Hydrogeochemical and temporal nitrate variation in an unconfined urban aquifer in a tropical area in Brazil

The Bauru Aquifer System (BAS) is a significant source of water supply in the urban area of Bauru city. Over the last decades, BAS has been widely affected by human activities. This study evaluates the nitrate plume in groundwater from 1999 to 2021 and how it relates to urbanization. The methods used were analysis of the data of 602 wells, survey of the sewer network and urbanization, and reassessment of nitrate concentration data. The seasonal analysis of 267 groundwater samples allowed the identification of concentrations up to 15.1 mg/L N-NO3 - mainly from the area’s central region, where the medium to high-density urban occupation dates back to 1910. Otherwise, the sewage system was installed before 1976. The reactions controlling the nitrogen species are oxidation of dissolved organic carbon, dissolution of carbonates, mineralization, and nitrification. Wells, with a nitrate-increasing trend, occur mainly in the central and northern regions, settled from 1910 to 1980-1990, when no legislation required the installation of the sewage network before urbanization. In turn, wells with stable or decreasing nitrate concentrations occupy the southwestern areas. Over the years, the concentrations of these wells have shown erratic behaviour, possibly caused by the wastewater that leaks from the sewer network. The bivariate statistical analysis confirms a high positive correlation between nitrate, sanitation age, and urban occupation density, which could serve as a basis for the solution of sustainable groundwater use in the region. Project supported by FAPESP (2020/15434-0) and IPA/SEMIL (SIMA.088890/2022-02).