Conference Abstracts

All Abstracts were presented at the Groundwater Conferences

Displaying 101 - 150 of 795 results
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Abstract

The generation of acid mine drainage (AMD), as a result of mining activities, has led to the degradation of groundwater quality in many parts of the world. Coal mining, in particular, contributes to the production of AMD to a large extent in South Africa. Although a vast number of remediation methods exist to reduce the impacts of AMD on groundwater quality, the use of a coal fly ash monolith to act as a reactive and hydraulic barrier has not been extensively explored. This study, therefore, aims to investigate how different ways of packing ash affect the hydraulic conductivity of ash and influence leachate quality when acid-mine drainage filters through the ash. Coal ash is highly alkaline due to the existence of free lime on the surface of the ash particles. Previous studies that investigated alternative uses of coal ash, particularly in AMD treatment, suggest that coal ash has the potential to neutralise pH in acid water and remediate acidic soils. To test the effects of different packing methods of coal ash on the hydraulic conductivity and quality of acid mine leachate flowing through it, several Darcy column tests will be conducted. During the course of these experiments, the following parameters will be measured, electrical conductivity, pH discharge, lime (CaCO3) and selected elements of environmental concern.

Abstract

An understanding of the movement of moisture fluxes in the unsaturated zone of waste disposal sites play a critical role in terms of potential groundwater contamination. Increasing attention is being given to the unsaturated or vadose zone where much of the subsurface contamination originates, passes through, or can be eliminated before it contaminates surface and subsurface water resources. As the transport of contaminants is closely linked with the water ?ux in through the unsaturated zone, any quantitative analysis of contaminant transport must ?rst evaluate water ?uxes into and through the this region. Mathematical models have often been used as critical tools for the optimal quantification of site-speci?c subsurface water ?ow and solute transport processes so as to enable the implementation of management practices that minimize both surface and groundwater pollution. For instance, numerical models have been used in the simulation of water and solute movement in the subsurface for a variety of applications, including the characterization of unsaturated zone solute transport in waste disposal sites and landfills. In this study, HYDRUS 2D numerical simulation was used to simulate water and salt movement in the unsaturated zone at a dry coal ash disposal site in Mpumalanga, South Africa. The main objective of this work was to determine the flux dynamics within the unsaturated zone of the coal ash medium, so as to develop a conceptual model that explains solute transport through the unsaturated zone of the coal ash medium for a period of approximately 10 year intervals. Field experiments were carried out to determine the model input parameters and the initial conditions, through the determination of average moisture content, average bulk density and the saturated hydraulic conductivity of the medium. A two dimensional finite-element mesh of 100m x 45m model was used to represent cross section of the ash dump. Two dimensional time lapse models showing the migration of moisture fluxes and salt plumes were produced for the coal ash medium. An explanation on the variation of moisture content and cumulative fluxes in the ash dump was done with reference to preexisting ash dump data as well as the soil physical characteristics of the ash medium.
{List only- not presented}

Abstract

Groundwater is a vital source of water for many communities in South Africa and elsewhere. Besides the changing climate, rapidly spreading invasive alien plants with deep roots e.g. Prosopis spp, pose a serious threat to this water source. Dense impenetrable thickets of Prosopis occur in the drier parts of the country mainly along river channels in the Northern, Eastern and Western Cape Provinces. Few studies have quantified the actual water use by this species outside of the USA where it is native. Consequently the impacts of Prosopis invasions on groundwater resources are not well documented in South Africa. The aim of this study was to quantify the actual volumes of water used by Prosopis invasions and to establish the effects on groundwater. Because deep rooted indigenous trees that normally replace Prosopis once it has been cleared also use groundwater, we sought to quantify the incremental water use by Prosopis over and above that used by indigenous trees in order to determine the true impacts on groundwater. The study was conducted at a site densely invaded by Prosopis at Brandkop farm near the groundwater dependent town of Nieuwoudtville in the Northern Cape. One in seven trees at the site is the Vachellia karroo (formerly A. karroo) which is the dominant deep rooted indigenous tree species. Actual transpiration rates by five Prosopis and five V. karroo are being measured using the heat pulse velocity (HPV) sap flow technique. Additional HPV sensors were installed on the tap and lateral roots to study the water uptake dynamics of the trees. Groundwater levels are being monitored in four boreholes drilled across the site while sources of water used by the trees (i.e. whether soil or groundwater) is being determined using O/H stable isotopes. For similar size trees, V. karroo had higher transpiration rates than Prosopis because of the larger sapwood to heartwood ratio in V. karroo than in Prosopis. However, at the stand level Prosopis consumed significantly larger amounts of water than V. karroo. This is because Prosopis invasions had a much higher tree density than V. karroo. From August 2013 to July 2014, annual stand transpiration for Prosopis (~ 372 mm) was more than 4 times higher than that of V. karroo (~ 84 mm). Tree water uptake was correlated to changes in groundwater levels (R2 ~ 0.42) with groundwater abstractions of ~ 2600 m3/ha/y by Prosopis compared to ~ 610 m3/ha/y for V. karroo. In addition, Prosopis showed evidence of hydraulic redistribution of groundwater wherein groundwater was deposited in the shallow soil layers while V. karroo did not. Results of this study suggest that clearing of Prosopis to salvage groundwater should target dense stands while less dense stands should be prevented from getting dense. {List only- not presented}

