make it important to establish a groundwater baseline in the Karoo. By focusing on boreholes and wells that are emitting methane, a better understanding of groundwater flow and interaction with geological layers can be determined. If other gasses like propane and butane can be analysed in addition to methane, more information can be gathered to determine the origins of the methane and whether it is thermogenic or biogenic.