stable isotopes

Previous studies have shown that river-aquifer connectivity exists. However, an integrated approach that consists of multiple measuring methods to quantify and characterise such connectivity still needs improved scientific understanding due to the underlying principles and assumptions of such methods, mainly when such methods are applied in a semi-arid environment. Three techniques (hydrogeochemistry, stable water isotopes, and baseflow separations) were applied to quantify and characterize river-aquifer interactions.

Basin-scale studies addressing the transfer of pollutants among groundwater and surface water bodies are essential to support local authorities in the sustainable management of freshwater resources. This work revealed that, in the hydro-system of the Oglio River basin (Northern Italy), nitrate pollution in groundwater, originated by overfertilization, is transferred downstream to surface water bodies via outflow through lowland springs and baseflow to gaining rivers. Downstream groundwater is unaffected due to reducing conditions that facilitate denitrification.

This study focuses on the coastal agricultural area of El-Nil River (Algeria), where anthropogenic activities heavily impact groundwater resources. A multi-tracer approach, integrating hydrogeochemical and isotopic tracers (δ2HH2O, δ18OH2O, δ15NNO3 and δ18ONO3), is combined with a hydrochemical facies evolution diagram and a Bayesian isotope mixing model (MixSIAR) to assess seawater contamination and distinguish the nitrate sources and their apportionment. A total of 27 groundwater samples and 7 surface water samples distributed over the entire study area were collected.

Stable isotopes of the water are widely used in volcanic contexts to identify the recharge area, thanks to a strong orographic effect. Such data help improve the study areas’ conceptual model, especially to identify flow paths through the volcanic edifice. The most common pattern considered is a high to medium-elevation recharge area on a flank of the volcano, feeding both local perched aquifers and a deep basal aquifer. This is quite common for “shield volcanoes”, with the flank comprising a thick accumulation of lava flows.

Water resources, including groundwater, are under threat globally from abstraction and pollution, making studies of water flows ever more urgent. South Africa has a growing population, a relatively dry climate and abundant mining activity, all of which increase the importance of water management. Mooiplaas Dolomite Quarry, southeast of Pretoria, has been mining metallurgical grade dolomite since 1969 and is located in the productive karst aquifers of the Malmani Subgroup, Transvaal Supergroup.

In South Africa and neighboring countries such as southern Zimbabwe, Botswana, southern Angola and Namibia, most river systems are non-perennial due to semi-arid/arid climatic characteristics. In such river systems, the interaction between groundwater and surface water is of significance in terms of developing appropriate methods for determining ecological water requirements among others. However, the interaction is not well understood in terms of the influence on the volume and quality of water on the gaining and losing water bodies.

Environmental isotope and hydrochemical analyses were employed to improve existing understanding of groundwater flow dynamics in the defunct mine for assessing the source of water at a pumping shaft located near Stilfontein Town, Northwest Province, South Africa. Currently pumping is done using the shaft at an average rate of 37,000 m3 /day to prevent flooding of downstream mines.

Groundwater recharge assessment was undertaken in the crystalline aquifer of the Upper Crocodile River Basin, Johannesburg South Africa. The basin is characterised by the complex hydrogeological setting represented by weathered and fractured granitic gneisses overlain by quartzite, shale and dolostone. A number of recharge estimation methods including the Stable Isotope Enrichment Shift method, were tested.