POSTER Water is an invaluable resource without which life would cease to exist. Supply in South Africa has become limited due to increases in demand brought upon by population growth, urbanisation and industrialisation. In Southern Africa, water systems are considerably degraded by mining, industry, urbanisation and agricultural activity and a large amount of the fresh surface water has already been utilised. The stresses on this resource will unlikely make the current usage sustainable in years to come. In order to provide for basic needs for the future, groundwater as a resource will have to play a major role. It is for this reason that groundwater integrity needs to be preserved.
Hydrocarbon contamination is a huge threat to groundwater as it contains toxic substances that are insoluble in water. These toxins are carcinogenic and mutagenic, and have a major impact on human health and ecosystem stability. When spilled, hydrocarbons will move downward through the unsaturated zone under the influence of gravity and capillary forces, trapping small amounts in the pore spaces. Accumulation will result in added weight along the water table, forcing the entire surface to be displaced downward. Some of the components can dissolve in the groundwater and move as a plume of contaminated water by diffusion and advection within the saturated zone. The transport of contaminants from petroleum hydrocarbon spills needs to be described in terms of a multiphase flow system in the unsaturated zone, taking into account contaminant movement in each of the three phases: air, water and free light non-aqueous phase liquid. Petroleum hydrocarbon behaviour in the subsurface is additionally complicated by the presence of multiple compounds, each with different properties. The net result is that some hydrocarbon fractions are transported faster than others and a contamination plume of varying intensity may spread over a large area.
The aim of this study is to develop a methodology to map and simulate the movement of groundwater that has been contaminated by hydrocarbons and to determine the fate of the water quality through decomposition. Associated remediation options will be determined thereafter.