Hydrostratigraphic controls on groundwater arsenic enrichment in the Brahmaputra river basin aquifers

Groundwater arsenic (As) distribution in alluvial floodplains is complex and spatially heterogeneous. Floodplain evolution plays a crucial role in the fate and mobilization of As in the groundwater. This study presents how groundwater As enrichment is controlled by the spatial disposition of subsurface sand, silt, and clay layers along an N-S transect across the Brahmaputra river basin aquifer. Six boreholes were drilled in the shallow aquifer (up to 60 m) along this transect, and 56 groundwater samples were collected and analysed for their major and trace elements, SO4, PO4, dissolved organic carbon (DOC), and dissolved oxygen (DO). Groundwater As ranges from 0.1 to 218 μg/L on the northern bank while from 0.2 to 440 μg/L on the southern bank of the Brahmaputra. Groundwater in the southern bank is highly reduced (Eh -9.8 mV) with low DO and low SO4 (2 mg/L), while groundwater in the north is less reduced (Eh 142 mV) with low DO and higher SO4 (11 mg/L). Subsurface lithologies show that the aquifer on the southern bank has a very thick clay layer, while the aquifer on the northern bank is heterogeneous and interlayered with intermediate clay layers. Depth comparison of the groundwater arsenic concentrations with subsurface lithological variations reveals that groundwater wells overlain by thick clay layers have higher arsenic, while groundwater wells devoid of clay capping have lesser arsenic. Detailed aquifer mapping could be decisive in exploring potentially safe groundwater from geogenic contamination.