Conference Abstracts

All Abstracts were presented at the Groundwater Conferences

Displaying 151 - 200 of 795 results
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Abstract

Multi-data integration approach was used to assess groundwater potential in an area consisting crystalline basement and carbonate rocks that are located in the North West Province of South Africa. The main objective of the study is to evaluate the groundwater resource potential of the region based on a thorough analysis of existing data combined with field observation. Integration of six thematic layers was supplemented by a statistical analysis of the relationship between lineaments density and borehole yield. Prior to data integration, weighting coefficients were computed using principal component analysis.
The resulting thematic layer derived from integration of the six layers revealed a number of groundwater potential zones. The most probable groundwater potential zones cover ~14% of the entire study area and located within carbonate rocks consisting limestone and dolomite. The presence of pre-existing structures together with younger and coarse sedimentary rocks deposited atop the carbonate rocks played a significant role in the development of high well fields in the southern part of the area. Moderate-to-high groundwater potential zones within Ventersdorp lava coincide with maximum concentrations of fractures. The results of statistical correlation suggest that 62% of high borehole yield within the Ventersdorp lave can be attributed to fracture density. In general, the present approach is very effective in delineating potential targets and can be used as a sound scientific basis for further detailed groundwater investigation.
KEY WORDS:- Multi-data, thematic layers, groundwater, carbonate rocks, structures

Abstract

Acid mine drainage (AMD) has lately received considerable media coverage in South Africa. This has caused considerable increase in researchers most of them with emphasis on decantation of contaminated water from the old gold mines in Witwatersrand basins and fewer on mine residue contamination from Coal and Gold mines in Mpumalanga and Limpopo provinces. The paper outlines results of ground geophysical surveys that were carried out along the perimeter of two mine dumps in the Barberton Greenstone belt in the Mpumalanga Province, South Africa. The aim of the study was to generate a 3D geo-electric model of the subsurface showing possible acid mine drainage contaminant pathways. Two geophysical methods namely Frequency Domain Electromagnetic profiling (FDEM) and electrical resistivity tomography (ERT) were applied in order to investigate the variation of electrical conductivity in the subsurface. ERT method was done over frequency domain electromagnetics anomalies to further investigate depth extent of the anomalies.
{List only- not presented}

On the resistivity section ERT1 of Dump 1, a discontinuity in the bedrock was identified. The FDEM survey identified an area with high conductivity values to the north of Dump 1. The ERT results show a shallow plume at 20m depth, which is consistent on two parallel sections on Dump 1. The area could be a possible pathway of mine dump residue (AMD) to a stream in the north. The bedrock is generally characterized by high resistivity values; a break in the bedrock exists on this high resistivity zone on ERT 6. The identified breaks in the bedrock in terms of resistivity could be a fault zone which can act as possible pathway of mine dump residue (AMD) to a shallow aquifer.

Potential contaminant recharge pathways were delineated using geophysical electrical and electromagnetic methods. Potential groundwater recharge pathways and sub-vertical low resistivity zones with values <100 Ohm.m were delineated using the ERT method. Investigation of contaminant plume migration is recommended over the anomalies that were generated from geophysics data in the Barberton areas.

KEYWORDS
Acid mine drainage, Frequency Domain Electromagnetic profiling and electrical resistivity tomography

Abstract

POSTER The improvement in horizontal drilling and hydraulic fracturing techniques has resulted in the exploitation of gas associated with low-permeability organic-rich shale formations in the United States of America (USA) to become one of the most important energy resources. The USA experience has resulted in renewed exploration interest in the shale formations in the main Karoo Basin. The basins consist of sediments of the Karoo Supergroup, which were deposited during the Late Palaeozoic-Early Mesozoic. Typically, South Africa has been heavily reliant on coal for its primary energy supply, but currently, the country is seeking to develop alternative sources in order to diversify its energy sources. In the Karoo basin, the Whitehill Formation is the most prospective shale gas target. The neighbouring shales such as the Prince Albert Formation are of commercial interest, particularly if the Prince Albert Formation is exploited as an extension of the Whitehill play. Water management has emerged as being crucial for the sustainable development of unconventional gas resources in particular the risks to groundwater resources. This study attempts to develop a conceptual model of deep basin groundwater flow systems in the main Karoo Basin. The conceptual model aims to inform possible solution to protect groundwater resources. This will be done by investigating possible scenarios for interaction between deep and shallow aquifers as to establish possible migration pathways of flowback and produced water that would lead to possible pollution to shallow Karoo aquifers during and/or after the hydraulic fracturing process or activities in the main Karoo Basin.

Abstract

The 'maintainable aquifer yield' can be defined as a yield that can be maintained indefinitely without mining an aquifer. It is a yield that can be met by a combination of reduced discharge, induced recharge and reduced storage, and results in a new dynamic equilibrium of an aquifer system. It does not directly or solely depend on natural recharge rates. Whether long-term abstraction of the 'maintainable aquifer yield' can be considered sustainable groundwater use should be based on a socio-economic-environmental decision, by relevant stakeholders and authorities, over the conditions at this new dynamic equilibrium.
This description of aquifer yields is well established scientifically and referred to as the Capture Principle, and the link to groundwater use sustainability is also well established. However, implementation of the Capture Principle remains incomplete. Water balance type calculations persist, in which sustainability is linked directly to some portion of recharge, and aquifers with high use compared to recharge are considered stressed or over-allocated. Application of the water balance type approach to sustainability may lead to groundwater being underutilised.
Implementation of the capture principle is hindered because the approach is intertwined with adaptive management: not all information can be known upfront, the future dynamic equilibrium must be estimated, and management decisions updated as more information is available. This is awkward to regulate.
This paper presents a Decision Framework designed to support implementation of the capture principle in groundwater management. The Decision framework combines a collection of various measures. At its centre, it provides an accessible description of the theory underlying the capture principle, and describes the ideal approach for the development operating rules based on a capture principle groundwater assessment. Sustainability indicators are incorporated to guide a groundwater user through the necessary cycles of adaptive management in updating initial estimations of the future dynamic equilibrium. Furthermore, the capture principle approach to sustainable groundwater use requires a socio-economic-environmental decision to be taken by wide relevant stakeholders, and recommendations for a hydrogeologists' contribution to this decision are also provided. Applying the decision framework in several settings highlights that aquifer assessment often lags far behind infrastructure development, and that abstraction often proceeds without an estimation of future impacts, and without qualification of the source of abstracted water, confirming the need for enhanced implementation of the capture principle.

Abstract

The way in which groundwater is utilized and managed in South Africa is currently being reconsidered, and injection wells offer numerous possibilities for the storage, disposal and abstraction of the groundwater resource for municipalities, rural communities, mining, oil and gas, and a multitude of other industries. This presentation is about the North Lee County Reverse Osmosis Water Treatment Plant Injection Deep Injection Well project in southwest Florida in the United States. Water is plentiful in Florida, but it is not drinking water quality when it comes out of the ground. As such, treating water from wells is an important part of water supply in the coastal regions of the state. One form of treatment is reverse osmosis (RO), which generates a brine concentrate waste. The concentrate must then be disposed of, and a preferred method of disposal is an injection well because the disposal is not visible to the general public. The injection well project was associated with the construction of a large water treatment plant. The emphasis of this presentation is on the drilling and technical work in the field for this injection well, and to illustrate the rigorous requirements of drilling, constructing and testing a Class I injection well. Class I injection wells are permitted by the United States Environmental Protection Agency (US EPA) for injecting hazardous waste, industrial non-hazardous liquid, and/or municipal wastewater beneath the lowermost Underground Source of Drinking Water (USDW). Aquifer storage and recovery (ASR) wells are permitted as Class V injection wells by the US EPA. The permitting of an injection well is rigorous and requires state and federal approval before, during and after the field portion of the project. {List only- not presented}

Abstract

POSTER The Department of Water and Sanitation (DWS) is the custodian of South Africa's water and thus is imperative that it reports on its state as the National Water Act of 1998 requires regular reporting to Parliament by the Minister. Hence, the annual compilation of report entitled "The National State of Water in South Africa." This report aims to give an overview of the status and trends of water quality and quantity, further assisting with international water reporting obligations to SADC Region, African Continent, and Globally e.g. the United Nations Commission on Sustainable Development. This information empowers the public and provides knowledge to water managers for informed decision-making. The main purpose is to enhance quality, accessibility and relevance of data and information relating to the goal of Integrated Water Resource Management towards attaining holistic Integrated Water Management, and Integrated Water Cycle Management in future. Three distinct requirements for collecting data by DWS are: (i) assessing and comparing the status and trends for both quantity and quality; (ii) monitoring for water use and (iii) monitoring for compliance to licence conditions. Such information is further used to assess the effectiveness of policies implemented and identify the existing gaps. Various challenges to the country's water demand proper integrated water resources planning and management. The report is divided into Themes such as, Resource Management, Water Services/Delivery, Water Development and Finance, based on selected indicators. The indicators are strategically selected to provide a representative picture of the state, as well as the changes over time to the drivers, pressures, impacts and responses related to the chosen themes. These Indicators include: Climatic Conditions, Water Availability, Water Use, Water Protection, Water Quality, Water Service Delivery, Water Infrastructure, Water Finance, and Sanitation. The report for Hydrological Year 2013/2014 has been completed and it shows that the amount of water available varies greatly between different places and seasons, and from one year to another. The average total storage was around 85% of full supply capacity in September 2014. Surface water quality is generally facing a threat from eutrophication and microbial pollution emanating mainly from mismanaged water (and waste) treatment plants and related landuse activities. Groundwater quality is generally good except in some localised areas where mining and industrial activities are prevalent. With regards to infrastructure; vandalism, lack of maintenance & management skills reflect on/as non-revenue water, highlighting the need for more funding towards maintenance, especially in groundwater which is normally wrongly deemed as an unreliable resource. In the past 20 years, water services delivery to communities has improved as the Millennium Development Goals have been met and surpassed, while the sanitation access goals were likely to be met.

