Conference Abstracts

All Abstracts were presented at the Groundwater Conferences

Displaying 351 - 400 of 795 results

Title	Presenter Name	Presenter Surname	Area Sort descending	Conference year	Keywords
Groundwater Sampling Errors: The Missing Link in the Broken Chain	Gaathier	Mahed	Karoo	2019	Sutherland, measurement uncertainty MU, theory of sampling TOS, chain of custody, hydrogeochemical processes
Abstract A hydrogeochemical analysis of multiple samples stemming from two fractured rock aquifers in the Karoo geological formation of South Africa was undertaken. The samples were taken using various sampling methods in numerous locations over varying time frames. The ion error balance for the groundwater samples from the previously mentioned secondary aquifers is further analysed. Graphical representation of the data, which includes a piper plot, gives insight into the groundwater geochemistry. Conclusions drawn highlight the precautionary measures to take into account when sampling in fractured rock aquifers in a South African context. The future recommendations include suggestions related to the entire chain of sampling in the context of the theory of sampling and measurement uncertainty for fractured rock hydrogeology in particular.
Characterising the Soils of the Karoo: Implications for Groundwater Resource Management	Gaathier	Mahed	Karoo	2019	Poster, hydraulic conductivity, recharge, preferential flowpaths, tracer tests
Abstract The aim of the following study was to characterise the soils of Sutherland, located in the Northern Cape of South Africa. This was completed in order to shed light on possible pathways for infiltration and understand the ultimate impact on groundwater resources. Therefore, the relationship between the soil characteristics and infiltration was explored. To achieve this, field work was conducted whereby soil profiles were exposed in order to examine the subsurface characteristics of the soil and map the soil types. Thereafter, infiltration tests were taken randomly across the terrain in order to determine the in-situ properties of the soils in the region. Dye tracer tests were conducted on two plots of 1m2 within the study area, to determine the preferential flow paths and heterogeneities within the area. Field observations, as well as dye tracer tests, indicate a low clay content at the surface. This could be attributed to high wind velocity. Finally, it is shown that local river beds are hydraulically conductive due to the coarse nature of the underlying gravel. Therefore these strips of land need to be protected in order to avoid possible contamination of the already limited groundwater supplies in the region.
The use of chemistry, isotopes and gases as indicators of deep groundwater in the Main Karoo Basin	Ricky	Murray	Karoo	2015
Abstract Numerous environmental concerns have been raised with the possible exploration and development of shale gas in the Karoo. One such concern is that deep borehole drilling and the hydraulic fracturing process may create conduits through which deep-seated groundwater could migrate to shallow aquifers.This study set out to characterise deep Karoo groundwaters and identify indicators of deep flow. It was not possible to obtain groundwater samples from the deep-seated shales that are being considered for shale gas exploration and development because no suitable deep boreholes exist. Instead, samples from thermal springs and two deep boreholes that pass through the shales were obtained as the best approximation of deep-seated groundwaters in the Karoo. Deep and shallow groundwaters were characterised and determinands were identified to differentiate these waters. A provisional guide on the limits for these determinands was developed, and at this stage, this list can be used for guidance on differentiating deep form shallow waters. The determinands that appear to be most reliable in identifying deep groundwater were grouped and prioritised for future monitoring programmes.
The Complexity Of Baseline Monitoring In Unconventional Gas Projects	Richard	O'Brien	Karoo	2013	anthropogenic influence, groundwater monitoring
Abstract The monitoring of groundwater to detect changes resulting from anthropogenic activities requires an understanding of the particular aquifer system, release mechanisms and migration pathways which form the basis of a conceptual hydrogeological model. This conceptual hydrogeological model illustrates the connections between sources, pathways and receptors. The objective of a monitoring programme implemented in the context of shale gas exploration activities in the Karoo would be the detailed monitoring of groundwater quality for the protection of groundwater users. This objective requires a defensible baseline dataset so that changes in water quality can be investigated. In selecting parameters to monitor, cognisance must be taken of parameters which occur in multiple sources, those naturally present in the shallow potable aquifer, potential tracers representing the deeper groundwater and additives arising from the exploration activities. Sodium, potassium and chloride are all likely to be present in both deep and shallow groundwater and are potential additives. Given the expected higher salinity of deep connate groundwater, the use of aggregate parameters such as electrical conductivity might be of particular importance. Lithium, fluoride, strontium and uranium, while constituents of both the shallow and deep groundwater, are likely to be present at higher concentrations in the deeper groundwater, and could be indicators of deeper groundwater. Geochemical analysis of cores may provide initial clues as to such indicator parameters. Methane, which is known to occur in some existing Karoo boreholes, is potentially one of the more mobile tracers which could indicate migration from potential future production zones to shallow aquifers. The viability of using methane and other dissolved gasses (for example ethane) as indicators would require the use of stable isotope analyses to elucidate the origin of the gases.
The Complexity of Baseline Monitoring in Unconventional Gas Projects	Richard	O'Brien	Karoo	2015
Abstract The subsurface has been likened to a maze due to the intricate and often disconnected pathways contained even in unconsolidated and relatively homogeneous aquifer systems. The weathered fractured aquifers in the Karoo offer unique challenges to those planning monitoring campaigns and provide opportunities for the research community to identify innovative solutions. Careful thought needs to be given to the objectives of monitoring as these can change the requirements of the work. Other important considerations are the location and design of monitoring wells which often needs to be tailored to site specific conditions while the selection of determinands to be analysed introduces yet another layer of complexity. These include questions around the relevant detection limits, representative sampling methods and a host of other aspects. Following prescribed approaches designed for managing traditional industrial processes may not be relevant even though these approaches are based on decades of research and learning from past experience, both good and bad. Careful consideration of the technical detail in advance of beginning any monitoring in the field is essential and even then, as in any hydrogeological assessment, a level of uncertainty will always remain. This presentation will cover the status of planning work on Karoo aquifer characterisation and geochemical assessment of the ambient or baseline conditions. Significant effort continues to be made to tailor fieldwork to site specific conditions and be ready to collect a representative data set when conditions allow. {List only- not presented}
In situ iron removal: Innovative option for preventing production borehole clogging	Kate	Robey	Karoo	2015
Abstract Worldwide many aquifer systems are subject to hydrochemical and biogeochemical reactions involving iron which limit the sustainability of groundwater schemes. This mainly manifests itself in clogging of the screen and immediate aquifer with iron oxyhydroxides resulting in loss of production capacity of the borehole. Clogging is caused by chemical precipitation and biofouling processes which also manifests in South African wellfields such as the Atlantis and the Klein Karoo Rural Water Supply Scheme. Both wellfields have the potential to provide a sufficient, good quality water supply to rural communities, however clogging of the production boreholes has threatened the sustainability of the scheme as quality and quantity of water is affected. Repeated rehabilitation of the affected boreholes using techniques such as the Blended Chemical Heat Treatment (BCHT) method does not provide a long term solution. Such treatments are costly with varying restoration of original yields achieved and clogging recurs with time. Currently, the research, management and treatment options in South Africa have focused on the clogging processes which are complex and site specific making it extremely difficult to treat and rectify. This project attempts to eliminate the cause of the clogging which is elevated concentrations of dissolved iron. High iron concentrations in groundwater are associated with reducing conditions in the aquifer allowing for dissolution of iron from the aquifer matrix. These conditions can be natural- and/or human-induced. Attempts to circumvent iron clogging of boreholes have focussed on increasing the redox potential in the aquifer to prevent dissolution and facilitate fixation of the iron in the aquifer matrix. Various in situ treatment systems have been implemented successfully overseas for some time. However, in South African in situ treatment of iron has only been a theoretical approach. Based on experience from abroad the most viable option to research and apply elimination of ferrous iron in South African aquifer systems would be through the in situ iron removal treatment The objective of this paper is to set out the experience from abroad and to outline the initial results of this treatment. A pilot plant for testing the local applicability of this method was constructed at the Witzand wellfield of the Atlantis primary aquifer on the West coast of South Africa.
A Systematic Approach To The Interpretation Of Conductivity Anomalies Across Intrusive Dolerite Dykes And Sills In The Karoo	Dakalo	Makhokha	Karoo	2015
Abstract South Africa is a semi-arid country. Its average rainfall of roughly 464 mm/a is much lower than the world average of 860 mm/a. Due to a shortage of surface water, groundwater plays an important role in the water supply to domestic, industrial, agricultural and mining users. Groundwater exploration has become increasingly dependent on the use of geophysical techniques to gain insight into the subsurface conditions to minimise the risk of drilling unsuccessful production boreholes. Dolerite dykes and sills are often targeted during groundwater exploration programmes in Karoo rocks. Due to the high pressures and temperatures that reigned during the emplacement of these structures, the sedimentary host rocks along the margins of the intrusive structures are typically strongly altered. These altered zones are often heavily fractured and, as a result, have increased hydraulic conductivities as compared to the unaltered host rock. The altered zones often act as preferential pathways for groundwater migration, making them preferred targets during groundwater exploration. In conjunction with magnetic methods, electromagnetic (EM) methods are the techniques most often used for groundwater exploration in Karoo rocks. In South Africa, the ground EM system most commonly used is the Geonics EM34-3 frequency-domain system. This system has already been in use for a few decades, yet a great deal of uncertainty still remains regarding the interpretation of anomalies recorded over geological structures associated with lateral changes in electrical conductivity. This uncertainty results from the fact that the Geonics EM34-3 system employs measurements of the out-of-phase components of the secondary magnetic field relative to the primary magnetic field to calculate an apparent conductivity for the subsurface. The apparent conductivity profiles across lateral changes in conductivity often do not make intuitive sense. This project focuses on the development of guidelines for the interpretation of anomalies recorded with the EM34-3 system across intrusive structures of geohydrological significance in Karoo rocks. Geophysical surveys were conducted across known dykes and sills in an attempt to systematically investigate the responses recorded across these structures. Data from magnetic and two-dimensional electrical resistivity tomography surveys, as well as from geological borehole logs in some cases, were used as controls to assist in the interpretation.
