Tracing mine water flows in a dolomite quarry, South Africa, using hydrochemistry and stable isotopes

Water resources, including groundwater, are under threat globally from abstraction and pollution, making studies of water flows ever more urgent. South Africa has a growing population, a relatively dry climate and abundant mining activity, all of which increase the importance of water management. Mooiplaas Dolomite Quarry, southeast of Pretoria, has been mining metallurgical grade dolomite since 1969 and is located in the productive karst aquifers of the Malmani Subgroup, Transvaal Supergroup. The site was investigated by sampling precipitation, surface water, groundwater and mine water for hydrochemical and stable isotope analysis from 2011 to 2017, totalling over 400 samples. Nitrate levels in groundwater and mine water were marginally above drinking water limits from explosives residues, and ammonia in the nearby Hennops River was unacceptably high due to municipal sewage outfalls, but otherwise, water quality was very good. Alkalinity from rock weathering, aided by the crushing of dolomite, was the main control on water chemistry. Combined analysis of dissolved matter (TDS, nitrate, Mg, etc.) suggested that the dewatering of the mine and resultant recharge from slime dams caused an aerated zone of groundwater, which mixed with regional groundwater flowing beneath the site. Stable isotopes, with an evaporated signature from mine open water bodies, also showed how mine operations cause recharge to groundwater and subsequent seepage back into the pit lakes. The mine appears not to contaminate the regional groundwater. However, mine designs should avoid situations where process water flows via groundwater back into pits, causing excessive dewatering costs.