Abstract

South Africa is facing a water supply crisis caused by a combination of low rainfall, high evaporation rates, and a growing population whose geographical demands for water do not conform to the distribution of exploitable water supplies. This situation is particularly critical in the river systems comprising the Limpopo River basin where every tributary river has been exploited to the limits possible by conventional engineering approaches. These attempts to meet society's demands for water for domestic, irrigation, mining and industrial uses have caused a progressive deterioration of the water resources as well as the aquatic ecosystems in these rivers. In addition to the pressure exerted by scarce water resources and deteriorating water quality, South Africa is facing a critical shortage of electrical power. There is an urgent need to address the country's electricity shortage through the building of new coal mines and coal fired power and the Waterberg area has been identified for these purposes. All of these new operations will be accompanied by a rapid growth in population which will put further stress on the water resources as well as the existing sewage plants. The Waterberg region is part of the Bushveld which can be classified as a hot and an arid region. Due to irrigation that currently exist in the region, which stems from the climate conductive to agriculture production and its current mining development, based on the vast mineral deposits present, the current water availability and water use in the Waterberg region is relatively in balance. Meaning that the available water resources in the Limpopo basin will not be able to meet the domestic and industrial demands for water that the new developments will pose and the flows in several rivers have already changed from perennial to seasonal and episodic. In order to satisfy the demand of water that will be required by the above mentioned projects, the Mokolo Crocodile Water Augmentation Project will supply additional water to the region. However, this area still contains a relatively high number of natural or near-natural ecosystems, and it is important that this natural capital is not significantly eroded in the development process. This is possible with effective environmental planning to limit and mitigate negative social, ecological and economic impacts.

This project promotes science-based environmental assessment and planning by developing an understanding of key aquatic ecological indicators and their associated thresholds. The project vision is to promote improved outcomes for stream and river ecosystem health, and ultimately human health and well-being in the Waterberg area. The outcomes of the study will be used to detect existing processes of change in aquatic ecosystems and estimate the likely future changes that increased coal mining, human population and water transfers will cause.

Abstract

A Waste Water Treatment Works (WWTW) is being constructed at Pearly Beach. A geohydrological assessment was conducted to assess the potential discharge of treated effluent above and below the subsurface calcrete layers. A hydrocensus has been completed of the area to confirm there is no use of groundwater down-gradient of the WWTW and there is no likely impact on ecosystem functioning. Based on existing boreholes, infiltration above the calcrete layer in the vadose zone was found to be more efficient. A geophysical study was conducted to determine the optimal locations of boreholes for disposal of the treated effluent. The geophysics included an extensive electromagnetic (EM) survey. Resistivity data were acquired along a single resistivity profile to use as calibration for the EM data. This information has been correlated with borehole information from the monitoring boreholes that were drilled at the proposed WWTW site. From this information it would seem that the areas with higher conductivity (lower resistivity) can be targeted for drilling boreholes to dispose of the treated effluent. Also, the higher conductivity areas are interpreted as the areas with increased porosity. However, the change in conductivity could result from an increase in salinity or changes in calcrete content in the subsurface. The expected depth of the unconsolidated sand formations is generally less than 10 m based on the interpreted depth of the saturated formation from the resistivity data. Drilling will target the unconsolidated sands, as well as potential higher porosity zones beneath the calcrete. The geophysics data should then be calibrated with the information obtained from drilling the first borehole. The other sites can then be confirmed or reviewed based on the information. The boreholes are to be drilled soon and pump tested. The obvious concern is that the boreholes may clog, however measures will be put in place to minimise this risk. A detailed monitoring network will also be established. On-going monitoring is crucial to ensure the success of the scheme. The full conference paper will include the drilling and pump testing results and infiltration tests. This method of disposal needs to be taken into consideration especially if such schemes can be run successfully so that another option is available for the disposal of treated effluent. {List only- not presented}

Abstract

Pollution of underground water is fast becoming a global problem and South Africa is not immune to this problem. The principal objective of this paper is to investigate the effectiveness of laws and policies put in place to mitigate underground water pollution. The paper also seeks to examine the causes and types of underground water pollution followed by a closer look into the laws and policies in place to mitigate the pollution levels. Finally, the paper seeks to ascertain whether the current policies are properly implemented. The paper follows content analysis (desk research) to achieve the objectives. Policy recommendations are given based on the findings. {List only- not presented}

Abstract

Inadequate characterization of petroleum release sites often leads to the design and implementation of inappropriate remedial systems, which do not achieve the required remedial objectives or are inefficient in addressing the identified risk drivers, running for lengthy periods of time with little benefit. It has been recognized that high resolution site characterization can provide the necessary level of information to allow for appropriate solutions to be implemented. Although the initial cost of characterization is higher, the long-term costs can be substantially reduced and the remedial benefits far greater. The authors will discuss a case study site in the Karoo, South Africa, where ERM has utilized our fractured rock toolbox approach to conduct high resolution characterization of a petroleum release incident to inform the most practical and appropriate remedial approach. The incident occurred when a leak from a subsurface petrol line caused the release of approximately 9 000 litres of fuel into the fractured sedimentary bedrock formation beneath the site. Methods of characterization included:
- Surface geological mapping of regionally observed geological outcrops to determine the structural orientation of the underlying bedding planes and jointing systems;
- A surface electrical resistivity geophysics assessment for interpretation of underlying geological and hydrogeological structures;
- Installation of groundwater monitoring wells to delineate the extent of contamination;
- Diamond core drilling to obtain rock cores from the formation for assessment of structural characteristics and the presence of hydrocarbons by means of black light fluorescence screening and hydrocarbon detection dyes;
- Down-borehole geophysical profiling to determine fracture location, fracture density, fracture dip and joint orientation; and
- Down-borehole deployment of Flexible Underground Technologies (FLUTe?) liners to determine the precise vertical location of light non-aqueous phase liquid (LNAPL) bearing joint systems and fracture zones, and to assist in determining the vertical extent of transmissive fractures zones.
ERM used the information obtained from the characterization to compile a remedial action plan to identify suitable remedial strategies for mitigating the effects of the contamination and to target optimal areas of the site for pilot testing of the selected remedial methods. Following successful trials of a variety of methods for LNAPL removal, ERM selected the most appropriate and efficient technique for full-scale implementation.
{List only- not presented}

Abstract

POSTER The Jeffreys Bay Municipal borehole field is located in the coastal town of Jeffreys Bay, Eastern Cape Province, South Africa. It is underlain by the Jeffreys arch domain which features the Skurveberg and Baviaanskloof formations of the Table Mountain Group. The Jeffreys arch has been subject to groundwater exploration, targeting its characteristic faults and folds. The investigation was intended to establish five (5) high yielding boreholes with good water quality. Geophysical surveys, drilling and pump tests were conducted in succession. Ground surveys were carried out across the study area using the electromagnetic method to identify subsurface geological structures through anomalies in the earth's magnetic field. The interpretation of the data revealed significant anomalies within an anticlinorium. Drilling through quartz and quartzitic sandstone posed considerable difficulties mostly along zones of oxidation. The main water strikes with airlift yields of 9 - 35 L/s were intersected within quartzitic sandstone at depths of about 120m and greater. Chemical sampling results revealed adherence of iron and manganese concentrations to the drinking water recommended limits as per SANS 241-1 (2011). Two (2) of the five (5) boreholes revealed higher than recommended of iron and manganese concentrations. The aquifer test data was processed using the Flow Characteristic programme, the recommended abstraction rates range between 4-17 L/s/24 hrs. Results observed during different exploration phases revealed high yields and good water quality with greater depths as compared to the existing shallow boreholes with high iron, conductivity and manganese concentrations. Treatment of borehole water with high concentrations is necessary. It is recommended that drilling for groundwater resources within the anticlinorium of the Jeffreys arch be done at great depths.

Abstract

Changes to South African water law and policy since the mid-90s have promoted integrated water resource management (IWRM) and the wider application of the principle of subsidiarity (decentralization), underpinned by the Constitutional emphasis on equity, human rights and redress. New water management organisations aim to promote equity, universal access to water, economic prosperity and gender equality but the reality, especially for groundwater, is less inspiring. The Water Act of 1998 envisages new organisations including Catchment Management Agencies (CMAs), Water User Organisations (WUAs) and Water Service Authorities (WSAs), but in many cases these organisations have inadequate capacity or do not exist at all. Only two of the nine (formerly nineteen) CMAs have been formed in more than fifteen years, and neither is yet financially self-reliant. The onerous process necessary to found a WUA and other disincentives have meant that fully-fledged WUAs as envisaged by the Water Act are rare. Hydrogeologists are unusual at Water Service Authority level, and the Department of Water and Sanitation (DWS) still assesses most groundwater resources. This has stoked argument between DWS and WSAs over long-term sustainable municipal water supplies. Our mandated organisations are not delivering the outcomes for groundwater that policy makers envisaged. Municipalities campaign for surface water instead of groundwater, yet groundwater is still the mainstay of rural water supply and has the most promise for underserved areas. Intractable problems with operation and maintenance are wrongly blamed on the primary groundwater resource, or on "shortages" of one kind or another. There is a need to emphasise function and outcomes rather than trust that these will follow automatically once "the right" organisations are in place. A hybrid of top-down expertise with a genuine focus on local outcomes is called for. We currently pay a considerable opportunity cost for delays, turf-wars and finger pointing - including reputational damage to groundwater as well as less reliable water supplies for the poorest South Africans.