Towards a conceptual understanding of groundwater-ecosystems interactions in the Tuli-Karoo transboundary aquifer	Kwazikwakhe	Majola	Karoo	2021	Ecosystem, TBAs, Dependent, Aquatic, Vegetation, Wetlands, Interactions, Transboundary flow, Integration, recharge, Discharge, conceptualisation
Abstract Xu,Y; Kanyerere, T Currently, there is little understanding of the nature and extent of groundwater-dependent ecosystems (GDEs) at catchment or aquifer scale globally, making it difficult to protect and incorporate them in integrated groundwater resources management plans. Groundwater levels fluctuations could alter groundwater accessibility patterns to GDEs, potentially resulting in groundwater quality deterioration too. The understanding of groundwater-ecosystems interactions is generally poor since most historical research has been skewed to surface water-related ecosystems. There exists a research need towards the understanding of groundwater processes that control the maintenance of GDEs at local level, through conceptual modelling. A study has been initiated in the Tuli-Karoo transboundary aquifer (TBA) – shared between Botswana, South Africa and Zimbabwe in the Limpopo Basin - to address this scientific knowledge gap because of possible cross-border negative impacts on respective groundwater resources attributed to interlinked aquifer systems’ nature between riparian countries. Ecosystems’ protective measures here are country-specific, disregarding neighbouring countries activities and based on low-flow requirements through baseflow, largely excluding terrestrial GDEs. Groundwater resource co-management agreements are also non-existent among sharing countries, warranting a collaborative approach to research. Potential GDEs in this TBA include riparian vegetation along the main stem Limpopo River and its major tributaries (Shashe and Mzingwane); terrestrial vegetation of Mopane bioregion of the Savanna Biome; and seasonal and permanent wetlands, pans and springs. Isotope analysis have ascertained dependency partly in one country and therefore extended to cover the TBA. Tuli-Karoo is characterized by shallow unconfined alluvium aquifer systems of the Karoo sandstones and basalts of shallow to medium depths. A conceptual model developed will demonstrate interactions between groundwater, surface water and ecosystems; allowing for assessments of impacts on GDEs to ensure resilience. Although TBA focused, the findings will be applicable to similar national aquifers in terms of lithology, geology, geohydrology and ecosystems types.
Investigating the impact of Groundwater Impact around a leaking plugged Gas Exploration bore	Willem J	Van Biljon	Karoo	2017	case study, Shale gas, plugged bore
Abstract The exploration for shale gas is imminent in the Karoo basin of South Africa. There are concerns that the exploration and production of gas might lead to groundwater contamination in a sensitive area where many communities rely on groundwater. This case study presents data from an abandoned gas exploration bore that was plugged many years ago and from where both gas and water has been observed to be leaking recently. The study aimed to determine the source of the water flowing from the plugged bore using isotope analyses and to determine whether community water supply boreholes in the area have been impacted. The laboratory results indicated that none of the community boreholes were impacted by the compounds of concern. The geochemical signature of the groundwater in the community boreholes is also significantly different from the water that is flowing out from the gas exploration bore, because it has a signature typical of recently recharged shallow groundwater.
SKA and Groundwater Management	Danita	Hohne	Karoo	2015
Abstract In 2009 it was announced that South Africa and Australia would be in competition for the race of the Square Kilometre Array (SKA). In 2009 the MeerKAT project was started in the Karoo near the core site of the SKA, which set out to demonstrate that South Africa was able to build the infrastructure of the SKA. The SKA required water for the building of roads, the dishes and the foundations of the dishes at the MeerKAT site. This poster explains the groundwater monitoring that is being performed at the MeerKAT site from 2011 till present in order to illustrate how good monitoring and management of groundwater can ensure sustainable groundwater use at sites like these. {List only- not presented}
Sustainable Groundwater Development Perspectives: Differences in sustaining individual abstraction rates based on test pumping data analysis with recharge based firm yield estimations for an aquifer or localised area.	Kes	Murray	Karoo	2021	development, water balance, groundwater budget
Abstract As populations, agricultural and industrial demands grow with time, increasing attention is placed on developing groundwater resources in a sustainable manner. At the small, local scale, this tends to involve exploration (scientific and otherwise) and test pumping (also subject to more and less scientific methods). While there can be some subjectivity in the analysis of scientific test pumping data (the selection of representative periods of drawdown stability, the inclusion of potential boundary conditions and the estimation of available drawdown), published methodologies such as the FC method (2001) and the Q20 (1959) and R20 (2006) concepts attempt to calculate sustainable abstraction rates based on these tests. At a larger catchment or aquifer scale, water balance estimates of inflows, storage and outflows are also used to estimate the effects of groundwater abstraction within such a “water budget”. This can be done conceptually, but is often also through a numerical model. A drawback of such methods is the difficulty in estimating representative annual inflow volumes, such as groundwater recharge. One such methodology is the Aquifer Firm Yield Model (2012) which assesses sustainable groundwater supplies based on threshold recharge inflows, baseflow and evapotranspiration outflows, and a 5 m aquifer saturated fluctuation limit. While this was intended for use at a preliminary stage of investigations, before sufficient hydrogeological data would be available for a numerical model, it nonetheless provides an estimate of the available groundwater for abstraction based on a water budget concept rather than test pumping data analysis. A comparison of the results of these two approaches is provided for several newly developed municipal production boreholes in the Karoo to compare where the assumptions inherent to each approach may be highlighted by noticeable differences in results.
Development of a water resource early warning monitoring system in the South Western Karoo	Zaheed	Gaffoor	Karoo	2015
Abstract POSTER Shale gas, a form of natural gas, has only recently become an economic source of energy. In the last 20 years techniques such as horizontal drilling coupled with hydraulic fracturing, have made possible the extraction of these unconventional hydrocarbon reservoirs. America has used hydraulic fracturing to produce numerous shale gas deposits in the country. This production has satisfied America's energy needs, and essentially made them a net exporter of petroleum. In light of this success South Africa is interested in developing potential economically profitable reserves of shale gas in the Karoo. However media, as well as recent studies, have identified issues with the hydraulic fracturing. These studies have linked hydraulic fracturing to contamination of groundwater resources in active production regions in America. There are fears among experts that the same could happen in the Karoo. This would be devastating to the local ecosystem and human population, as groundwater is the main water resource in the region. However it may still be necessary to proceed with shale gas development for its economic benefits. To ensure that some of the risks of hydraulic fracturing is mitigated, this paper proposes an early warning monitoring system. This system will essentially protect the local groundwater resources by early detection of any indicators that identify hydraulic fracturing contamination. The early warning system will operate by continues monitoring of groundwater parameters, in real time, and compare this regional baselines, and there by identify any changes in the groundwater properties. If a change is linked to a contamination event, the system will warn authorities, thus allowing for rapid response and ultimately ensure conservation of groundwater resources in the region.
Assessing The Influence Of Groundwater Recharge Mechanism In Non-Perennial River Systems, Tankwa Karoo, South Africa	Phumlani	Mqondeki	Karoo	2017	Ephemeral rivers, localized recharge, baseflow, Hydrochemistry, stable isotopes
Abstract In South Africa and neighboring countries such as southern Zimbabwe, Botswana, southern Angola and Namibia, most river systems are non-perennial due to semi-arid/arid climatic characteristics. In such river systems, the interaction between groundwater and surface water is of significance in terms of developing appropriate methods for determining ecological water requirements among others. However, the interaction is not well understood in terms of the influence on the volume and quality of water on the gaining and losing water bodies. In past years, research on non-perennial rivers (NPRs) has not been widely published for various reasons. In certain cases, NPRs experience extended periods of water ponding within their channels. This could possibly be caused by groundwater seepage that is sufficient to maintain pools but insufficient to generate channel flow (gaining stream) and overcome evaporation losses. The opposite can also occur, whereby some reaches of the river channel are recharging the underlying aquifer (losing stream). Abstraction of either groundwater or surface water thus impacts on both water resources. The objectives of the study are to investigate the role of the Tankwa River in recharging the underlying aquifer and the role of the aquifer in recharging the Tankwa River. Preliminary findings through literature review and field observations seem to suggest that the groundwater flow in terms of the regional perspective is driven by recharge in the far upland TMG Mountains. However, on a local scale, field observations seem to suggest that there is some aquifer-river interaction, whereby the aquifer is maintaining the pools in some parts of the channel whereas some parts of the river are dry. These findings suggest that the river contains both losing and gaining reaches thereby providing indication of an exchange of water between the water resources. This has implication on the quantity and quality of water in gaining and losing water bodies in aquifers and rivers. Future work will involve installing piezometers at points where permanent pools are located and along the river riparian zone. Monitoring of groundwater levels and the river will be carried through the different seasons. Samples will be collected from the aquifer, surface water bodies and rain gauges to integrate with the groundwater chemistry. The overall purpose of the present study is to develop a regional hydrogeological conceptual model of recharge for the Karoo in order to improve understanding of the recharge mechanism in non-perennial river systems especially in the semi-arid environment, using the Tankwa River as a case study.
Determination Of Uranium Mobility Through Geochemical Modelling In The Karoo Uranium Province	Joyce T	Leshomo	Karoo	2017	geochemistry, uranium, redox potential
Abstract The availability of freshwater is one of the major development challenges that South Africa faces. South Africa is a water-scarce (semi-arid) country with rainfall distributed unevenly and away from the centres of major developments. The rainfall is tied to seasonal cycles that drive us repeatedly between floods and droughts. This paper serves to study the groundwater chemistry in light of the uranium mining that precedes shale gas fracking in the Karoo Uranium Province. The aim is to have groundwater baseline chemistry assessment before mining commence in order to be able to track mining effect on groundwater in the future. A total of 128 samples are dealt with in this work, 112 collected from groundwater, 9 collected from springs and 7 extracted from a database. The samples were analysed for physical parameters, cations, anions and metals. Redox potential was also determined as it plays a pivotal role because it controls the availability and form of uranium in a solution. Uranium is a radioactive actinide naturally occurring in the area. Therefore, this assessment will be crucial in order to understand how changing redox and pH conditions affect uranium solubility and to estimate the extent of uranium transport by water during and after mining. The effects of the redox potential and pH on uranium mobility have been examined in this work by means of computer modelling by using the Geochemist’s Workbench (GWB) 11.0. The composition of the water used for modelling resembled that of a typical bedrock groundwater of Karoo Uranium Province. The simulations were carried out under different redox potentials at different pH levels in the presence of ferrihydrite, dissolved organic matter and carbonates/bicarbonates to include the effects of uranium adsorption. The results show that the redox potential at which the uranium mineral (uraninite) dissolves varies depending on the pH of the groundwater. Analysis of the simulation results indicated that the dissolution of uraninite takes place at a lower Redox condition with increasing pH (alkaline pH condition). This means higher redox conditions are needed for the dissolution of uraninite at low pH. Moreover, it is further concluded that the adsorption of uranium to ferrihydrite and carbonates is important at pH 6-10 and pH 5-8 respectively, which therefore play an important role in controlling the mobility of uranium in the modelled groundwater.
