Combined effects of seawater intrusion and nitrate contamination on groundwater quality in the coastal agricultural area of El-Nil River, Algeria

This study focuses on the coastal agricultural area of El-Nil River (Algeria), where anthropogenic activities heavily impact groundwater resources. A multi-tracer approach, integrating hydrogeochemical and isotopic tracers (δ2HH2O, δ18OH2O, δ15NNO3 and δ18ONO3), is combined with a hydrochemical facies evolution diagram and a Bayesian isotope mixing model (MixSIAR) to assess seawater contamination and distinguish the nitrate sources and their apportionment. A total of 27 groundwater samples and 7 surface water samples distributed over the entire study area were collected. Results show classic inland intrusion combined with an upstream seawater impact through the river mouth connected to the Mediterranean Sea. Results from nitrate isotopic composition, NO3 and Cl concentrations, and the MixSIAR model show that nitrate concentrations chiefly originate from sewage and manure sources. Nitrate derived from sewage is related to wastewater discharge, whereas nitrate derived from manure is attributed to an excessive use of animal manure to fertilise agricultural areas. The outcomes of this study are expected to help decision-makers prepare suitable environmental strategies for effective and sustainable water resources management in the study area.