Abstract

The present study applied multivariate statistical analysis (MSA) to investigate the status of the hydrochemistry of groundwater Upper Berg River Catchment, Western Cape, South Africa. Factors that influence the quality of groundwater are well established. The aim of the present study was to characterize groundwater quality in the Upper Berg River Catchment, using multivariate statistical analysis methods in order to establish the evolution and suitability of such waters for agricultural use in addition to confirming major factors that explain groundwater quality in the study area. Principal Component Analysis (PCA) and Hierarchical Cluster Analysis (CA) were applied to groundwater physicochemical data that were collected from 30 boreholes. Data collection and analysis followed standard procedure. The use of a Piper Diagram showed that Na-Cl water types were the predominant groundwater facies. Furthermore, PCA extracted five major factors that explained 83.11 % of the variation in the physicochemical characteristics of groundwater. Using Varimax rotation, two main factors, namely, surface water recharge and rock-water interactions, were extracted which collectively explained 60.81% of the variation in the groundwater physicochemical data. The two factors indicate that the predominant factors affecting groundwater quality in the study area are natural (biochemical) processes in the subsurface as well as interactions between the rock matrix and passing water. Cluster Analysis extracted three major groundwater clusters based on dissimilarities in groundwater physicochemical characteristics in different sites. The first cluster included 7 borehole sites located in the Franschhoek Valley area and 14 borehole sites located in the Robertsvlei Saddle area as well as the upper catchment (behind the Berg River Dam). The second and third clusters collectively included 9 groundwater sites within the Franschhoek Valley area. These sites were located on agricultural land where extensive vineyard and orchid cultivation is done. Groundwater quality in the Upper Berg River Catchment mainly reflects the influence of natural process of recharge, rock-water interactions and microbial activity. The quality of groundwater fell within Target Water Quality Guidelines for agricultural water use published by the Department of Water and Forestry Affairs meaning such waters are suitable for agricultural use.

Key words: Dendrogram, Groundwater quality, Hierarchical Cluster Analysis, Principal Component Analysis, Physicochemical, Spatial.

Abstract

Data acquisition and Management (DAM) is a group of activities relating to the planning, development, implementation and administration of systems for the acquisition, storage, security, retrieval, dissemination, archiving and disposal of data. Data is the life blood of an organization and the Department of Water and Sanitation (DWS) is mandated by the National Water Act (No 36 of 1998) as well as the Water Services Act (No 108 of 1997), to provide useful water related information to decision makers in a timely and efficient manner. In 2009 the DWS National Water Monitoring Committee (NWMC) established the DAM as its subcommittee. The purpose was to ensure coordination and collaboration in the acquisition and management of water related data in support of water monitoring programs. The DAM subcommittee has relatively been inactive over the years and this has led to many unresolved data issues. The data extracted from the DWS Data Acquisition and Management Systems (DAMS) is usually not stored in the same formats. As a result, most of the data is fragmented, disintegrated and not easily accessible, making it inefficient for water managers to use the data to make water related decisions. The lack of standardization of data collection, storage, archiving and dissemination methods as well as insufficient collaboration with external institutions in terms of data sharing, negatively affects the management water resources. Therefore, there is an urgent need to establish and implement a DAM Strategy for the DWS and water sector, in order to maintain and improve data quality, accuracy, availability, accessibility and security. The proposed DAM Strategy is composed of the six main implementation phases, viz. (1) Identification of stakeholders and role players as well as their roles and responsibilities in the DWS DAM. (2) Definition of the role of DAM in the data and information management value chain for the DWS. (3) Development of a strategy for communication of data needs and issues. (4) Development of a DAM life Cycle (DAMLC). (5) Review of existing DAMS in the DWS. (6) Review of current data quality standards. The proposed DAM Strategy is currently being implemented on the DWS Groundwater DAM. The purpose of this paper is to share the interesting results obtained thus far, and to seek feedback from the water sector community.

Abstract

Hydrogeological environments are commonly determined by the type of underlying geology; these environments may have a tremendous effect on the mobility and recovery of LNAPLs.  Hydrogeological environment include intergranular sediments and bedrocks of contrasting permeability and porosity. This paper synthesizes several case studies and conceptual models of different hydrological environments and illustrates how they affect the flow characteristics and rebound of LNAPLs.

Abstract

Lake Sibayi (a topographically closed fresh water lake) and coastal aquifers around the lake are important water resources, which the ecology and local community depend on. Both the lake and groundwater support an important and ecologically sensitive wetland system in the area.
Surface and subsurface geological information, groundwater head, hydrochemical and environmental isotope data were analysed to develop a conceptual model of aquifer-lake interaction which would later be integrated into the three dimensional numerical model for the area. Local geologic, groundwater head distribution, lake level, hydrochemistry and environmental isotope data confirm a direct hydraulic link between groundwater and the lake. In the western section of the catchment, groundwater feeds the lake as the groundwater head is above lake stage, whereas along the eastern section, the presence of mixing between lake and groundwater isotopic compositions indicates that the lake recharges the aquifer. Stable isotope signals further revealed the movement of lake water through and below the coastal dune cordon before discharging into the Indian Ocean. Quantification of the 9 year monthly water balance for the lake shows strong season variations of the water balance components. Based on lake volume and flow through rate, it was further noted that the average residence time for water in the lake was about 6 years.
A recent increase in the rate of water abstraction from the lake combined with decreasing rainfall and rapidly increasing plantations in the catchment may result in a decrease in lake levels. This would have dramatic negative effects on the neighbouring ecosystem and allow for potential seawater invasion of the coastal aquifer.

Abstract

Quantification of groundwater is important as it should determine the maximum sustainable use of the resource. The SAMREC Code that is required for mineral resource quantification sets out minimum standards, guidelines and recommendations for public reporting of exploration results for mineral resources and reserves. The code serves as the basis for mineral asset valuation and provides quality assurance to the process and an understanding of the results. In groundwater far too often, various methods are used for resource quantification that leads to various results even should the same resource be investigated by two different hydrogeologists. In far too many cases, the resource is not quantified properly which leads to vast over or under estimations. The result is a lack of trust in groundwater resources. As has been done in the international arena, it is similarly proposed that a code be developed for South Africa to ensure that the sustainability of groundwater resources is determined and the impacts of utilization on the water Reserve and the environment be quantified at a minimum level and that basic hydrogeological principles are followed. A South African Groundwater Regulation Code for sustainable resource quantification and impact assessment (SAGREC) is developed that is proposed to guide groundwater investigations and development processes from planning to baseline assessments, drilling and aquifer testing to resource quantification and sustainability modeling. The aim is to ensure trust being built on groundwater as a resource due to projects that follow a formal process that quantifies the assurance of supply and determines the environmental impacts.

Abstract

The intangible nature of groundwater provides challenges when trying to understand and quantify the role of groundwater in the hydrology of lakes and wetlands. This task is made even more difficult by the frequent absence of data. However, by adopting a scientific approach, it is possible to assess the hydrogeological contribution

Abstract

Different biological and chemical transport results are evaluated in this study. Ecoli and PDR1 were selected as the biological tracers with salt and rhodamine as chemical tracers. The transport experiments were evaluated through the primary aquifer material found at the University of the Western Cape research site. A series of controlled experiments under laboratory and field conditions was conducted. Each provides a different kind of data and information. The results from laboratory studies could be used to better design the field studies. In both cases, the data collected was to provide information on fate and transport of microbes in groundwater. The field design phase of the experiment was an up-scaling of the laboratory phase of this project. The amount injected into the aquifer was increased in proportion to the size of the research site. Tracer tests using chemical and microbial tracers were carried out simultaneously. Results of laboratory tests show a 5 times slower transport of microbes, compared to salts.. The salts at field scale show a breakthrough occurring after 2 days whereas the microbes never managed to breakthrough with the experiment stopped after 45 days. A new borehole was drilled closer to reduce distance/ travel time, but this had no effect on field results for the microbes. {List only- not presented}

Abstract

This study intent to share the legal and institutional analysis of the UNESCO IHP project "Groundwater Resources Governance in Transboundary Aquifers" (GGRETA) project for the Stampriet Transboundary aquifer. The Intergovernmental Council (IGC) of the UNESCO International Hydrological Programme (IHP) at its 20th Session requested the UNESCO-IHP to continue the Study and Assessment of Transboundary Aquifers and Groundwater Resources and encouraged UNESCO Member States to cooperate on the study of their transboundary aquifers, with the support of the IHP. The GGRETA project includes three case studies: the Trifinio aquifer in Central America, the Pretashkent aquifer in central Asia and the Stampriet aquifer in southern Africa. This study focuses on the Stampriet Transboundary Aquifer System that straddles the border between Botswana, Namibia and South Africa. The Stampriet system is an important strategic resource for the three countries. In Namibia the aquifer is the main source of water supply for agricultural development and urban centers in the region, in Botswana the aquifer supplies settlements and livestock while in South Africa the aquifer supplies livestock ranches and a game reserve. The project methodology is based on UNESCO's Shared Aquifer Resources Management (ISARM) guidelines and their multidisciplinary approach to transboundary aquifers governance and management, addressing hydrogeological, socio-economic, legal, institutional and environmental aspects. The GGRETA builds recognition of the shared nature of the resource, and mutual trust through joint fact finding and science based analysis and diagnostics. This began with collection and processing of legal and institutional data at the national level using a standardized set of variables developed by the International Groundwater Resources Assessment Center (IGRAC). This was followed by harmonization of the national data using common classifications, reference systems, language, formats and derive indicators from the variables. The harmonized data provided the basis for an integrated assessment of the Stampriet transboundary aquifer. The data assisted the case study countries to set priorities for further collaborative work on the aquifer and to reach consensus on the scope and content of multicountry consultation mechanism aimed at improving the sustainable management of the aquifer. The project also includes training for national representatives in international law applied to transboundary aquifers and methodology for improving inter-country cooperation. This methodology has been developed in the framework of UNESCO's Potential Conflict Cooperation Potential (PCCP) program. The on-going study also includes consultation with stakeholders to provide feedback on proposals for multicountry cooperation mechanisms. It is anticipated that upon completion of the study, a joint governance model shall have been drawn amongst the three countries sharing the aquifer to ensure a mutual resource management.