Hydraulic fracturing and Water Resources: Separating fact from fiction	Lizanne	Bredenkamp	Karoo	2015	Shale gas, Dolerite Intrusions
Abstract Shale gas in South Africa can be a game changer for the Karoo and South Africa economy but it may have a devastating effect on the environment. The Karoo communities is highly reliable on groundwater for their stock, irrigation and also for domestic use. Knowing the process and the potential impacts of gas-well drilling and fracturing on shallow groundwater systems beforehand different appropriate studies can be done before any hydraulic fracturing can took place in South Africa. The biggest concerns with hydraulic fracturing is that the fracturing fluids will flow and discharge into shallow aquifers due to the high pressure used or the produced water mixed with deep saline water may discharge into the environment. This paper presents a baseline dataset that will be a reference point against which any future changes in groundwater concentrations can be measured. The Karoo basin with its numerous dolerite intrusions make it unique and different from other countries. These dolerite intrusions are associated with high yielding boreholes because of the fractured contact. The Karoo Basin may be under artesian conditions, which imply that any pollutant might migrate upwards in the Karoo. The understanding of key attributes for characterising groundwater of Karoo Aquifers is most importantly the depth to water level, the yield, and groundwater quality.. The understanding of these characteristics will help to close possible legislative loopholes regarding fracturing. This paper establish an interactive database to obtain full understanding of the hydrogeology of the Karoo to be able to quantify how much water is available in the Karoo and who is the users. Not only the quantity of the water in the Karoo, but also quality and age/origin by making use of different isotopes in conjunction with basic macro chemistry. This will allow for a broader picture before any unconventional gas mining in the Karoo takes place and it can be used to identify any future changes in groundwater quality and quantity of the Karoo aquifers.
Recent Developments in The Understanding Of Karoo Aquifers And The Deeper Underlying Formations	Peter	Rosewarne	Karoo	2013	Shale gas, Karoo Groundwater Atlas
Abstract The possibility of large reserves of shale gas underlying the Karoo and their exploitation has focused attention on the groundwater resources and aquifers of this region. Much is known about the relatively shallow aquifers (<300 m) which supply many local municipalities and farmers with water for domestic, stock and irrigation use (mostly from boreholes <150 m in depth). Conversely, little is known about the deeper formations (>500 m) and associated groundwater occurrences and their possible interconnection to the shallow aquifer systems. This paper covers a desk study of the southern Karoo, mostly above the Great Escarpment, carried out by a group of hydrogeologists/geochemists with a cumulative experience of about 250 years. The main consideration at this stage has been the collation and analysis of existing information, using GIS, conceptualisations, and identification of knowledge gaps. A Karoo Groundwater Atlas was published in 2012 and Volume 2 has been released at this conference, which present a summary of the main analyses. Borehole yield, recharge and quality in the shallow aquifer tend to improve, and water levels become shallower, from west to east, associated with higher rainfall and increased percentage of dolerite and sandstone. Aquifer yield, quality, lithology and presence of dolerites constitute 60% of a groundwater attributes ratings classification; 54% of the study area has a high rating. Twenty four percent of the study area has a high vulnerability rating. Knowledge of the characteristics of groundwater associated with the deeper formations is restricted to a few thermal springs and sparse data from some deep hydrocarbon exploration wells. Weak artesian flows were recorded from two such wells in the Dwyka Group below the Great Escarpment, with Total Dissolved Solids of up to 10 000 mg/L and temperatures of up to 77 oC, from depths of 2 347 to 3 100 m. Further work and cooperation with other researchers/institutions is on-going and planned to fill in knowledge gaps and assess the risks to groundwater of shale gas exploration.
An Acid Base Accounting study of the coal-bearing formations in the Waterberg coalfield	Lore-Mari	Deysel	Karoo	2015	coal mine, sulphur, acid base accounting
Abstract Coal constitutes 77% of the primary energy needs in the country, with the Waterberg Coalfield estimated to host about 40% of the remaining South African coal resources. The Karoo coals were deposited in a reduced environment that have the potential to produce sulphides within the sediments they are hosted. The sulphur content within the coal can range from 0.1 wt.% to as high as 10 wt.%. Mining generates a disturbance in the natural groundwater levels and affects the surrounding water chemistry when sulphate is produced as a result of pyrite oxidation. Acid base accounting (ABA) was used to determine the balance between the acid producing potential (AP) and acid neutralizing potential (NP). From the analysis the Net Neutralising Potential (NNP) classified samples as either acid or non-acid producing. ARD does not only result in the generation of acid but is accompanied by decreased pH and increased values of specific conductance, dissolved metals and sulphate. The ABA results showed that interburden and coal samples have higher risks of producing acid upon oxidation than overburden samples. Higher concentrations of neutralising minerals are present in overburden samples. ABA indicated that the material 60m below ground surface had a higher acid producing potential than the material above. The analysis from kinetic tests showed the long-term behaviour of different samples, with the electrical conductivity (EC) and pH changing over time. Samples with lower pH continued to produce more sulphate, while calcium continued to increase until it was depleted from the samples. Inductively coupled plasma analysis determined the release of the heavy metals which can be detrimental to the environment, such as As, Co, Ni and Pb. The water demand will increase as mining continues in the area, with inter-catchment transfers identified to overcome local water scarcity issues. ARD poses a big threat to both groundwater and surface water resources.
Investigating Risks To Groundwater Systems In The Main Karoo Basin Of South Africa	Thandokazi	Maceba	Karoo	2017	hydraulic fracturing, Shale gas, contamination, conceptual risk assessment, over-abstraction
Abstract The improvement in hydraulic fracturing techniques resulted in the exploitation of natural gas associated with low-permeability organic-rich shale formations in the United States. South Africa has prospective shale gas resources linked with the marine black shales of the Whitehill Formation found in the Karoo Basin. Plans exist to develop the Karoo shale gas resources to diversify the primary energy mix. However, concerns among stakeholders about groundwater contamination and source of water for hydraulic fracturing remain unresolved. Such concerns include the potential of spills, fugitive gases, mechanical well integrity, and water management practices individually and collectively to introduce methane, hydrocarbons, metals, radionuclides, or other chemicals in groundwater posing human and environmental health-related risks. However, such concerns have not been assessed to provide evidence-based results that can be used to develop either an early warning or mitigation or adaptive monitoring system for shale gas development activities. The study was designed to develop a conceptual risk assessment model of potential shale gas operations to provide insights for groundwater protection. The western part of Greater Karoo Basin was used as a case study area. Applying this model suggests that hydraulic fracturing itself will have low risks in contaminating groundwater resources. However, the risks for over-abstracting groundwater remain high. These results suggest that it is crucial to learn from countries which have practised hydraulic activities for long periods of time, especially countries where the environmental setting are similar to South Africa. These findings form the basis of designing field-based studies that will influence policy making for action planning.
Drought in the Northern Cape Karoo: Lessons Learned and Options for Future Use	Danita	Hohne	Karoo	2017	Drought
Abstract Most of the Northern Cape has been hit with a drought for the past 4-7years. The western part of the Northern Cape have been dry for at least 7 years now with no rainfall or very little rainfall, while the more central part have been dry for the past 4 years with very little rainfall. It is only the past 2 years that this has been seen as a problem, but for the past 7years the Department with local municipalities have tried their utmost to manage the problem of water scarcity. During the past 7years the DWS has learned many lessons on how to manage the groundwater in these areas to ensure sustainable future use but must also look at new initiatives to deal with this problem as drought is going to be the new norm in the western parts of South Africa.
