Assessment of Groundwater Chemistry in Shallow Aquifers, Beaufort West

Groundwater forms an important part of the water resources of South Africa, especially in Karoo region, where groundwater is an important source of fresh water. Beaufort West is a town that uses groundwater as a major source of municipal and private water supply. Groundwater samples were collected from a network of 43 boreholes, between November 2015 to December 2018 within Beaufort West town and 10km radius surrounding. The water samples were analysed for inorganics, organics, stable isotopes and radioactive isotopes. The hydrogeochemical results indicate that all the boreholes onsite are collecting water from the shallow aquifer with neutral pH. From the 228 groundwater samples analyses, the total dissolved solids (TDS) concentrations averaged 1041 mg/L. This falls within the SANS 241:2015 guideline standard of ? 1200 mg/L for TDS. The high nitrates and sulphates in the water indicate that shallow aquifer has aerobic conditions. Generally, the water type is Calcium Magnesium Bicarbonate and Magnesium Sulphate. Both the inorganic chemistry and the stable isotopes have a signature of water that is recently recharged. The carbon dating results indicate that water has been underground for no more than 3 000 years. The groundwater samples generally show no contamination of organic compounds with the exception of boreholes located in the Karoo National Park, which showed high amounts of organic compounds (xylene and ethylbenzene). The interaction of the known uraniferous deposit of the Poortjie Formation in the Beaufort West area has possibly influenced the groundwater. This has resulted in groundwater with elevated average amount 17.58 ?g/L of uranium against background values of 10 ?g/L. This is however below the SANS 241:2015 standard of 30 ?g/L.