Abstract

In order to obtain a better understanding of a groundwater system, it is very important to understand the recharge mechanisms of such a system. Several intensive investigations have been done, documenting the different methodologies to derive recharge. Most of these studies have been centred on the detailed analysis and description of isotopes, which are either a characteristic of the water, the rock, or both. The isotopes of strontium, in particular the isotopic 87Sr/86Sr ratio, is one of such methodologies applied to drive the sources of recharge. The Oshivelo management area is part of the greater Owambo Basin, with no major rivers flowing through the project area, while the Omuramba Owambo, which crosses the area from east to west, bears water only rarely. This rural area therefore heavily relies on groundwater resources. Towards the end of the 20th century, through exploratory drillings an artesian aquifer in the southern part of the Owambo basin was discovered. Several investigation and water supply boreholes have been drilled, with the major findings summarised: - In the late 1990s DWA (DWA, 1999) drilled 12 exploration boreholes and six observation boreholes, showing high yields ranging between 40 and 200 m?/h. One of the boreholes yielded saline water, classified under the Oshivelo Artesian Aquifer and it was recognized that there may be a risk of saltwater intrusion when beginning to exploit the aquifer. It was assumed that the aquifer receives local recharge from the Etosha Limestone Member aquifer in the order of 3.75 MCM/a and additional unquantified recharge from the Otavi Dolomite Aquifer. - In the early 2000s KfW funded a study of the Tsumeb area, including the development of a groundwater flow model according to which an amount of 31 MCM/a would be leaving the Tsumeb area at the northern model boundary, i.e. flow into the Oshivelo Region. - The DWA plans to supply the north-western Oshikoto Region with water from the KOV2 aquifer via a pipeline in order to overcome water shortages there and to become more independent from surface water supplies from Angola. Though, through the groundwater model, a first estimate of groundwater resources availability has been established, the source of recharge is yet to be determined, including the flow mechanisms. Without, this vital piece of information, a valuable groundwater resource may be eventually utilized unsustainably. This presentation will focus primarily on the determination of groundwater recharge mechanisms, which would produce additional input to refine the existing groundwater flow model, concentrating on the Oshivelo Aquifer system. Upon the successful completion of this investigation, the next step would then be to evaluate the groundwater flow model and use it for a proper groundwater management plan. {List only- not presented}

Abstract

Noble gases are used in this study to investigate the recharge thermometry and apparent groundwater residence time of the aquifers on the eastern slope of the Wasatch Mountains in the Snyderville Basin of Summit County, Utah. Recharge to and residence time for the basin aquifer in the Salt Lake Valley, Utah, from the western slope of the Wasatch Mountain range by 'mountain-block recharge' (MBR), is a significant source of subsurface flow based on noble gas and tritium (3H) data. The Snyderville Basin recharge thermometry from 15 wells and 2 springs indicates recharge temperatures fall within the temperature "lapse space" defined by the recharge thermometry determined in the study of MBR for the Salt Lake Valley and the mean annual lapse rate for the area. Groundwater residence times for the Snyderville Basin were obtained using tritium and helium-3 (3He). The initial 3H concentrations calculated for the samples were evaluated relative to the 3H levels in the early 1950s (pre-bomb) to categorize the waters as: (1) dominantly pre-bomb; (2) dominantly modern; or (3) a mixture of pre-bomb and modern. Apparent ages range from almost 6 years to more than 50 years. Terrigenic helium-4 (4He) is also used as a groundwater dating tool with the relationship between terrigenic 4He in Snyderville Basin aquifers and age based on the apparent 3H/3He ages of samples containing water from only one distinct time period. The 4He is then used to calculate groundwater residence times for samples that are too old to be dated using the 3H/3He method. The mean groundwater residence times calculated with both methods indicate the water yielded by wells and springs in the Snyderville Basin generally ranges from 6 to more than 50 years. In addition, the calculated terrigenic 4He age for the pre-bomb component of many samples was found to exceed 100 years. While terrigenic 4He residence times are not as definitive as those calculated with the 3H/3He method, or chlorofluorocarbons (CFCs), age dating with terrigenic 4He allows initial estimates to be made for groundwater residence times in the Snyderville Basin, and is an important tool for establishing groundwater residence times greater than 50 years. Historic water levels from production wells indicate a declining water table. This trend in conjunction with precipitation data for the area illustrates the decline in the water levels to be a function of pumping from the aquifers. Groundwater residence times in the Snyderville Basin and declining water levels support the need for a groundwater management program in the Snyderville Basin to effectively sustain the use of groundwater resources based on groundwater age. {List only- not presented}

Abstract

Vapour intrusion (VI) is recognized to drive human health risk at numerous sites that have been contaminated by petroleum products and other volatile contaminants. The risks related to VI are typically evaluated using direct measurement (vapour sampling) or modelling methods. ERM has developed a toolbox approach using a combination of exclusion distance criteria, direct measurement and modelling methods to assess risks and achieve closure. For direct measurement, samples of vapour are taken beneath the floor slab of buildings (sub-slab sampling) or from the air inside the buildings (indoor air sampling). Modelling methods are often used to estimate the partitioning of volatile contaminants from soil or groundwater sources into the vapour phase and the subsequent transport of vapours from the subsurface environment into habitable buildings. A limitation of modelling approaches is that they are designed to be conservative to be adequately protective of sensitive receptors. VI models also do not typically take into account the degradation of hydrocarbon vapours in the presence of oxygen, which has been found to be a significant process for petroleum hydrocarbons. The authors have compiled a dataset of petroleum vapour and groundwater results from over 50 petroleum release sites in southern Africa. These data were used to develop exclusion distance criteria for vapours emitted from contaminated groundwater sources (i.e. distance from the source at which sufficient aerobic attenuation has occurred for the VI risk to be negligible). A standard "lines of evidence" approach has been applied to the assessment of VI risk by firstly applying the exclusion distance criteria to sites with groundwater contaminant plumes beneath buildings, and if these are met, the sites are considered to have no unacceptable VI risk. Where exclusion screening criteria are not met, risk is estimated using modelling, and if a potential risk is predicted, then direct sub-slab measurements are taken to more accurately assess the risk. Lastly, where sub-slab assessment predicts a potential VI risk, indoor vapour measurement are taken to evaluate actual risk, taking into account interferences from other sources and background levels of contaminants. Mitigating measures can then be applied as appropriate. Various case studies will be presented including direct measurements at industrial and residential sites overlying contaminant plumes and modelling methods at residential properties adjacent to service station sites. A risk-based approach to the assessment of contaminated land provides a sustainable and cost effective methodology, and also avoids unnecessary remediation. The results show that VI risks can be adequately addressed with a toolbox approach using multiple lines of evidence.

Abstract

Collecting groundwater information close to the ocean often raises the question whether a tidal effect could be influencing the data. Sometimes this issue leads to speculation that is counterproductive and sometimes it is overlooked thereby causing judgement errors when interpreting data. This paper looks at the theoretical background of tidal influences in coastal aquifers to identify the screening factors to consider when deciding whether a contaminated site assessment needs to take tidal influences into account. The rising and falling of the tides cause a standing wave with varying frequency that is dampened by the neighbouring aquifer as the wave travels into it. Unconfined aquifers generally tend to be affected over a short distance, while the pressure wave can travel significant distances in a confined aquifer. There are indications that the rise and fall of the tides prevent discharge of the LNAPL, but it could cause lateral spreading due to the head changes in the aquifer. The tidal fluctuation also causes uncertainties in the LNAPL measurements. The case study presents data from a site where tidal variation directly influences the distribution of LNAPL in monitoring holes, while the variation in total fluid level is slight. In this specific case the tidal variation has to be accounted for, otherwise skewed measurement data will be collected.

Abstract

Since the first decant of acid mine drainage in the West Rand in 2002, a great deal of effort has gone into researching the challenges which it poses there and in the adjacent Central Rand and East Rand Gold Fields. Short-term interventions have been implemented to maintain water at conservatively-determined safe levels and remove the worst contaminants from the water pumped from the mined. A feasibility study, looking at the long-term options has proposed treatment of water to a much higher standard, identifying a number of potential end-users of the treated water and highlighted the extremely high costs involved in responsible management. During the second half of 2010, a team of experts was convened to assess problems related to acid mine drainage in the Witwatersrand and propose solutions. A number of recommendations were made and the most urgent - the need for a short-term intervention to bring things under control and the the feasibility study for long-term management of the problems were undertaken. Nevertheless, despite the intense focus on the problem, a number of questions have remained unanswered. Throughout the period of min flooding, no detailed systematic monitoring of surface water flow has been undertaken, preventing the detailed apportionment of pollution between underground and surface sources. Ingress control measures have been proposed, but funding mechanisms, regulatory hurdles and challenges relating to long-term management have not all been comprehensively addressed. On a more positive note, the installation and operation of pumps to control the water level in the Western and Central Basins will start to provide valuable data regarding the response of the flooded mine workings to pumping, assisting in the characterisation of the hydraulic properties and behaviour of the large voids. This will facilitate the optimisation of pumping strategies and the refinement of environmental critical levels and assist in the development of more sustainable management options.