Groundwater Risk Mapping Of The Karoo Uranium Province Of South Africa	Joyce	Leshomo	Karoo	2019	risk mapping
Abstract The groundwater risk map for the Karoo aquifers has been developed by incorporating the major geological, hydro-geological and uranium concentration factors that affect and control the groundwater contamination using GIS-based DRIST model. This work demonstrates the potential of artificial intelligence to produce a map by using various spatially geo-referenced digital data layers that portray cumulative aquifer sensitivity ratings across the Karoo Uranium Province, South Africa. This provides a relative indication of groundwater risk to uranium contamination. The pollution index used in this analysis was the uranium concentration (expressed as ?g/L). The selection of this index was based not only on the fact that it constitutes the main contaminant that occurs naturally in the geology of the study area but also because it is a prime health hazard and its presence in concentrations that exceed the drinking water guidelines is a representative indicator of groundwater quality degradation. The methodology used for assessment of groundwater risk was based on an approach which was modified specifically for assessment of Uranium pollution at a regional Karoo Uranium Province, where the five DRIST maps were integrated to form an intrinsic vulnerability map. The results show that the high risk for contamination of groundwater by uranium covers the central and northern parts of the study area. The southern part is slightly less risky due to a combination of parameter settings which tend to favour attenuation as compared to transport of uranium in the subsurface. This parameter includes; rocks with good chemical attenuation properties, deeper groundwater table, and less yielding aquifers. The results were validated using the area under the curve approach and a high validation value of 0.737 was obtained. Thus, the groundwater risk map developed can be used for regional environmental planning and predictive groundwater management
Potential Impacts Of Fracking On Groundwater In The Karoo Basin Of South Africa	Gerrit	Van Tonder	Karoo	2013	potential impact
Abstract Determining impacts associated with the production of shale gas in the semi-arid Karoo on groundwater is vital to people living in the Karoo. On the one hand shale gas can be a game-changer for energy supply, but on the other it may have a devastating effect on the environment. Knowing the potential impacts of shale gas mining beforehand, the government can set appropriate regulatory protocols and tools in place to mitigate potential risks. This paper describes research done on the potential impact that hydraulic fracturing could have on groundwater in the Karoo. A wild card that only exists in the Karoo Basin of South Africa is the numerous dolerite intrusions. These dolerite structures are associated with relative high-yielding boreholes because of the fractured contact aureole that exist between solid dolerite and the adjacent Karoo sediments. Compromised cement annuli of gas wells are the major preferential flow paths along which methane and fracking fluid can escape into shallow, freshwater aquifers. This study focused solely on the impact of compromised cement annuli of gas wells. The Karoo Basin is under artesian conditions which imply that any pollutant will always try to migrate upwards in the Karoo. The hot-water springs in the Karoo indicate that upward velocities of water are relatively high (the spring water take only days to travel from deep down to the surface). The cubic law was used to estimate potential upward leakage rates from gas wells (during production, but after cessation thereof as well, when pressures will rebuild because of artesian behaviour of the Karoo formations). Potential leakage rates along faulty annuli of a well can vary between a value close to zero to two liters per second in the case of an aperture of 0,5 mm. These leakage rates were used as input to a 2D numerical groundwater flow and mass transport model. The 2D model was run for 30 years and the movement of pollution from the gas wells on the pad simulated. The model indicates that an area of 300 ha could be contaminated over a period of 30 years in a downstream groundwater flow direction. If an abstraction borehole drilled along a fault zone or a dyke, intersecting the fracked reservoir, is introduced into the model, results predict that the pollutant will reach the borehole in less than two months if the borehole is situated six kilometres from the well-pad. The total impact that fracking will have on the groundwater in the Karoo, is a function of the total area that will be fracked. The outcomes of this research clearly show that fracking in South Africa cannot be done in the same way than it is currently done worldwide. A rule that will force gas companies to disclose fracking fluid contents is non-negotiable. Companies should also be required to measure pressures in the fracked gas reservoir after closure. An additional requirement to enforce sealing of the entire fracked reservoir with a very dense material like bentonite or a mud with a very high density to capture the fracking fluids deep down in the gas reservoir should not be negotiable.
A Geostatistical-Hydrogeological Approach To Groundwater Monitoring Network Design In South Western Karoo, South Africa	Zaheed	Gaffoor	Karoo	2017	anthropogenic influence, Shale gas, Monitoring network design, kriging method, contaminant pathways, sampling grid
Abstract Groundwater in the South Western Karoo is of critical importance in the overall freshwater supply. However groundwater sustainability is vulnerable to natural as well as anthropogenic influence. Groundwater monitoring scheme are employed to provide the necessary information during decision making situations. Groundwater monitoring thus performs in important role in groundwater management and protection. Interest in exploiting potentially vast reserves of shale gas in the deep geological formations in the region, has been met with concerns that can negatively impact the groundwater system. The current monitoring network is not adequately designed to capture the necessary level of information. Hence in this paper a revised monitoring network is designed. A novel geostatistical hydrogeological approach is applied to a case study area in the South Western Karoo. Kriging methods are used to determine required density of the new network using the spatial autocorrelation of water levels in the case study area. Using the spatial autocorrelation range a hexagonal sampling grid is developed. Using key hydrogeological features, such as contaminant pathways and zones of favourable water resources monitoring points are systematically positioned within the sampling grid. Using thus approach the current monitoring network is expanded from 34 points to a total of 95 monitoring points. The new network shows an increase in optimization by lower overall kriging prediction standard error than the current network. This allows more efficient monitoring of baseline conditions and detection monitoring.
Testing Potential Reservoir Connectivity Using Isotopes	S	Dlakavu	Karoo	2017	Shale gas, hydraulic connectivity, geochemical, Isotopes, contamination
Abstract Anticipated Shale Gas Development could intensify possible natural hydraulic connectivity between deep groundwater reservoirs and shallow aquifers in the Karoo. This project attempts to test geochemical evidence of natural mixing between old groundwater from deep aquifers and young groundwater from shallow aquifers using selected isotopic signatures in conjunction with borehole yields. Borehole yields were determined using slug tests. All isotopes (δ18O, δ2H, δ13C, 3H and 14C) were analysed in the laboratory of Environmental Isotope Group of iThemba Laboratories in Gauteng. To date, results from four water samples collected in Jansenville reveal these average isotope signatures: δ18O = -3.02 ‰, δ 2H = -21.17 ‰, δ 13C = 12.46 ‰ 3H = 0.45 TU and 14C = 65.38 pMC. The δ18O-δ 2H relationship for the groundwater has a gradient of 4.48. This demonstrates that the groundwater has experienced evaporation before or during recharge. The unevaporated isotopic signature of the water is -5.86 ‰ and -33.89 ‰ for δ18O and δ2H, respectively. The enriched δ13CDIC signature suggests that methanogenesis has influenced the groundwater. The unstable isotopes (3H and 14C) suggest that there is groundwater mixing in Jansenville between younger water from shallow aquifers and older water likely from deeper aquifers. Borehole yields increase with decreasing radioactive isotope concentrations. This suggests that high yielding boreholes are areas of potential contamination because they are associated with mixed groundwater.
Natural methane in the Karoo: Its occurrence and isotope clues to its origin	Siep	Talma	Karoo	2013	Methane concentration
Abstract The possible future exploitation of methane in the Karoo has stimulated work from various disciplines to examine its occurrence, exploitability and exploitation risks. Groundwater issues are vital in this context because of its possible use during exploration and exploitation, and more important, to understand the risks of its pollution during and after all these activities. This paper presents the experiences of the authors to document the presence of methane in the Karoo based on data from boreholes, springs, tunneling and deep drilling. There have been frequent anecdotal reports of explosive gas in boreholes, both dry and wet, in the Karoo. In some cases the gas is identified as methane. Thermal spring waters in the Karoo invariably contain some amounts of methane. Methane pockets have been found in the Karoo during tunneling projects and in some deep Soekor boreholes. A groundwater study in the vicinity of the Gariep Dam indicated substantial quantities of methane in warm groundwater and an association with helium. The isotope concentrations of carbon and hydrogen in methane characterise the methane-forming processes. Such analyses in samples from the central Karoo basin are consistent with that of thermogenic gas found elsewhere in the world. Towards the edges of the basin, lower 13C-values indicate that methane there is produced by microbial processes at shallower depths. The presence of thermogenic methane together with helium on the surface is likely to give clues to pathways from depth.
Hydrocarbon groundwater analyses: a Karoo case study	Danita	Hohne	Karoo	2021	Hydrocarbon, Water level, contamination, Artisan borehole, Methane concentration, Natural gas, Dolrites, quality, Fracturing
Abstract The South African government is considering shale gas extraction in the Karoo basin, South Africa. To protect groundwater resources, there is an urgent need to do a groundwater baseline in possible gas extraction areas. Various groundwater samples have therefore been taken at a borehole and 2 soekor wells in the Northern Cape, from 2016 to 2021. The groundwater samples were analysed for dissolved gasses, specifically focussing on methane. As laboratories became more efficient ethane was also included in later analyses. From the analyses we found that drought might influence the dissolved gas concentrations in the groundwater via pressure influences on the groundwater flow and the dissolved gas flow towards the shallow aquifers. Artesian conditions at this site are helping with the flow of dissolved gasses from deep to shallow aquifers via preferential pathways. The possibility of shallow-deep groundwater interconnections and the migration of deep methane to shallow aquifers make it important to establish a groundwater baseline in the Karoo. By focusing on boreholes and wells that are emitting methane, a better understanding of groundwater flow and interaction with geological layers can be determined. If other gasses like propane and butane can be analysed in addition to methane, more information can be gathered to determine the origins of the methane and whether it is thermogenic or biogenic.
Investigating groundwater governance arrangements for shale gas exploration and production in the main Karoo Basin, South Africa	Athenkosi	Matshini	Karoo	2015
Abstract South Africa relies on coal and imported crude oil for most of its energy demands. However, the current high demand for the coal and oil and other sources of energy threat the sustainability of such energy sources, hence, the need to diversity the energy sources. However, these energy sources (coal and oil) are non-renewable sources of energy and the production of energy from renewable sources is almost non-existent. Therefore, the production of shale gas in the main Karoo Basin of South Africa provides a potential and opportunity to diversify South Africa energy mix. In pursuing such an opportunity, one has to be mindful that shale gas is neither sustainable nor a green energy system. This study aims to improve knowledge on groundwater governance arrangements regarding shale gas exploration and production in order to inform the appropriate regulatory regime and best practices to protect groundwater resources. Although there has been much effort to understand the technical implications of shale gas exploration and production on groundwater, not much attention has been given to understanding the broader groundwater governance issues. Addressing groundwater governance issues is critical to effective regulation of unconventional gas exploration and production. This is because; failure of groundwater management often results from inadequate governance arrangements, rather than lack of knowledge about sustainable yield or pollution vulnerability of aquifers. It has been argued that, there exists a perpetual tension between viewing groundwater as a common-resource and the rights of private appropriation of groundwater for use. Thus, groundwater is inherently vulnerable to the "tragedy of the commons" in which actual users and potential polluters act solely in their individual short-term interest rather than taking into account long-term communal considerations. The study provides significant insights regarding appropriate and effective institutional arrangements for groundwater governance.
Groundwater Governance Requirements for the Exploration and Production of Unconventional Gas Sources	Kevin C	Pietersen	Karoo	2013	groundwater governance
Abstract South Africa has an energy crisis. The country requires 53 Gigawatt of new capacity by 2030. The exploitation of unconventional gas is a potential game-changer to meet South Africa’s current energy deficit to fuel economic growth and development. Water management, both in terms of abstraction and disposal, has emerged as a critical issue in the development of unconventional gas reservoirs. This presentation focuses on a high-level, qualitative analysis of the groundwater-related institutional and governance challenges associated with unconventional gas exploration and production. The findings represent a synthesis of information sourced from regulatory and legislative documents as well as international experience. The analysis maps the current groundwater institutional and governance landscape in South Africa and lessons learned from other regimes such as the United Kingdom and United States of America. Good governance entails ensuring that there is compliance with policy and legislation, effective decision-making, appropriately allocated accountability, transparency and that stakeholder interests are considered and balanced. This forms the basis of a preliminary gap analysis.
