South Africa is the leading user of pesticides in Sub-Saharan Africa, but data on pesticide occurrence in (ground)water is limited. Consequently, there is a need to improve knowledge on transport pathways that cause pesticides to enter the aquatic environment. This research monitored pesticide concentrations in three agricultural catchments in the Western Cape, South Africa, including Grabouw (pome fruit), Hex River Valley (table grapes), and Piketberg (wheat). Passive samplers were deployed in rivers from March 2022- March 2023, adding to a 2017-2019 dataset of analytical and pesticide application data. Field and laboratory methods were developed at Stellenbosch University to measure pesticides using Liquid Chromatography-Mass Spectrometry. For quality control, duplicate samples were analyzed at Eawag, Switzerland. 30 compounds were detected, yet two/three comprise most of the total mass, including an analyte not considered in earlier investigations (dimethomorph).
Rainfall-flow relationships and agricultural application could only partially explain detection levels, suggesting that other factors, including non-agricultural application or groundwater input, might influence detections. Two compounds exceeded European Environmental Quality Standards (chlorpyrifos and imidacloprid). Imidacloprid is particularly concerning because it exceeded consistently despite few recorded applications. 2017-2022 imidacloprid data indicates a decreasing concentration trend in Hex River Valley and increasing trends in Piketberg and Grabouw. Consistently high detections during wet and dry periods suggest groundwater input. However, such pesticide transport pathways are poorly understood due to a lack of local evidence. Local authorities must establish a long-term monitoring program to understand better the risk pesticides pose to the aquatic environment and human health.