Abstract

Vapour intrusion (VI) is the term used to define the encroachment of vapour phase contaminants from subsurface sources into structures such as buildings and basements. It is widely recognized that VI often forms the principal risk of exposure to receptors at petroleum release sites. Petroleum VI (PVI) generally occurs where a release of petroleum hydrocarbon product migrates from its source (e.g. from a leaking underground storage tank) to the groundwater table at which point, given favourable conditions, the hydrocarbon plume may migrate laterally beneath an adjacent building or structure. Subsequent volatilisation of the petroleum product results in the upward diffusion of vapours towards the surface where the vapours may enter into the building or structure at concentrations which may be harmful to human health. The subject of PVI with regards to its fate and transport mechanisms, as well as associated mitigation measures is rapidly gaining attention on a global scale, although to date this exposure pathway remains largely un-assessed in South Africa, with no regulatory guidance currently available. In the late 1990's and early 2000's focus was placed on the development of VI screening criteria by which sites could be screened with respect to their hydrogeological conditions and contamination status so as to determine whether VI could be a potential exposure pathway of concern, with much of the early work being completed by the United States Environmental Protection Agency. For the past decade the majority of the available screening criteria and guidance has had a partially incomplete understanding of hydrocarbon vapour fate and transport processes associated with VI, which has led to doubt over the application of such screening criteria in many cases. Furthermore, recent research conducted abroad has highlighted the importance of the role of oxygen in the vadose zone in the natural attenuation of petroleum hydrocarbon vapours as they diffuse through the soil profile. This research is pointing towards the notion that currently applied screening criteria may be overly conservative, leading to many unnecessary PVI investigations being conducted to the disruption of occupants of the buildings, and at great cost. Over the last two years ERM has compiled a dataset of PVI results from numerous investigations it has conducted throughout Southern Africa and in this paper the authors present data that supports the growing global trend towards recognizing the role that oxygen plays in attenuating petroleum hydrocarbon vapours in the vadose zone. The data also supports the notion that confirmed cases of PVI into buildings have generally been found to be the exception to the rule and not the norm.

Abstract

Tailings storage facilities are significant contributors of dissolved solids to underlying aquifers and adjacent watercourses. Salt balances indicate estimated seepage loads of the order of 1 500 tonnes of chloride per year. Actual seepage loads will be determined by the hydraulic conductivity of the tailings and mechanisms of flow within the tailings. Field observations and sample analytical results from several platinum tailings facilities are presented. These indicate the development of lenses of clay sized material within coarser silty material and suggest a tortuous seepage flow path, perhaps characterised by zones of preferential flow. The implications of seepage modelling and geochemical data on the salt loads mobilised from tailings are discussed. Results suggest that tailings facilities are effective at retaining salts and that release of accumulated salts after closure may take place at long time scales. {List only- not presented}

Abstract

The study characterized the hydrodynamic and hydrochemical properties of the quaternary porous aquifer which supplies the municipality of Pont-en-Ogoz (Department of Fribourg in Switzerland) with drinking water. The hydrostratigraphic series is composed of a thin overburden material, a porous aquifer composed of gravel and sand, a thin silt-clay layer and sandstone that forms the deeper aquifer. Pumping tests of a borehole nearby the well PSG1 and well PSG1 itself was used to calculate a mean hydraulic conductivity of the aquifer. The hydraulic conductivity from the test varies between 7.4?10-7 m/s and 2.4?10-5 m/s. The values of hydraulic conductivities are typical for sedimentary rocks as silt, fine sandstone and fine sand. The main physical and chemical parameters like concentration in cations and anions, as well the pH, the dissolved oxygen, the electrical conductivity and the alkalinity were measured and saturation indices were calculated. The analysis of the physical and chemical parameters shows that the type of water is Ca-HCO3 and that it contain mixture of old water coming from a regional groundwater flow system, probably from the deeper aquifer, and from recently infiltrated water as local groundwater flow system. The quality of water is generally good, but the effect of the purification of it through the thin overburden layer is limited. An initial one dimension steady state models based on the hypothesis of Dupuits for an unconfined and confined aquifer was used to calculate the mean recharge. This model gives us a recharge values from 24.8 cm/year and 12.1 cm/year, respectively. A second, two dimensional, confined, homogeneous and isotropic model has been calibrated in order to represent the spatial distribution of the piezometric surface. All the models have been calibrated as a steady state. Two groups of predictive scenarios were done to evaluate the drawdown in the well PSG1 using the 2D model. The maximum drawdown calculated was 40 m for the first group of scenarios and 3-4 m for the second group. The second group of scenarios considered from the deeper sandstone aquifer contributing to the well PSG1. The results of the second group of scenarios fit the field results better and the capture zone is much smaller than the one from the first model. The reality is probably between those two models. In order to lower the uncertainty, spatial variation should be added

Abstract

This study was aimed at developing an integrated groundwater-surface water interaction (GSI) model for a selected stretch of the Modder River by considering the following five different aspects of the GSI: 1) the distribution of different aquifer systems (structural connectivity) along the river 2) the hydraulic connectivity between the aquifer systems, 3) the volumes of water abstracted from the aquifers by streamside vegetation, 4) the volumes of water replenished to the groundwater system through rainfall recharge, and 5) the exchange fluxes between the various components of the groundwater-surface water system. The distribution of the aquifer systems was investigated by means of a) geo-electrical surveys, and b) in situ slug tests while their hydraulic connectivity was investigated by hydrogeochemical routing. The volumes of water abstracted by streamside vegetation were estimated by the quantification of the transpiration from individual plants and the groundwater recharge was estimated by a root zone water balance. The water exchange fluxes between the groundwater and surface water were determined from a simple riparian zone groundwater budget. The results of the geo-electrical surveys and slug tests allowed the delineation of the riparian area aquifers (RAA) and the terrestrial area aquifers (TAA) on both the south-eastern and north-western sides of the river. Based on the results of hydrochemical analyses, saturation indices and inverse mass balance modelling, the GSI involves flow of water from the TAA to the RAA, and finally to the river on the south-eastern side while it involves flow from the river into the RAA with a limited exchange with the TAA on the south-eastern side. The dominant vegetation on the study area was found to be the Acacia karroo and Diospyros lycioides. The close similarities in isotope compositions of the xylem sap and the borehole water samples suggested that the Acacia karroo sourced its water from the groundwater storage while differences in isotope compositions suggested that the Diospyros lycioides did not source water from the groundwater storage at the time of measurement. The results of groundwater recharge estimation in the study area highlighted the fact that both the antecedent moisture and the rainfall amounts determine whether recharge to the groundwater system will take place. Finally, the results of baseflow estimation indicated that the river is a gaining stream along the south-eastern reach while acting as a losing stream along the north-western reach.

Abstract

The mineral rich basin of the West African region has vast reserves of gold, diamond as well as iron ore deposits. Throughout the regional geological setting characterised by structural variations and intrusive belts with metamorphic mineral rich sequences covered by saprolite soils, one common chemical constituent remains a constant in the water reserves. Arsenic is in high concentrations throughout the region with chemical ranges commonly above the various country guidelines as well as international IFC and WHO standards. The aqueous chemical species is associated with arsenopyrite rich mineralogy of the regional greenstone belts and highly weathered soils. This conference article and presentation investigates the natural source of the arsenic through baseline data as well as the effect of mining on the already high concentrations of arsenic in both the groundwater and surface water. Natural levels of various chemical species in the regional area are already high at baseline level. One of the main research questions is thus whether mining and other anthropogenic activities will have an impact on the environment or will the changes to concentrations be so insignificant to allow the ecosystems and water users to continue in their current ways without any effect. Various case studies in Burkina Faso, Liberia, Sierra Leone and other countries have been combined to investigate the arsenic-rich resources of the West African region through groundwater specialist investigative methods with emphasis on geochemical modelling of the fluid-rock and fluid-fluid interactions leading to the water quality in the region.

Abstract

The Saldanha / Langebaan area is expanding at a significant rate, increasing the water demand for the area. The expansion comes from the industrial, residential and tourism sector. In addition there are economically viable deposits of silica and phosphate in the area. Ecosystem functioning in the area is also to a degree dependent on groundwater. All of these factors require an improved understanding of the geohydrology of the area. The geology of the area consists of basement Cape Granite and Malmesbury Group rocks that underlie the sediments of the Sandveld Group. The unconsolidated formations present, are (in order of oldest to youngest) as follows: - Elandsfontyn Formation (oldest): This formation overlies the bedrock in depressions and palaeo-channels in the bedrock. This formation is about 40 m thick and is composed of upward fining quartz sediments. - Varswater Formation: This formation is composed of marine deposits and is restricted to the western (seaward) parts of a bedrock depression to the east of the Langebaan Lagoon and Saldanha. The formation is characterized by rounded quartz grains. - Langebaan Formation: This formation consists of calc-arenites. The sediments are generally grey to cream coloured and consist of quartz and shell fragments, the grain size ranges from coarse to fine and the consolidation is variable. - Witzand Formation (youngest). This formation consists of light-coloured, calcareous, coastal dune sand that can be distinguished from the underlying consolidated Langebaan Formation. The Elandsfontyn Aquifer System (EAS) and the Langebaan Road Aquifer System (LRAS) are the main aquifer systems in the area. These aquifer systems are defined by palaeo-channels that have been filled with gravels of the Elandsfontyn Formation and represent preferred groundwater flow paths. Within each of these aquifer systems (EAS and LRAS) two aquifer units are present. Namely, the confined Lower Aquifer Unit (LAU) geologically consisting of the basal gravels of the Elandsfontyn Formation and the Upper Aquifer Unit (UAU) composed of consolidated sands and calcrete. The two units are separated by a clay aquitard. A numerical model has been established for the area, and extends from the Berg River to the Langebaan Lagoon. Granite outcrop and river system define the other boundaries of the model. Extensive logging of groundwater levels by the Department of Water and Sanitation (DWS) has enabled the accurate establishment of a model. In addition extensive field work and a detailed hydrocensus, as well as the capture of a lot of historical information has resulted in a comprehensive GIS which assists with the refinement of the numerical model. The model provides a valuable tool in modelling potential impacts whether they been from planned groundwater abstraction or artificial recharge. {List only- not presented}

Abstract

POSTER The Fountains East and Fountains West groundwater compartments (by means of the Upper and Lower Fountain springs) have been supplying the City of Pretoria with water since its founding in 1855. These adjacent compartments which are underlain by the Malmani dolomites of the Chuniespoort Group are separated by the Pretoria syenite dyke and are bounded to the north by the rocks of the Pretoria Group (Timeball Hill Formation). Swallow holes and paleosinkholes play important roles in recharge in karst environments. Available sinkhole data and geotechnical percussion borehole logs are being collated to compile a detailed conceptual geological model. Inorganic chemistry data (2007 - 2012) as well as spring discharge volumes (2011 - 2012) for the Upper and Lower Fountain springs, supplied by the City of Tshwane Municipality, is being used to characterise the two compartments. This is done by means of piper diagrams, stiff diagrams and temporal plots. Isotope data for the Upper and Lower Fountain springs are available for 1970 to 2007. ?D and ?18O data from the Upper and Lower Fountain springs are plotted against each other and the Global Meteoric Water Line. Other stable isotopes (including 14C and 3H) are also plotted as time trends and interpreted. Interpretation of the combined geotechnical, chemical and isotope data will aid in understanding the karst aquifer and the controls on groundwater system within and possibly between these compartments.