Monitored Natural Attenuation of Inorganic Constituents: A Case Study in a Karoo Aquifer	Vevanya	Naidoo	Karoo	2015
Abstract Natural attenuation describes a set of natural processes which decrease the concentrations and/or mobility of contaminants without human intervention. In order to evaluate and demonstrate the effectiveness of natural attenuation, regular long term monitoring must be implemented. This entire process is called Monitored natural attenuation (MNA). The focus of MNA is generally placed on hydrocarbons and chlorinated solvents but according to the United States Environmental Protection Agency (USEPA) MNA can be used for various metals, radio nuclides and other inorganic contaminants. MNA was deemed the best method to reduce the concentration and mobility of contaminants impacting the groundwater environment, at a fertiliser plant in the Free State. A number of improvements in infrastructure were made in 2013which were assumed to have prevented further release of contaminants into the groundwater system, from the source areas on site. MNA was also considered to be the most effective affordable solution for the site as groundwater in the vicinity is not used for domestic purposes (low risk). Cl, NO3 and NH4 were used to monitor the movement of the contamination off site and the effectiveness of MNA. With regards to the inorganic contaminants emanating from the site, sorption, dispersion, dilution, and volatilization are the main attenuation mechanisms. These mechanisms are considered to be non-destructive attenuation mechanisms. Denitrification, nitrate reduction through microbial processes, may also facilitate in the attenuation of the in organic constituent nitrate. Denitrification is considered a destructive mechanism. Classed posts and temporal graphs of the Cl, NO3 and NH4 concentrations between 2008 and 2014 were utilised to show the movement and change in size and shape of the contamination plumes and subsequently, monitor MNA. The data indicates that the NO3, Cl and NH4 contamination plumes from the various source areas on the site have detached from the site and are currently moving down gradient along the natural drainage. Contaminant concentrations at the site have generally decreased in recent monitoring events while concentrations downstream of the site have remained stable. This indicates that MNA is currently an effective method of remediation for the site and monitoring should be continued to ensure that it remains effective.
Possible Wastewater Volumes Associated With Unconventional Oil And Gas Extraction In South Africa And The Management Thereof	RD	Williamson	Karoo	2017	Unconventional gas, Wastewater, Fracking
Abstract Several oil and gas companies have applied for licenses to extract unconventional oil and gas (UOG) resources in South Africa (SA) through a process known as hydraulic fracturing or fracking. The South African government is in the process of drafting regulations and procedures to allow the extraction of these resources. It is surmised, based on evidence from fracking examples around the world, that large volumes of wastewater may, however, potentially be generated during the extraction of these UOG resources. The issues arise when it comes to determining the actual volumes of wastewater that may be generated from this process, should it be used in SA, as well as the management of the wastewater. The volume of wastewater generated is dependent on a number of factors, with well properties, rock formation, basin properties and the number of fracturing stages within the well, being some of the dominant factors. In this project an extensive review of existing literature, reports and fracking databases was used to identify the methods used for determining wastewater volumes, which databases were used as well as the assumptions and challenges each data source faced. The data was analysed and interpreted in order to come up with various ranges and averages of wastewater generated through UOG extraction. The potential volumes of wastewater generated through fracking were then modelled into the hypothetical scenarios outlined in the Strategic Environmental Assessment (SEA) on Shale Gas Development in the Central Karoo. This allowed for the determination of potential volumes of wastewater associated with UOG extraction in SA from which management implications for wastewater in South Africa can be determined.
Expanding the boundaries of the Eastern Kalahari Karoo Transboundary Aquifer (EKK-TBA) shared between Botswana and Zambia: A governance challenge	Kevin C	Pietersen	Karoo, Botswana, Zambia	2021	transboundary, joint management
Abstract The EKK-TBA is significant in anchoring Gross Domestic Product growth and development in both countries is heavily reliant on groundwater. Recently a transboundary diagnostic analysis (TDA) and a strategic action plan (SAP) for the EKK-TBA was completed. The analysis resulted in a three-fold expansion of the EKK-TBA boundary. The new EKK-TBA boundary overlaps part of the Okavango and Zambezi River Basins and now also includes major wellfields in Botswana and Zimbabwe (Nyamandlovu and Epping Forest) as well as the Makgadikgadi Pans which act as the surface water and groundwater discharge zone. An analysis of institutional arrangements was carried out to enhance effective and efficient management of the EKK-TBA. Noting the complexity of the EKK-TBA. the initial institutional response could potentially be the development of a bilateral agreement between Botswana and Zimbabwe for cooperation and coordination to support the management of the TBA. This agreement would seek to establish a Joint Permanent Technical Committee (JPTC) that would also co-opt in members from the two shared watercourse commissions. Such a JPTC would enable improved coordination across the varying transboundary dimensions and would align with the precepts of the Revised Protocol on Shared Watercourses. This would include such principles including sustainable utilization, equitable and reasonable utilisation and participation, prevention, and co-operation, as well as aspects of data and information exchange and prior notification.
Geophysical Borehole Siting at Elizabeth Conradie School in Kimberley, Northern Cape Province, South Africa	Matome	Sekiba	Kimberley, Northern Cape	2021	geophysical methods, mapping , Drilling
Abstract The Council for Geoscience has a corporate responsibility in rural development projects as part of the South African government initiative in food and water security. Geophysical surveys were carried out at Elizabeth Conradie School in Kimberley, Northern Cape Province South Africa aimed on siting production boreholes to supply the school with water. Traditional geophysical techniques including magnetic, electromagnetic and resistivity were used to locate groundwater bearing structures. The magnetic method was used to locate intrusive magnetic bodies (i.e. Dolerites), while electromagnetic and resistivity were used to map conductivity and resistivity distribution associated with the subsurface geology. The magnetic method delineated possible groundwater bearing structures which may be related to dolerite dykes and sills. The electromagnetic method appears to have identified shallow fresh dolerite sill. The resistivity method was good in identifying areas of low resistivity which might be related to fractures and/or faults. The high resistivity values might be related to dolerite dykes or sill. The results of the study showed that geophysical methods are useful non-intrusive tools for mapping groundwater resource. The 1:250 000 scale geological reconnaissance map used to constrain the geophysical interpretation is at a bigger scale when compared to the geophysical interpretation resolution. Considering this and also the ambiguity and none uniqueness in geophysical interpretation, results need to be consolidated by a local scale hydrogeological mapping and drilling results.
Groundwater Remediation In The Klerksdorp Goldfields	Gawie	van Dyk	Klerksdorp	2013	Groundwater
Abstract Gold mining activities over the past 60 years in the Klerksdorp goldfield produced saline mine drainage that polluted water. Oxidation of sulphide material in tailings storage facilities, waste rock dumps and extraction plants is mobilised to produce saline mine drainage with sulphate, minor salts and metals that seep to the groundwater and ultimately into surface water resources. Water regulation requires mines to prevent, minimise/reduce or eliminate pollution of water resources. The waste philosophy has matured from tolerate and transfer to treat and termination of pollution sources. The impact of the pollution was determined and possible technologies to treat the impact were evaluated. Source controls with proper water management by storm water management, clean dirty water separation, lined water conveyance structures and reduced deposition of water on waste facilities are crucial. The aquifer character determines the possible remediation technology. From the possible technologies phytoremediation, physical interception and re-use of this water was selected. In future possible treatment of the water would be considered. This paper explain the strategy and report on the phased implementation of these plans and the expected results. The establishment of 500 ha of woodlands as phytoremediation, interception trenches of 1 000 m, 38 interception boreholes and infrastructure to re-use this water is planned. The total volume of 15 Ml/day would be abstracted for re-use from the boreholes and trenches. The woodlands can potentially attenuate and treat 5 Ml/day. The established woodlands of 150 ha prove to be successful to intercept diffused seepage over the area of establishment and reduce the water level and base flow. The two production interception well- fields that are abstracting 50 and 30 l/s, respectively , indicate a water level decline of between 2 to 14 m, with regional cones of depression of a few hundred meters to intercept groundwater flow up to a 20 m depth. Predictions from groundwater modelling indicate that these schemes can minimise pollution during the operational phase and protect downstream water resources. Predictions from modelling indicate that the pollution sources need to be removed to ensure long-term clean-up to return the land to safe use. The gold and uranium prize is securing the removal of the sources through re-processing of the tailings and waste rock dumps. After removal of the sources of pollution, the remediation schemes would have to be operated for 20 years to return the groundwater to an acceptable standard of stock watering and industrial water use. The water quality is observed by a monitoring network of approximately 100 observation boreholes.
An innovative approach to dealing with elevated iron concentrations at the Knysna Hospital	Roger	Parsons	Knysna	2021	Iron treatment, TMG, pumping rates
Abstract In response to the drought which started in 2017, the Western Cape Government set about securing water supplies to key facilities across the province, including the Knysna Hospital. Drilling and testing of two boreholes at the facility indicated it to be viable to establish a groundwater supply of 66 KL/d from the underlying Table Mountain Group Aquifer. Iron concentrations were low and the initial water chemistry analyses pointed to concentrations below the SANS 241 aesthetic limit. However, further to the implementation and operationalization of the groundwater supply schemes, significantly elevated iron concentrations of up to 6 mg/L were observed. This contributed to the difficulty in getting the Knysna Hospital’s alternative water supply operational. Best practice requires that as little oxygen as possible gets introduced into the groundwater system; and this can be achieved by pumping the borehole continuously at the lowest rate possible. It is not always possible to do this under operational conditions when the water demand varies. To counter the iron problem in the potable water and to prevent or retard an increase in the iron concentration in the abstracted groundwater, iron treatment was added to the treatment train and a dual pumping regime was adopted. Using the variable speed drives that had been installed with the pumps, two pumping rates were adopted – with the rate controlled by the level in the treated water storage tank. When the tank level is low, the borehole is pumped at a rate of 0.9 L/s. However, when the level fills to 70%, the pumping rate is reduced to 0.35 L/s and continues pumping even if the tank is full. The modified system was brought into operation in August 2019 and has continued to meet the water demand of the hospital.
