Assessing The Role Of Oxygen In The Attenuation Of Petroleum Hydrocarbon Vapours In The Vadose Zone

Vapour intrusion (VI) is the term used to define the encroachment of vapour phase contaminants from subsurface sources into structures such as buildings and basements. It is widely recognised that VI often forms the principal risk of exposure to receptors at petroleum release sites. Petroleum VI (PVI) generally occurs where a release of petroleum hydrocarbon product migrates from its source (for example, from a leaking underground storage tank) to the groundwater table at which point, given favourable conditions, the hydrocarbon plume may migrate laterally beneath an adjacent building or structure. Subsequent volatilisation of the petroleum product results in the upward diffusion of vapours towards the surface where the vapours may enter into the building or structure at concentrations which may be harmful to human health. The subject of PVI with regards to its fate and transport mechanisms, as well as associated mitigation measures, is rapidly gaining attention on a global scale, although to date this exposure pathway remains largely unassessed in South Africa, with no regulatory guidance currently available. In the late 1990s and early 2000s focus was placed on the development of VI screening criteria by which sites could be screened with respect to their hydrogeological conditions and contamination status so as to determine whether VI may be a potential exposure pathway of concern, with much of the early work being completed by the United States Environmental Protection Agency. For the past decade the majority of the available screening criteria  and  guidance  has  not,  or  has  only  partially  accounted  for  biodegradation  processes associated with VI, which has led to doubt over the application of such screening criteria in many cases. Furthermore, recent research conducted abroad has highlighted the importance of the role of oxygen in the vadose zone in the natural attenuation of petroleum hydrocarbon vapours as they diffuse through the soil profile. This research is pointing towards the notion that currently applied screening criteria may be overly conservative when applied to petroleum impacted sites, leading to many  unnecessary  PVI  investigations  being  conducted  to  the  disruption  of  occupants  of  the buildings, and at great cost. Over the last two years ERM has compiled a dataset of PVI results from numerous investigations it has conducted throughout Southern Africa and in this paper the authors present data that supports the growing global trend towards recognising the role that oxygen plays in attenuating petroleum hydrocarbon vapours in the vadose zone. The data also support the notion that confirmed cases of PVI into buildings have generally been found to be the exception to the rule and not the norm.