Abstract

Modelling of groundwater systems and groundwater-surface water interaction using advanced simulation software has become common practice. There are a number of approaches to simulate Lake-aquifer interactions, such as the LAK Package integrated into MODFLOW, the high conductivity and fixed stage approaches. LAK and the high conductivity approaches were applied and compared in simulating Lake- aquifer interaction in the Lake Sibayi Catchment, north-eastern, South Africa using the finite difference three-dimensional groundwater flow model, Visual MODFLOW Flex under steady state conditions. The steady state model consisted of two layers: an upper layer consisting of the Sibayi, KwaMbonambi, Kosi Bay and Port Durnford Formations which have similar characteristics, and a lower model layer representing the karst, weathered and calcareous Uloa Formation. The bottom model boundary is constrained by the impermeable Cretaceous bedrock. The model area covers the surface and groundwater catchments of Lake Sibayi which is constrained in the east by the Indian Ocean. A no-flow boundary condition is assigned to the northern, western and southern sides and a constant head boundary is assigned to the eastern side. The Mseleni River and neighbouring plantations were modelled using the River and Evapotranspiration boundary conditions respectively. Input parameters for the various boundary conditions were obtained from the previously developed high resolution conceptual model, including recharge

Abstract

Work is being conducted in Limpopo province following a large volume spill of petroleum hydrocarbons that took place from a leaking underground pipeline, resulting in significant volume of groundwater contamination. This is by far the largest spillage to date in South Africa.10 million litres of jet fuel leaked for a 15 year period from an underground pipeline until its detection 13 years ago. The leak has since been repaired and bailing was the first method proposed and applied to the recovery of the free product, but due to its ineffectiveness the "quicker"pump-and-treat method replaced it. Due to complications caused by pum-and-treat, the process was stopped in 2007 and is about to be reinstated again in 2013. A village to the north of the spillage depends mostly on groundwater. Immediate remediation actions have to be established before the contaminant reaches their abstraction boreholes. This project aims to model the areal extent of this contaminant and eventually design a life cycle of remediation. This will be based on comparison between existing models dated 2002 and 2012 respectively for background information and to address the influence of ten years' bailing, pumping and natural attenuation. The new model will focus around implementing remedial measures to prevent further migration of the free phase or dissolved plumes in order to protect the water supply to the surrounding villages. The progress will be presented in this paper.

Abstract

In this paper we present results of a field study that focused on the characterisation of submarine groundwater discharge (SGD) into False Bay (Western Cape) with emphasis on its localisation. SGD is defined here as any flow of water from the seabed to the ocean. Thus, it includes (1) advective flow of fresh terrestrial groundwater as well as (2) seawater that is re-circulated across the ocean / sediment interface. Groundwater discharge into the coastal sea is of general interest for two reasons: (i) it is a potential pathway of contaminant and nutrient flux into the ocean, and (ii) it may result in the "loss" of significant volumes of freshwater. In our investigation we applied environmental aquatic tracers, namely radionuclides of radon (222-Rn) and radium (223-Ra, 224-Ra), as well as physical water parameters (salinity and temperature). The concentrations of radon and radium can be used as tracers for groundwater discharge since radon and radium are highly enriched in groundwater relative to seawater. We conducted discrete point measurements of seawater and of terrestrial groundwater as well as continuous radon time-series measurements of near-coastal seawater. A large-scale survey was performed along the entire shoreline of False Bay and revealed distinct positive anomalies of radon in the area of Strand/Gordons Bay and a rather diffuse anomaly along the Cape Flats, which is indicating possible groundwater discharge in these areas. The location of these anomalies remained constant to a large extent throughout several surveys that were performed during different seasons, although these anomalies varied with regard to their magnitude and clearness. Further detailed studies were undertaken in the area of Strand/Gordons Bay including radon time-series measurements in the coastal sea at a fixed location in order to estimate the quantity of SGD and its variability on a tidal time scale. The results indicate that groundwater discharge rates are significantly elevated during low tide. Furthermore, the distribution of radium isotopes (224-Ra/223-Ra ratios) in the Strand/Gordons Bay area indicate a "groundwater" residence time of less than 10 days within a distance of 5 km from the shore. In summary, we found spatially considerable constant SGD locations during different field campaigns. Additionally, we gained a rough understanding of the SGD dynamics on a tidal time scale, its magnitude and groundwater residence time within the inner bay after discharge. These results can be beneficial to trace back contamination in near-coastal waters or to find potential locations for groundwater abstraction.

Abstract

The karst aquifer downstream of the actively decanting West Rand Gold Field (a.k.a. the Western Basin) has for decades been receiving mine water discharge. Evidence of a mine water impact in the Bloubank Spruit catchment can be traced back to the early-1980s, and is attributed to the pumping out of so-called "fissure water" encountered during active underground mining operations for discharge on surface. Rewatering of the mine void following the cessation of subsurface mining activities in the late-1990s resulted in mine water decant in 2002. The last five hydrological years (2009?'10 to 2013?'14) have experienced the greatest volume and worst quality of mine water discharge in the 45-year flow and quality monitoring record (since 1979?'80) of the Bloubank Spruit system, causing widespread alarm and concern for the receiving karst environment. The focus of this attention is the Cradle of Humankind World Heritage Site, with earlier speculation fuelled by an initial dearth of information and poor understanding of the dynamics that inform the interaction of surface and subsurface waters in this hydrosystem.

Oblivious to these circumstances, the natural hydrosystem provides an invaluable beneficial function in mitigating adverse impacts on the water resources environment at no cost to society. The hydrologic and hydrogeologic framework that informs this natural benefaction is described in quantitative physical and chemical terms that define the interaction of allogenic and autogenic water sources in a subregional context before highlighting the regional benefit. The subregional context is represented by the Bloubank Spruit catchment, a western tributary of the Crocodile River, which receives both mine water and municipal wastewater effluent and therefore bears the brunt of poor quality allogenic water inputs. The regional context is represented by the Hartbeespoort Dam catchment, which includes major drainages such as the Crocodile River to the south and its eastern tributaries the Jukskei and Hennops rivers, and the Magalies River and its southern tributary the Skeerpoort River to the west. Each of these drainages contribute to the quantity and quality of water impounded in the dam, and an analysis of their respective contributions therefore provides an informative measure of the temporal mine water impact in a regional context.

The result indicates that amongst other metrics, the total dissolved solids (TDS) load delivered by the Bloubank Spruit system in the last five hydrological years amounted to 11% of the total TDS load delivered to Hartbeespoort Dam in this period, ranking third behind the Jukskei River (49%) and the Hennops River (30%), and followed by the Magalies River (5%), Crocodile River (4%) and Skeerpoort River (1%). By comparison, the long-term record reflects changes only in the contributions of the impacted Bloubank Spruit (10%) and pristine Skeerpoort River (2%). The difference is attributed mainly to the intervention of Mother Nature.

Abstract

The Gravity Recovery and Climate Experiment satellites detect minute temporal variation in the earth’s gravitational field at an unprecedented accuracy, in order to make estimation of the total water storage (TWS). GRACE provides a unique opportunity to study and monitor real time water variation in the hydrologic stores( snow, groundwater, surface water and soil moisture) due to increase or decrease in storage. The GRACE monthly TWS data are used to estimate changes in groundwater storage in the Vaal River Basin. The Vaal River Basin has been selected because it is one of the most water stressed catchment in South Africa; it is well-renowned for its high concentration of industrial activities and urbanized zones. Therefore, in order to meet future water demands it is critical to monitor and calculate changes in groundwater dynamics as an important aspect of water management, where such a resource is a key to economic development and social development.

Previous studies in the Vaal River Basin, where mostly localized focusing largely on groundwater quality and to a lesser extent groundwater assessment. Hydrological models have been generated for the whole of South Africa, many of this models does not take into account the groundwater. Thus, there is a significant gap in our understanding of surface and ground water dynamics in the Vaal River Basin. The paucity of data and monitoring networks is often the limitation in calculating changes in water storage over a large area, particularly in Africa. In this scenario GRACE is the only approach to estimate changes in hydrological stores as it covers large areas and generate real time data. It does not require information on soil moisture, which is often difficult to measure. The preliminary results indicate that the change in TWS anomaly derived from GRACE data is - 12.85 mm of vertical column of water at 300 km smoothing radius. The change in groundwater storage is calculated by incorporating hydrologic components to the TWS (work in progress). The results obtained from this study will be compared to existing hydrological models and results generated from models applicable to the semi-arid region of South Africa. It is anticipated that this satellite observation technique, GRACE, will provide an accurate estimate of change in groundwater storage. Furthermore, it will show the usefulness of satellite based techniques for improving our understanding of groundwater dynamic, which will improve water management practices.