Application of Environmental Tracers for Differentiation of Fresh and Re-Circulated Submarine Groundwater Discharge (Sgd) Into Knysna Estuary, South Africa	E.	Petermann	Knysna Estuary, South Africa	2017	Environmental tracers, Submarine Groundwater Discharge
Abstract In coastal areas worldwide terrestrial groundwater resources and the coastal sea are generally hydraulically connected thus allowing continuous groundwater/seawater interaction. This major form of land-ocean interplay is associated with two potential pathways of dissolved matter transport, namely (1) flux from the marine to the terrestrial environment in form of seawater intrusion into terrestrial aquifers and (2) flux of terrestrial groundwater into the coastal ocean manifested as submarine groundwater discharge (“SGD”). The sea-to-land pathway is of relevance due to the risk of irreversible salinization of coastal groundwater resources and is in most cases a manmade (and hence manageable) phenomenon set off by excessive groundwater exploitation that is not balanced by groundwater recharge. The land-to-sea pathway (i.e. SGD), on the other hand, occurs naturally everywhere an aquifer with a positive hydraulic head is connected to the ocean. It is of interest due to two potential threats, namely (i) the loss of freshwater to the ocean, an issue that is particularly relevant in climate zones characterized by water scarcity, and (ii) the detrimental impact of nutrient- or contaminant-laden groundwater discharge on the coastal water quality, an aspect that is of relevance along urbanized coastlines worldwide. The latter implies that SGD localization and quantification is of major relevance with regard to (i) the evaluation of the vulnerability of the coastal sea to groundwater pollution and for (ii) understanding the associated matter cycles including nutrients, organic compounds or inorganic contaminants. We present results of an environmental tracer based approach that aimed at evaluating short-term SGD dynamics into the Knysna estuary, South Africa. Both natural components of SGD, terrestrial freshwater (FSGD) and recirculated seawater (RSGD), were estimated individually. We conducted an end-member mixing analysis for time series of radon (222Rn) and salinity over two tidal cycles in order to determine four water fractions within the estuary: seawater, river water, FSGD and RSGD. The results were backed by stable isotope data (18OH2O and 2HH2O). End-member mixing ratio analyses revealed the mixing ratios that fit best to the observations at every time-step of the 24 h time series, which was carried out near the estuary mouth. Results indicated highest FSGD and RSGD fractions in the estuary water during low tide amounting to 0.2 % and 0.8 % for FSGD and RSGD, respectively. A radon mass balance for the whole estuary revealed a radon flux via SGD of 41 ± 7 Bq m^-2 d^-1, which equals a total FSGD of 4.6 10⁴ m³ d^-1 and RSGD of 1.5 10⁵ m³d^-1 . The results do imply that the majority of nutrient fluxes (DIN) into the estuary are SGD-derived.
Comparison Of Analytic And Numerical Estimations Of Groundwater Drawdown Evolution For Open Pit Dewatering	Jaco	Nel	Kolwezi, Democratic Republic of the Congo	2013	dewatering, Drawdown
Abstract A new mining site situated near Kolwezi in the Democratic Republic of the Congo plans to develop a pit in phases over a period of six years. The mine requires dewatering volume estimates of the pit as well as a constant water supply to the plant. Hydrogeologic data available at the site during the scoping phase was limited to a few water level measurements and blowout yields from only five hydrological boreholes. Hydraulic properties from reports at neighbouring sites were extrapolated to the geological units at the site. The depth to water level at the site is about 20 m, with a planned final pit depth of approximately 180 m below surface. Based on the limited data available an analytical approach to estimate the inflow into the mine was adopted. Analytical calculations proposed by Marinelli and Niccoli (2000) were used to estimate the inflow into the Pumpi mine pits. The analytical calculations consider recharge, depth of mining vertical and horizontal hydraulic conductivities. Drawdown evolution of pit dewatering are obtained by using different mining depths at different mine stages. The output results from the analytical calculations are the maximum extent of influence of the pit as well as the volume of water inflow into the pit. Limitations of the analytical equations are that they, amongst others, cannot consider complex boundaries. Drilling and pump testing to obtain local hydraulic properties and boundary conditions are planned during the first quarter of 2013. The numerical model will be set up after the drilling and pumping tests, using the new data for calibration. The numerical model will contain as much of the physical layer definitions and potential internal boundaries as possible with model boundaries incorporated along far field fault zones and hydraulic boundaries. The numerical model should improve the reliability of estimates of pit inflow and water supply to the plant. The results between the analytical and numerical approaches can then be compared to improve future dewatering estimates with limited data. It is expected that the reliability of the analytical predictions will reduce after year 4, where the role of boundaries are expected to influence the drawdowns and related flow towards the pit.
Case Study: Groundwater Exploration In The Basement Granites Of The Kraaipan Group Using Aeromagnetic Surveys	Marius	Terblanche	Kraaipan, North West Province	2013	groundwater exploration, case study, Granites
Abstract Historically groundwater exploration consisted of reconnaissance geophysical surveys followed by detail ground surveys. Where no potentially water-bearing geological structures are shown on geological maps and aerial photos, the project area would be divided into a grid on which the ground geophysical survey would be done. This type of exploration is time-consuming and expensive. In some cases the terrain or cultural noise prohibits the use of conventional geophysical methods, with only more expensive and time-consuming methods being left as an option. This is where the high resolution airborne magnetic survey excels. The results obtained from this type of survey are of such a nature that ground geophysical surveys are only performed where potential drilling targets were identified from the aerial survey. Not only can there be cost- and time-savings on ground geophysical surveys, but drilling of dry boreholes can be limited, which makes up the largest cost component of a groundwater exploration project. This paper will discuss successes achieved using high resolution aeromagnetic surveys as the basis for groundwater exploration in traditionally low- yielding igneous geology.
Using Electrical Resistivity Tomography To Describe The Aquifer Architecture Linked To Groundwater And Surface Water Interaction	Teboho	Shakhane	Krugerdrift Dam, Free State	2013	Electrical Resistivity Tomography, aquifer, Groundwater, surface water
Abstract POSTER One of the critical elements of water resource management is the dynamic exchange between groundwater and surface water. Quantifying this exchange strongly relies on an adequate characterisation of the lithological architecture of the involved aquifer system. In the past, this characterisation often relied on lithological data obtained through invasive methods. However, given the spatial heterogeneity of the subsurface, these methods do not provide the density of sampling required for an accurate ‘‘image’’ of the large‐scale architecture of the aquifer system, leading to large uncertainties in the variations and continuities of subsurface structure. These uncertainties inevitably lead to inaccuracies in the conceptual geohydrological model, thereby diminishing the prospects of an accurate assessment of the groundwater–surface water interaction. In order to limit the uncertainties, the results of electrical resistivity tomography (ERT) surveys conducted on a site near the Krugersdrift Dam in the Free State Province of South Africa were used to make inferences regarding the prevailing geohydrological conditions. The resistivity models were compared to borehole logs from existing boreholes to produce a refined model of the subsurface architecture related to groundwater–surface water interactions.
A 1: 100 000 Hydrogeological Mapping: Kuruman Map Sheet 2723A	Phathu	Nemaxwi	Kuruman	2019	Poster, mapping
Abstract As part of supporting the National Development Plan (NDP) vision 2030, Council for Geoscience has been tasked by the Department of Mineral Resources to embark on an integrated and multidisciplinary geoscience mapping programme to systematically map South Africa in a more detail manner. With the idea of groundwater resource development and preservation purposes, a 1:100 000 geohydrological map, explanatory booklet, geohydrological data base for all data obtained from various sources and an ISO document was produced. The map is situated in the middle reach of Kuruman River and covers an area of 2750 km2. Mapping process commenced by sorting existing geological and hydrogeological data sourced from the Council for Geoscience database, Department of Water and Sanitation, Department of Agriculture and Kuruman municipalities. The process also includes filling identified gaps through extensive hydrocensus which entailed site surveying, hydrocensus, measuring and groundwater sampling, determination and demarcating of groundwater units, legend standardization and GIS cartography. Different aquifer types were categorised by analysing factors which control groundwater occurrence in the area; these factors includes lithostratigraphy, groundwater quantity, geological and linear structures. These were later used as datasets in Arc GIS for map processing. Before being used to determine aquifer media and geohydrological boundary conditions, these factors were closely studied through different approaches by interpreting geological and remotely-sensed data, field verification and survey of historical information. Four aquifer types were identified, namely; Intergranular aquifer covering an area of 152.9 km2; Intergranular and fractured aquifer which covers 696.4 km2 area; Fractured aquifer which covers an approximate area of 408.5 km2 and Fractured karst aquifer with a total size of 1486.1 km2. The insert groundwater quality map show completely unfit water (Class 4) for use in the central and south-eastern side of the map. Electrical conductivity in most parts of the map fall within recommended operational limit.
Modelling of Lake-groundwater interactions using a three-dimensional groundwater flow model for the Lake Sibayi catchment	Jannie	Weitz	KwaZulu-Natal	2015
Abstract Lake Sibayi (a topographically closed fresh water lake) and coastal aquifers around the lake are important water resources, which the ecology and local community depend on. Both the lake and groundwater support an important and ecologically sensitive wetland system in the area. Surface and subsurface geological information, groundwater head, hydrochemical and environmental isotope data were analysed to develop a conceptual model of aquifer-lake interaction which would later be integrated into the three dimensional numerical model for the area. Local geologic, groundwater head distribution, lake level, hydrochemistry and environmental isotope data confirm a direct hydraulic link between groundwater and the lake. In the western section of the catchment, groundwater feeds the lake as the groundwater head is above lake stage, whereas along the eastern section, the presence of mixing between lake and groundwater isotopic compositions indicates that the lake recharges the aquifer. Stable isotope signals further revealed the movement of lake water through and below the coastal dune cordon before discharging into the Indian Ocean. Quantification of the 9 year monthly water balance for the lake shows strong season variations of the water balance components. Based on lake volume and flow through rate, it was further noted that the average residence time for water in the lake was about 6 years. A recent increase in the rate of water abstraction from the lake combined with decreasing rainfall and rapidly increasing plantations in the catchment may result in a decrease in lake levels. This would have dramatic negative effects on the neighbouring ecosystem and allow for potential seawater invasion of the coastal aquifer.
