Contribution of gravel pit lakes in reducing the groundwater nitrate contamination originating from agricultural land

The alluvial aquifer in the Varaždin region has a long-standing problem with high groundwater nitrate concentrations, mainly from agricultural activities. Since groundwater is used in public water supply networks, it is important to ensure its sustainable use. The aquifer is also used to exploit gravel and sand, and the increased demand for this valuable construction material causes the excavation of gravel pit lakes, making groundwater more vulnerable. Although engineered processes can remove nitrate from groundwater, natural attenuation processes should be investigated to understand the nitrogen behaviour and additional mechanisms for groundwater remediation. Previous research has shown nitrate is a conservative contaminant in the critical zone. Aerobic conditions within an aquifer system prevent significant denitrification. Thus, nitrification is the main process controlling nitrogen dynamics in groundwater. Since groundwater and gravel pit lakes are hydraulically connected, and natural nitrate attenuation exists in these lakes, an additional mechanism for groundwater remediation is possible. This work used isotope hydrochemistry and groundwater modelling to investigate gravel pit lakes as possible sites to reduce nitrate concentration in groundwater. Based on the isotopic composition of groundwater and nitrate concentrations, water balance and solute mass balance were calculated, which made it possible to estimate the nitrate attenuation rate in gravel pit lakes. The gained retardation factor was applied to the groundwater flow and nitrate transport model through several scenarios to evaluate the contribution of gravel pit lakes in reducing the groundwater nitrate concentrations