Abstract

POSTER Water resources are not just lakes, glaciers and polar ice caps and rivers; however one of the largest water resources is underground water well-known as Groundwater. Groundwater is one of the most important source of water as it the huge reservoir for freshwater. Groundwater can be defined as water existing underneath the earth surface in rock bodies known as aquifers. Approximately 140 communities in South Africa depend on groundwater as the source of water (Department of water affairs and forestry, 1998). Nevertheless groundwater is vulnerably to pollutants resulting from surrounding environmental effects which lead to poor groundwater quality. Numerous environmental effects have a huge impact in polluting groundwater such as pesticides, seawater encroachment, sewage effluent discharges to the ground and storage tanks underground; hence one need to identify, evaluate and come up with solutions on eradication of all these environmental effects that lead to groundwater pollution ( Hearth 1983).

The objectives of the report will be based on minimizing the groundwater pollution at the source and to restore groundwater quality to extent that the beneficial users recognise its suitability. Inspection in University of the Western Cape (UWC) campus site and Rawsonville site will be conducted by BSc Environment and Water Science students of UWC in June using various tools in order to identify and monitor surrounding environmental effects towards groundwater pollution. UWC campus research site is located on top of the Cape Flats primary aquifer (unconfined sand aquifer); Cape Flat aquifer is overlain by an impermeable bedrock Malmesbury (shale) secondary fractured aquifer. Generally this borehole test will be based on testing on how the surrounding environmental impacts with various aquifer properties affect the groundwater quality or whether the surrounding environment interrupts the groundwater quality in Cape flats aquifer and Rawsonville site. The UWC campus site has low infiltration compared with Rawsonville site as it is surrounded by vegetation that plays role in trapping water from infiltrating therefore this aquifer is less likely to be contaminated by pollutants from the land surface, however with it being surrounded by residential areas and industries it is likely to be polluted. Rawsonville on the other hand is located in the grape farm which makes it easier for the site to be contaminated by fertilisers used for agricultural practice. The pumping test will further enable one in knowing the quantity of groundwater in UWC campus site and Rawsonville site thus extraction levels for municipal works, irrigation and so forth will be monitored in a correct manner (Department of water affairs and forestry, 1998). Finally groundwater models will be used to further investigation on the behaviour of groundwater systems.

Abstract

Cadmium is a highly mobile and bioavailable non-essential element that is toxic to plants, and is an animal and human carcinogen (affecting the kidneys and bones in vertebrates). Since the late-1970s the effects of cadmium on the environment have become a global issue of concern, and many countries have conducted evaluations on the exposure of their populations to cadmium in phosphate fertilizer (a major non-point source of anthropogenic cadmium). A scoping project, funded by the Water Research Commission, aimed to review cadmium contamination of South African aquifer groundwater systems (predominantly) via phosphate fertilizer use. Topics reviewed included fertilizer composition and types, metal speciation, metal mobility in soil and groundwater systems, metal bioavailability, health and environmental effects, and local South African contamination case studies. A preliminary study site, namely the greater Hermanus region, was identified for trace metal and groundwater quality studies (which incorporated urban and agricultural areas in various hydrogeological settings). Hermanus was selected due to: 1) the discovery of cadmium concentrations of 20 ?g/l (in comparison to the SANS 241-1:2011 cadmium limit of 3 ?g/l) in a golf estate irrigation borehole, during drilling and test-pumping of the borehole at the end of 2012

Abstract

At a regional scale, groundwater recharge is often calculated using surface water models. Precipitation and surface water runoff are easier to measure than groundwater recharge, and evapotranspiration can be estimated with relative accuracy using indirect methods. In modelling, surface water measurements can be used for calibration, and groundwater is the residual term in the water balance of the catchment. This can give a good indication of regional trends, but provides limited scope for the accommodation of groundwater system characteristics and recharge processes. Recently, much research has been focused on the interaction of surface and groundwater models. The coupling of physically based surface and ground water models allows for calibration of the model using both surface and groundwater data while providing scope for improved insight into the processes which define the interaction of groundwater with the rest of the water cycle. For example: stream discharge, interflow, preferential flow through the unsaturated zone and interaction with surface water retained in dams and wetlands. One such model is GSflow (United States Geological Survey), which we are applying to the Upper Vaal Catchment. This model integrates the surface water model PRMS (Precipitation-Runoff Modelling System) with MODFLOW (Modular Groundwater Flow model). The model is initially being calibrated at quaternary catchment scale, starting with the surface water components and later adding the groundwater system. The quaternary catchment is subdivided into smaller, topologically defined hydrological response units. This scaling allows for a better understanding of how well the characteristics of the units are represented in the physical processes incorporated into the model, so that ultimately the sensitivity analysis can incorporate these processes. The results will be compared to current work on recharge being carried out using GRACE data and previous work done in the same area. Once the entire model has been calibrated, there will be scope to calculate future scenarios, allowing for climate and land-use changes. A brief overview of existing work as well as methods and initial results and sensitivity analysis will be presented.

Abstract

Geochemical investigations for a planned coal mine indicated that the coal discard material that would be generated through coal processing would have a significant potential to generate acid rock drainage. A power station is planned to be developed in close proximity to the coal mine, and the potential for co-disposal of coal discard with fly-ash material required examination. Fly-ash is typically highly alkaline and has the potential to neutralise the acidic coal discard material. In order to investigate whether this was a viable option, the geochemical interaction between the coal discard and fly-ash was investigated. Geochemical data, including acid-base accounting, total chemical compositions, leach test data and kinetic test data, were available for the coal discard material and the fly-ash. Using these data as inputs, a geochemical model was developed using Phreeqci to predict the pH of leachate generated by mixing different ratios of coal discard and fly-ash. The ratio of coal discard to fly-ash was established that would result in a leachate of neutral pH. Using this prediction, a kinetic humidity cell test was run by a commercial laboratory for a total of 52 weeks using the optimal modelled ratio of discard and fly-ash. Although leachate pH from the kinetic test initially reflected a greater contribution from fly-ash, the pH gradually decreased to the near-neutral range within the first 20 weeks, and then remained near-neutral for the remainder of the 52-week test. During this period, sulphate and metal concentrations also decreased to concentrations below those generated by either the fly-ash or coal discard individually. The addition of fly-ash to the coal discard material provided sufficient neutralising capacity to maintain the near-neutral pH of the co-disposal mixture until the readily available sulphide minerals were oxidized, and the oxidation rates decreased. At the end of the test, sufficient neutralising potential remained in the humidity cell to neutralise any remaining sulphide material. The results of this investigation suggested that, under optimal conditions, co-disposal of fly-ash with coal discard is a viable option that can result in reduced environmental impacts compared to what would be experienced if the two waste materials were disposed of separately.

Abstract

The provision, usage and discharge of water resources are major concerns for coal mines, both underground and opencast. Water resources in a coal mining environment will often account for a significant portion of the daily operational cost. In order to cut costs, the mine will often collect as much runoff as possible to recycle for future use. This on-going recycling of site water and management of the resource demands a complete site water balance model in order to understand the dynamics of the resource within the boundaries of the mine. To improve the understanding of the dynamics of the resource on a much larger scale, and the effect it will have on recharge in an open cast coal mine environment, one must consider alternative modelling approaches which can compensate for such conditions. This amounts to describing recharge as a modelling component in a physically based distributed model. The main goal of this project is to calculate recharge into the main pit at this specific colliery by applying parameters on a quaternary catchment scale. The colliery is located just west of the town of Ogies, Mpumalanga on the peripheral region of the quaternary catchment B20G. The physiography of the quaternary catchment B20F is described as a central Highveld region gently sloping to the north. The geohydrological modeling application MIKE SHE (developed by DHI) was used to develop a fully integrated catchment model. The model was created mainly to simulate the impact of human activities on the hydrological cycle and hence on water resource development and management. Different modules of MIKE SHE that was used during the modelling stage include saturated- and unsaturated flow and a small degree of overland flow.

Key words: Mpumalanga, MIKE SHE, recharge

Abstract

Groundwater is used extensively in the Sandveld for the irrigation of potatoes. The groundwater resources are plentiful and of good enough quality for the production of potatoes, however there has been a significant increase in potato production especially from the period 1975 to 2008. The area planted has increased from 2 369 Ha to 6 715 Ha in this period. The rate of increase has reduced significantly since 2008 and is now quite consistent at approximately 6 800 ha/a. In the region groundwater is vital for the proper functioning of ecosystems and it is also the sole source of water for five towns in the area and supplies most of the domestic water for the farms in the area. Thus the abstraction of groundwater for agriculture needs to be carefully assessed to ensure impacts on other systems and users do not occur.

For this reason Potatoes South Africa has taken the responsible approach of investing in the on-going monitoring of groundwater levels (quantity) and groundwater quality in the Sandveld. PSA appointed the groundwater consultancy, GEOSS to do this monitoring and they have continually committed to this monitoring for the past 10 years. The long term monitoring data has been very valuable in that it shows groundwater trends and the spatial distribution of the measured parameters. Regarding the trends it is clear that certain areas are being over-abstracted and groundwater levels are dropping. In the more critical areas, intervention has occurred - boreholes were closed down and the points of abstraction distributed over a much wider area. This region (Lower Langvlei River) is showing clear signs of recovery both in terms of groundwater levels and quality. The other localized areas where negative trends are evident the land owners have been informed and are aware of the problems. In some critical areas continuous groundwater level loggers have been installed to monitor trends.