Developing And Optimising Conditions For Bioflocculation Of Bacillus Sp.Isolated From The Estuary On The Umlalazi Catchment At Mtunzini, KZN Province	TM	Kubhayi	KwaZulu-Natal	2017	Bioflocculant, flocculating activity
Abstract Synthetic flocculants are widely used in water treatment for their efficiency when it comes to flocculation but pose a risk to the environment and human health. The need for an alternative flocculant was investigated in this study. Bioflocculants which are produced by microorganisms have the potential to flocculate fine suspended particles. The bioflocculant production by Bacillus sp. isolated from Umlalazi Estuary in Mtunzini, KwaZulu-Natal Province was evaluated. Optimum flocculation conditions were obtained with an inoculum size of 1% v/v (89%), carbon source which was glucose with a flocculating activity of 88%, a multiple nitrogen source with a flocculating activity of 88%, an optimum temperature of 400C with 95% flocculating activity, shaking speed of 120 rpm with 95% flocculating activity, K+ for the cations was optimum at 95% flocculating activity and the pH of 7 had the flocculating activity of 94%. In the time course assay optimum conditions were reached after 84 hours with the flocculating activity of 92% at pH 5.29 using 0.4% (w/v) kaolin suspension. After extraction and purification, a bioflocculant yield of 2.1g/L was recovered from a 1L fermentation broth. Water treatment without the risk to human health is now a reality.
Understanding Site Hydrology of the Northern Kwa Zulu Natal Anthracite Coal fields	Hendrik	Botha	KwaZulu-Natal	2015	coal mining, AMD, mine closure
Abstract POSTER Investigations have shown that receiving water bodies, which mainly include rivers, streams and the more complicated geohydrological system, are part of the primary end receivers of harmful contaminants from identified coal mining waste bodies. Some of these potential dangers include acid mine drainage (AMD) and sulphur mine drainage (SMD) which have dire effects on the surroundings. The need for a cost effective methodology to assess site hydrology and geohydrology, to understand the associated legal responsibility of contaminated streams and aquifers, is recognised. In the compilation of this paper the unique nature of South African legislation and policies are implemented in the development of a logical approach towards mine closure specifically in the field of groundwater assessments. Furthermore, this paper explores co-disposal of discard and slurry material and the environmental impact of co-disposed wastes is assessed. The unique geological attributes of the KZN coal fields and the geochemical research results found indicates that on its own discard has great potential to produce long term SMD and that slurry has lower SMD potential. Co-disposed results are promising and buffering against long term chemical changes are noted. The final product of this approach constantly considered site hydrogeology, related impacts, risks and liabilities. This gave more clarity on aspects related to the principles followed to identify objectives for sustainable mine closure and to adopted a philosophy of mine closure as a hydrogeological concept. Overview of methods that could be used for mitigation of polluted aquifers and a brief site specific application is discussed with the aim to achieve the key deliverable which focuses on methods to scientifically assess sources, pathways and receivers. Ultimately this process has led to the development of a logical approach towards mine closure for groundwater assessment and remediation in the typical anthracite mine environment.
Characterization of the Co2 Springs Associated With the Bongwana Fault, Its Impact on Fresh Surface Water and Groundwater Quality and Implications on Carbon Capture and Storage (Ccs) In South Africa	M.	Nkwane	KwaZulu-Natal	2017	Bongwana Fault, CO2 springs, Environmental Isotopes, Hydrochemistry, South Africa
Abstract The natural CO2 springs at the Bongwana area emanates from a number of sites along an 80 km long N-S trending fault known as Bongwana fault. CO2 rich groundwater is observed at a shallow depth in a borehole drilled for water supply parallel to the main fault. The geology along the entire fault length is characterized mainly by Dwyka Group sediments. The objectives of this study are to characterize the CO2 springs and assess their impacts on groundwater and surface water quality. To that end, existing literature and data were reviewed followed by the collection of groundwater and surface water samples at both CO2 emission and CO2 free streams, springs and boreholes around the length of the Fault zone. Major ions, trace elements and environmental isotopes analyses were carried out on the samples collected. EC, TDS, pH, Temperature, DO, Eh, ORP, total alkalinity, CO3 2- , HCO3 - ) were measured onsite. Acidic pH conditions, elevated TDS, EC and trace metals concentration were detected in all CO2 emission sites compared to CO2 free streams, springs and boreholes. These results clearly show the impacts of CO2 on groundwater and surface water quality within the vicinity of emission points. All the travertine cone springs located near Umtamvuna River are characterized by Na-Ca-Mg-HCO3 water types, while boreholes from shallow groundwater and river samples show Ca-Na-Mg-HCO3 types. The correlation among the deep CO2 rich groundwater parameters indicates that the major geochemical processes that could be responsible for the observed chemical composition are the precipitation of calcite and dolomite where their saturation indices (SI) range from 0.74 to 0.82 and from 0.24 to 1.35, respectively and the weathering of feldspars. Stable isotope (δ18O and δ2H) composition of the travertine cone springs shows a major negative shift from the meteoric water lines with δ18O and δ2H values ranging from -7.78 to -6.52 ‰ and -21.5 to -17.9 ‰, respectively. The stable isotopic composition of shallow groundwater reflects local and modern meteoric recharge. These observations indicate that the reservoir and source of recharge for the deep circulating groundwater are different from the shallow groundwater. It appears that natural CO2 emission along the Bongwana fault have impacted the ambient groundwater and surface water quality at the emission sites rendering it unfit for human consumption due to elevated concentration of dissolved constituents above safe drinking standards. The implication of this to CCS in South Africa is the fact that any unintended CO2 leakage into fresh groundwater and surface water resources from subsurface storage site can impact this already scarce resource. Therefore, strict scientific site selection protocols and CO2 leakage detections through properly designed monitoring systems are required to minimise the risk.
The Study Of The Effectiveness Of Rehabilitation Of Abandoned Dundee-Newcastle Coal Mines On Groundwater And Surface Water Quality	Preanna	Naicker	KwaZulu-Natal	2017	abandoned coal mines, AMD, Rehabilitation, Hydrochemistry
Abstract The legacy of mining in South Africa in general and in KwaZulu-Natal (KZN) province in particular, continues to affect the quality of surface water and groundwater resources. Rehabilitation of Northern KZN abandoned coal mines and their discard coal mine dumps had been undertaken by Government in the 1990’s following the emergence of stricter environmental legislation. The purpose of this study was to study the success of the rehabilitation of these abandoned mines in improving the quality of surface water and groundwater resources around the area. Hydrochemical data for the past seven years including data generated during this research was analysed through hydrochemical plots, trend analysis, bivariate and multivariate statistical analyses and calculation of saturation indices using various software, including AqQA, SPSS and PHREEQC. These hydrochemical analyses results were interpreted along with groundwater level and environmental isotope data. The results show that since the start of the monitoring period seven years ago, the groundwater is characterized by circumneutral pH and contains relatively low concentrations of metals. Ionic concentrations of groundwater were assessed and found to correlate with neutralization reactions, specifically calcite and dolomite Acid Mine drainage (AMD) buffering reactions. Time series analysis of saturation indices revealed slight fluctuations for calcite and dolomite, although groundwater appeared to remain oversaturated with respect to these minerals. This was due to the generation of Ca2+, Mg2+ and SO4 2- ions from carbonate- AMD neutralization reactions. Time series data of EC, SO4 2- and total Fe indicated no anomalous values except with few episodes of elevated levels. The main groundwater hydrochemical facies identified was Ca-Na-HCO3. The surface water samples displayed elevated EC at various sampling points, indicative of the impact of both the neutralization reaction and the AMD. The analysis of all available data and information show that the rehabilitation operation has been largely successful, with exception of a few possible seepage zones that have been impacting surface water quality.
Statistical Analysis Of Groundwater Level Variability Across Kwazulu-Natal Province, South Africa	Minenhle	Ndlovu	KwaZulu-Natal	2017	groundwater level variability, Mann Kendall test, trend analysis, Sen's slope
Abstract This paper reports the results of groundwater level variability analysis across KwaZulu-Natal (KZN) Province of South Africa and its relationship with rainfall. The study used 32 groundwater level monitoring sites and 15 rainfall stations. The main objective of the study was to understand groundwater level trends for the monitoring period, i.e. from 2004 to 2015 and understand its controls. The Mann-Kendall test was used to explore the presence of trends in groundwater level and rainfall data at 10% statistical significance level. The slope of the trend has been estimated using Sen’s slope estimator. The results revealed that within the Usuthu-Mhlathuzi Water Management Area (WMA), both groundwater level and rainfall have a declining trend for the entire record period. Tembe and Mbazwana areas showed a groundwater level decline of 0.7 and 2.7 m, respectively; while areas around Richards Bay experienced a groundwater level reduction between 0.7 and 6.3 m from 2004 to 2015. During the same period, rainfall was significantly reduced around Tembe, Mbazwana and Richards Bay areas by 26, 6 and 18% from the mean, respectively. The uThukela WMA, around Dundee and Newcastle exhibited an increase in groundwater levels by about 1.5 m between 2004 and 2010 but later declined by 1.2 m in the period from 2014 to 2015. During the period from 2004 to 2010, the rainfall showed increasing trend by 8%, but decreased by 22% in 2015. The central part of the uThukela WMA, around Tugela Ferry and Greytown, showed a decrease in groundwater level and rainfall by 3.2 m and 15%, respectively for the entire record period. The northern Mvoti- uMzimkhulu WMA around Maphumulo showed groundwater level decline by 11 m for the period from 2005 to 2011. However, the groundwater level recovered by 8 m between 2012 and 2013 following an increase in rainfall by 21%. Areas around Durban, groundwater level showed an increasing trend from 2005 to 2008 which coincided with an increasing rainfall amount by about 13%. The rainfall decreased by 21% from 2012 to 2015 resulting in the decline of groundwater level by 0.4 m for the same period. The steady decline in the groundwater level across the province appears to be a response to prolonged reduction in rainfall, which consequently reduced the amount of groundwater recharge reaching the aquifer. The response of the groundwater level to changes in rainfall across KZN has a lag time between 1 to 4 months.
