An Acid Base Accounting study of the coal-bearing formations in the Waterberg coalfield

Coal constitutes 77% of the primary energy needs in the country, with the Waterberg Coalfield estimated to host about 40% of the remaining South African coal resources. The Karoo coals were deposited in a reduced environment that have the potential to produce sulphides within the sediments they are hosted. The sulphur content within the coal can range from 0.1 wt.% to as high as 10 wt.%. Mining generates a disturbance in the natural groundwater levels and affects the surrounding water chemistry when sulphate is produced as a result of pyrite oxidation. Acid base accounting (ABA) was used to determine the balance between the acid producing potential (AP) and acid neutralizing potential (NP). From the analysis the Net Neutralising Potential (NNP) classified samples as either acid or non-acid producing. ARD does not only result in the generation of acid but is accompanied by decreased pH and increased values of specific conductance, dissolved metals and sulphate. The ABA results showed that interburden and coal samples have higher risks of producing acid upon oxidation than overburden samples. Higher concentrations of neutralising minerals are present in overburden samples. ABA indicated that the material 60m below ground surface had a higher acid producing potential than the material above. The analysis from kinetic tests showed the long-term behaviour of different samples, with the electrical conductivity (EC) and pH changing over time. Samples with lower pH continued to produce more sulphate, while calcium continued to increase until it was depleted from the samples. Inductively coupled plasma analysis determined the release of the heavy metals which can be detrimental to the environment, such as As, Co, Ni and Pb. The water demand will increase as mining continues in the area, with inter-catchment transfers identified to overcome local water scarcity issues. ARD poses a big threat to both groundwater and surface water resources.