The long-term groundwater monitoring, has helped significantly in addressing the negative perception about the widespread impact on groundwater resources due to potato cultivation in the Sandveld. It is important the monitoring continues and regular feedback provided to land owners. The monitoring that the local municipality and the Department of Water Affairs do also needs to be integrated into a single database. It is evident that the initial abstraction of groundwater in the pioneer days of potato cultivation did impact groundwater resources and associated ecosystems in the Sandveld, however currently as the rate of expansion has reduced and stabilized, the groundwater resources closely mimic rainfall patterns and the areas that are being impact are localized, well known and being addressed.

Abstract

South Africa is a semi-arid country. Its average rainfall of roughly 464 mm/a is much lower than the world average of 860 mm/a. Due to a shortage of surface water, groundwater plays an important role in the water supply to domestic, industrial, agricultural and mining users. Groundwater exploration has become increasingly dependent on the use of geophysical techniques to gain insight into the subsurface conditions to minimise the risk of drilling unsuccessful production boreholes. Dolerite dykes and sills are often targeted during groundwater exploration programmes in Karoo rocks. Due to the high pressures and temperatures that reigned during the emplacement of these structures, the sedimentary host rocks along the margins of the intrusive structures are typically strongly altered. These altered zones are often heavily fractured and, as a result, have increased hydraulic conductivities as compared to the unaltered host rock. The altered zones often act as preferential pathways for groundwater migration, making them preferred targets during groundwater exploration.
In conjunction with magnetic methods, electromagnetic (EM) methods are the techniques most often used for groundwater exploration in Karoo rocks. In South Africa, the ground EM system most commonly used is the Geonics EM34-3 frequency-domain system. This system has already been in use for a few decades, yet a great deal of uncertainty still remains regarding the interpretation of anomalies recorded over geological structures associated with lateral changes in electrical conductivity. This uncertainty results from the fact that the Geonics EM34-3 system employs measurements of the out-of-phase components of the secondary magnetic field relative to the primary magnetic field to calculate an apparent conductivity for the subsurface. The apparent conductivity profiles across lateral changes in conductivity often do not make intuitive sense.
This project focuses on the development of guidelines for the interpretation of anomalies recorded with the EM34-3 system across intrusive structures of geohydrological significance in Karoo rocks. Geophysical surveys were conducted across known dykes and sills in an attempt to systematically investigate the responses recorded across these structures. Data from magnetic and two-dimensional electrical resistivity tomography surveys, as well as from geological borehole logs in some cases, were used as controls to assist in the interpretation.

Abstract

The city of Bloemfontein is currently entirely dependent on remote surface water sources for its potable water supply. The water is purified at great cost, before being pumped over large distances to the reservoirs of the city. However, the surface water resource is unreliable and susceptible to droughts. In addition, large volumes of the purified water are lost before reaching the users. These losses are due to various factors, including leakages in the pipelines transporting the water to Bloemfontein and illegal connections. To reduce the city's dependence on remote surface water sources, this investigation aims to assess the potential for using groundwater resources to augment the municipal water supply. A prominent ring-dyke underlying the city is thought to be associated with strong aquifers. Our geophysical investigations have shown that this dyke yields large and well-defined magnetic and resistivity anomalies that allow easy interpretation of the geometry of the dyke. Future investigations will include the installation of boreholes at positions as determined from an interpretation of the geophysical data. Hydraulic tests will be performed on the aquifers intersected by the boreholes to determine the hydraulic parameters and sustainable yields. The groundwater quality will be assessed to evaluate its suitability for human consumption.

Abstract

A groundwater assessment was conducted to identify and predict the contamination and transport properties of a groundwater system. The motivation for the study was the rising concern of a farm owner about the deteriorating water quality of the aquifer system. An investigation of the surface and groundwater quality indicated that two fertilizer dumpsites were the sources of pollution. Water analyses revealed elevated concentrations of Ca, Mg, K, F, NO3, SO4, Mn and NH4 within boreholes near the pollution sources. The NH4 and NO3 concentrations were exceptionally high: 11 941 mg/L and 12 689 mg/L, respectively. These high concentrations were the direct result of the dumping of fertilizer. The rise in these concentrations may also have been catalysed by the nitrogen cycle and the presence of the Nitrosomonas bacterium species. Due to the high solubility of NO3, and because soils are largely unable to retain anions, NO3 may enter groundwater with ease, and could migrate over large distances from the source. Elevated NO3 in groundwater is a concern for drinking water because it can interfere with blood-oxygen levels in infants and cause methemoglobinemia (blue-baby syndrome). A geophysical study was undertaken within the area of investigation to gain insight on the underlying geological structures. The survey indicated preferential flow paths within the aquifer system along which rapid transport of contaminant is likely to occur.
Key words: aquifer system, groundwater quality analyses, fertilizer, nitrogen cycle, Nitrosomonas species, geophysics.

Abstract

Natural attenuation describes a set of natural processes which decrease the concentrations and/or mobility of contaminants without human intervention. In order to evaluate and demonstrate the effectiveness of natural attenuation, regular long term monitoring must be implemented. This entire process is called Monitored natural attenuation (MNA). The focus of MNA is generally placed on hydrocarbons and chlorinated solvents but according to the United States Environmental Protection Agency (USEPA) MNA can be used for various metals, radio nuclides and other inorganic contaminants. MNA was deemed the best method to reduce the concentration and mobility of contaminants impacting the groundwater environment, at a fertiliser plant in the Free State. A number of improvements in infrastructure were made in 2013which were assumed to have prevented further release of contaminants into the groundwater system, from the source areas on site. MNA was also considered to be the most effective affordable solution for the site as groundwater in the vicinity is not used for domestic purposes (low risk). Cl, NO3 and NH4 were used to monitor the movement of the contamination off site and the effectiveness of MNA. With regards to the inorganic contaminants emanating from the site, sorption, dispersion, dilution, and volatilization are the main attenuation mechanisms. These mechanisms are considered to be non-destructive attenuation mechanisms. Denitrification, nitrate reduction through microbial processes, may also facilitate in the attenuation of the in organic constituent nitrate. Denitrification is considered a destructive mechanism. Classed posts and temporal graphs of the Cl, NO3 and NH4 concentrations between 2008 and 2014 were utilised to show the movement and change in size and shape of the contamination plumes and subsequently, monitor MNA. The data indicates that the NO3, Cl and NH4 contamination plumes from the various source areas on the site have detached from the site and are currently moving down gradient along the natural drainage. Contaminant concentrations at the site have generally decreased in recent monitoring events while concentrations downstream of the site have remained stable. This indicates that MNA is currently an effective method of remediation for the site and monitoring should be continued to ensure that it remains effective.

Abstract

Globally, a growing concern have been that the heavy metal contents of soil are increasing as the result of industrial, mining, agricultural and domestic activities. While certain heavy metals are essential for plant growth as micronutrients, it may become toxic at higher concentrations. Additionally, as the toxic metals load of the soil increases, the risk of non-localized pollution due to the metals leaching into groundwater increases. The total soil metal content alone is not a good measure of risk, and thus not a very useful tool to determine potential risks to soil and water contamination. The tendency of a contaminant to seep into the groundwater is determined by its solubility and by the ratio between the concentration of the contaminant sorbed by the soil and the concentration remaining in solution. This ratio is commonly known as the soil partitioning or distribution coefficient (Kd). A higher Kd value indicate stronger attraction to the soil solids and lower susceptibility to leaching. Studies indicate that the Kd for a given constituent may vary widely depending on the nature of the soil in which the constituent occurs. The Kd of a soil represents the net effect of several soil sorption processes acting upon the contaminant under a certain set of conditions. Soil properties such as the pH, clay content, organic carbon content and the amount of Mn and Fe oxides, have an immense influence on the Kd value of a soil. Kds for Cu, Pb and V for various typical South African soil horizons were calculated from sorption graphs. In most cases there were contrasting Kd values especially when the cations, Cu and Pb, had high contamination levels, the value for V was low. There is large variation between the Kds stipulated in the Framework for the Management of Contaminated land (as drafted by the Department of Environmental Affairs) and the values obtained experimentally in this study. The results further indicate that a single Kd for an element/metal cannot be used for all soil types/horizons due to the effect of soil properties on the Kd. The results for Cu and Pb indicated that the Kds can range in the order of 10 to 10 000 L/kg for Cu and 10 to 100 000 L/kg for Pb. The variation in V Kd was not as extensive ranging from approximately 10 to 1 000 L/kg. {List only- not presented}

Abstract

VLF-Electromagnetic and geoelectric soundings were carried out at Ibuso-Gboro area via Ibadan, Oyo state. The objective was to delineate the groundwater potentials of the area. VLF-Electromagnetic method was adopted for reconnaissance survey with a view to locating bearing fractured zones in the basement bedrock. Sixteen (16) VLF-Electromagnetic profiles whose length ranges from 90-290 m were occupied with station interval of 10 m. The VLF-Electromagnetic results were presented as profiles. Linear features, suspected to be fractured zones, which were from the anomaly curves of the VLF-Electromagnetic were delineated in seven localities along the profiles. These localities were further confirmed by Vertical Electrical Soundings (VES). The seven Schlumberger Vertical Electrical Soundings (VES) were occupied with the electrode spacing (AB/2) varying from 1 m to 100 m with the total spread length of 200 m. The VES data were presented as sounding curves and interpreted by partial curve matching and computer assisted 1-D forward modeling. The results were presented as geoelectric sections, which showed the subsurface geoelectric images. Two out of the seven delineated linear features were test drilled and the fractured zones were met at depth range of between 25.0 m and 38.2 m beneath borehole (1) and 43.0 m and 52.1 m beneath borehole (2) for confined fractured. The pumping test analysis revealed borehole yield varied from 4.8 m3/hr and 5.2 m3/hr, where three (3) abortive boreholes had earlier been drilled. {List only- not presented} Key Words: VLF-Electromagnetic, Linear features, Geoelectric Soundings and Pumping test.