Cost Effective Drilling Methods For Obtaining Water Supply In Sodwana, Northern Kwazulu Natal	Jean	Simonis	KwaZulu-Natal	2015
Abstract We contend that borehole drilling costs on the Zululand Coastal Plain, South Africa can be much reduced by assisting low cost drillers in drilling 6" diameter boreholes using light weight, maneuverable rigs with trained teams which are more cost-effective and provide optimal value for money invested over the lifespan of the borehole. The improved drilling package will allow local drillers to tap into the deeper more sustainable aquifer identified in the area and provide for better borehole construction. The remoteness of the rural population in the Maputaland area, northern KZN, South Africa, influences the degree of groundwater development. Rural water supply infrastructure is minimal and 40 per cent of the rural community is forced to rely on surface water as well as shallow, low cost drilling for water supply. A number of these low cost drillers were investigated to determine their expertise. Results showed that formal training in drilling technology is unavailable in the area. The inexperience of the drillers results in poor borehole construction. Currently low cost drilling is not cost effective as most of these boreholes collapse after a short time. The correct method of drilling in the area is by Direct Mud Rotary (DMR). Professional DMR drilling and borehole construction costs are in excess of US$ 125/m, unaffordable for poor households. We propose that with limited training and suitable equipment the local drillers can halve existing drilling costs, provide quality work as well as focus on good management practices. This will create jobs as well solve the pending water crisis in the area (and elsewhere in Africa).
Estimation of evapotranspiration from pine plantations in the Lake Sibayi catchment and its effect on groundwater and Lake level	Mokhadi	Nchabeleng	KwaZulu-Natal	2015
Abstract POSTER Pine plantations require large amount of water for transpirational demand and the amount of water depend on the area of plantation and the rooting depth of plants. The large amount of water required may result in disturbance of the natural water table equilibrium to meet the demand and insure growth. The lake Sibayi catchment area is covered by the 65 km2 freshwater lake sibaya, 70km2 of pine and eucalypts woody plantations and crops. The lake is recharged dominantly from groundwater and it is a water resource for local communities. A large extraction of groundwater by plantations will decrease the water table and the lake level and that will decrease the amount of water available for local residences. The main aquifer is composed of tertiary to quaternary age sediments which form a thin covering which blankets most of the Maputaland coastal plain and rests on a cretaceous system. Shallow marine and beach deposits of tertiary origin overly the cretaceous aged silt, while the quaternary age sediments which constitute most of the cover are predominantly of Aeolian origin. The Uloa formation of tertiary age is identified to be the most promising aquifer in the region consisting of coarse grained shelly sandstone with calcarenite associated with it. The aquifer is approximately 40m in depth and it is recharged dominantly from rainfall through infiltration. Rainfall averages 900mm per annum over the catchment but varies between 1200mm per annum in the south east and 700mm per annum in the west and evaporation equals to ? 1420 mm per annum (Pitman and Hutchinson, 1975). Lake Sibayi is a freshwater lake of 65km2, in surface area and it is a water resource for surrounding communities and other inhabitants. The sandy substrate surrounding Lake Sibayi limit the amount of surface runoff and consequently the water level within the lake are maintained by groundwater recharge. The growth of plantations is influenced by the ability of trees to extract soil water from the intermediate zone below the root zone and the capillary fringe. The water supply depends on the depth of the water table and on the structure of deposited soil layers and the water table depth is determined by the rate at which vegetation extracts water for transpiration and the recharge rate of groundwater. The specific yield of a soil determines the amount of water that percolates to recharge groundwater and because vegetation extracts water from layers of soils above the water table they decrease the amount of recharge for groundwater.
Investigation of sources and remedial options for high Fe- content in groundwaters around Lake Sibayi	Zinhle	Mnisi	KwaZulu-Natal	2015
Abstract POSTER High iron (Fe) content in the waters of the aquifers around Lake Sibayi is derived from the geological units in which the aquifers are situated. When drawn to the surface the water precipitates solid iron hydroxide [Fe (OH)3] causing a cloudy reddish colour, a condition which is partly caused by the exposure of the high Fe water to the atmosphere. Fe is an essential ion necessary for the growth of people, animals and plants
Preliminary Hydrogeological Investigation Of The Natal Group Sandstone, South Africa	Molla	Demlie	KwaZulu-Natal	2013	Hydrogeological, investigations, Boreholes
Abstract The Paleozoicage Natal Group Sandstone (NGS) that outcrops from Hlabisa (in the north) to Port Shepstone (in the south) and Greytown (west) to Stanger (east) in the Province of KwaZulu-Natal, South Africa, is investigated in terms of its hydrogeological characteristics. This sandstone group, which comprises a lower Durban and an upper Marrianhill Formations, is a secondary/fractured aquifer system that has variable but good productivity across its members. It is characterised by variable borehole blow yields ranging from 0.2 l/s to as high as 20 l/s, with more than 50% of the boreholes having blow yield > 3 l/s. Preliminary analysis of these boreholes yields indicates that higher yielding boreholes are associated with a network of intersecting fractures and faults, and are recommended targets for future water well-siting in the area. Groundwater in the NGS is of good quality in terms of major and trace element composition and it has a total dissolved solids (TDS) composition of <450 mg/l. It was observed that the specific electrical conductivity (EC), TDS and major ions composition of groundwater within the sandstone decrease from north to south, which appears to be controlled by the geochemical composition of the aquifer material and an increase in the rate of recharge. Depth to groundwater is also found to decrease southwards because of an increase in the rate of recharge. Groundwater hydrochemical facies are generally either Na-HCO3 or Na-HCO3–Cl, and environmental isotope data (2H, 18O, Tritium) indicates that the groundwater gets recharge from modern precipitation. Furthermore, the EC increases from inland to the coastal zone, indicating maritime influences and the general direction of groundwater flow is eastwards, to the Indian Ocean.
Groundwater chemical evolution at an underground coal gasification pilot plant in Majuba	Lehlohonolo	Mokhahlane	KwaZulu-Natal	2015
Abstract Underground coal gasification (UCG) is technology that aspires to exploit coal reserves using in-situ gasification. This mining method gasifies coal seams while extracting a syngas that can be used for electricity generation. Since the bulk of this process occurs in the subsurface, there is a possibility of impacting on regional groundwater quality. This paper seeks to assess this impact on groundwater across different aquifers while taking into account the chemical evolution of these aquifers. Three aquifer systems were identified namely the shallow, intermediate and the deep aquifer which comprises of the coal seam. The water chemistry was reviewed over a two year period during which the gasifier was still active. Alkaline conditions were prevalent across the three aquifers with minor seasonal changes. High levels of dissolved solids were observed especially in the deep aquifer but the quality of water was poor even in background samples. The impact of gasification does have small variation in already unusable water in the deep aquifer which was also characterized by low hydraulic conductivity. Higher hydraulic conductivity values were established in the shallow aquifer. No significant groundwater chemistry change was detected in this aquifer as a result of gasification process.
Multivariate Statistical Analysis Of Hydrochemical And Environmental Isotope Data To Characterise The Hydrogeological And Hydrogeochemical System Of The Lake Sibayi Catchment, North-Eastern South Africa	Jannie	Weitz	KwaZulu-Natal	2017	Environmental Isotopes, multivariate statistics, Hydrochemistry, coastal aquifers, Lake Sibayi
Abstract An integrated approach involving multivariate statistical analysis combined with graphical methods (Piper trilinear diagram and δ18O-δ 2H plots), and environmental isotope analyses were successfully applied to characterise the spatial distribution of hydrogeochemical parameters and their controlling factors within the Lake Sibayi catchment located in north-eastern South Africa. Bivariate and Multivariate statistical analyses (Factor and Hierarchical Cluster Analyses) were performed on 12 physiochemical parameters (variables) including pH, EC, TDS and major ions of 46 samples collected from various water sources (streams, Lake, shallow and deep boreholes). Bivariate Pearson’s correlation matrix of the measured variables revealed a strong positive correlation between EC and several major elements, which included Na+ , K+ , Mg2+, Ca2+ , Cland HCO3 - indicating their contribution to the salinity. These major ions were also found to be strongly correlated to one another with all correlations found to be significant. Factor analyses in the form of Principal components analyses were performed with the main aim of identifying the underlying factors or processes responsible for the observed hydrochemistry in the study area. The results revealed three principle factors explained about 95% of the hydrochemical variation in the study area. Most of the variance is contained within Factor-1 (69.5%), which has a high positive loading factor associated with EC, TDS, Na+ , Mg+ and Clconcentrations, interpreted in terms of the contribution of these major ions to the salinity of the water (EC and TDS). Factor-2 represents 17.7% of the total variation in the hydrochemistry and has high positive loadings for pH, HCO3 - , K+ , Ca+ and Fe concentrations. The HCO3 - , K+ and Ca+ could be the result of weathering and dissolution of carbonate minerals in calciferous Uloa and Umkwelane Formations and redox processes. The Fe concentrations could be related to leaching of ferricrete layers known to exist in the area and a result of anoxic condition within the aquifer. The variables NO3 - and SO4 - contribute most strongly to Factor-3, which explains 8.01% of the total variance. The loading for NO3 - was positive and could result from anthropogenic pollution of the shallow aquifer and streams, while that of SO4 - being negative and could result from historical marine influences. Hierarchical cluster analysis of hydrochemical data performed using the Ward method with squared Euclidean distance, grouped the water samples into two clusters, representing unique hydrochemical systems, i.e. surface water and groundwater. Each of these two clusters was in turn divided into two sub-clusters, representing stream and lake samples, and shallow and deep aquifers, respectively. These groupings were further supported by characteristic water types; namely, a Na-Cl-HCO3 facies for the river, lake and surrounding boreholes; a Na-Cl hydrochemical facies for shallow boreholes, while deep borehole samples were Na-Ca-Cl to Na-Cl-HCO3 in composition. These clustering were supported by isotopic signals that show a clear distinction between groundwater and lake water samples.