Abstract

Underground coal gasification (UCG) is considered a cleaner energy source as its known effect on the environment is minimal; it is cheaper and a lesser contributor to greenhouse gas emissions when compared to conventional coal mining. It has various potential impacts but the subsidence of the surface as well as the potential groundwater contamination is the biggest concerns. Subsidence caused by UCG processes will impact on the groundwater flow and levels due to potential artificial groundwater recharge. The geochemistry of the gasifier is strongly depended upon site specific conditions such as coal composition/type and groundwater chemistry. Independent of the coal rank, the most characteristic organic components of the condensates is phenols, naphthalene and benzene. In the selection of inorganic constituents, ammonia, sulphates and selected metals and metalloids such as mercury, arsenic, and selenium, are identified as the dominant environmental phases. The constituents of concern are generated during the pyrolysis and after gasification as dispersion and penetration of the pyrolysis take place, emission and dispersion of gas products, migration by leaching and penetration of groundwater. A laboratory-based predictive study was conducted using a high pressure thermimetric gasification analyser (HPTGA) to simulate UCG processes where syngas is produced. The HPTGA allows for simulation of the actual operational gasifier pressure on the coal seam and the use of the groundwater sample consumed during gasification. A gasification residue was produced by gasifying the coal sample at 800 °C temperature and by using air as the input gas. The gasification residue was leached using the high temperature experimental leaching procedure to identify the soluble phases of the gasified sample. The leachate analysis is used to determine the proportion of constituents present after gasification which will be removed by leaching as it is exposed to external forces and how it will affect the environment. The loading to groundwater for the whole gasifier is then determined by applying the leachate chemistry and rock-water ratio to the gasifier mine plan and volumes of coal consumed. 

Abstract

In South Africa, the use of stochastic inputs in surface water resources assessments has become the norm while this is rarely done for groundwater resources. Studies that have applied multi-site and multi-variate methods that incorporate stochastic generation of groundwater levels are limited. Stochastic based inputs account for uncertainties attributed to inherent temporal and spatial variability of hydrologic variables and climatic conditions. This study applied variable length block (VLB) stochastic generator for simultaneous generation of multi-site stochastic time series of rainfall, evaporation and groundwater levels. In the study, 100 stochastic sequences with record length of 34 years (1980-2013), similar to the historic one were generated. Performance of VLB was assessed by comparing single statistics of historic time series located within box plots of the 100 annual and monthly stochastically generated time series. The statistics used include mean, median, 25th and 75th percentiles, lowest and highest values, standard deviation, skewness, and serial and cross correlation coefficients. Majority (9 out of 10) of the historical statistics were mostly well preserved by VLB, except for skewness. Historic highest groundwater levels were mostly underestimated. Historic statistics below interquartile range (overestimation) is a common problem of weather generators which can be reduced by including additional covariates that influence atmospheric circulation. The generation of multi-site stochastic sequences support realistic assessment of groundwater resources and generation of groundwater operating rules.

Abstract

Pollution of underground water is fast becoming a global problem and South Africa is not immune to this problem. The principal objective of this paper is to investigate the effectiveness of laws and policies put in place to mitigate underground water pollution. The paper also seeks to examine the causes and types of underground water pollution followed by a closer look into the laws and policies in place to mitigate the pollution levels. Finally, the paper seeks to ascertain whether the current policies are properly implemented. The paper follows content analysis (desk research) to achieve the objectives. Policy recommendations are given based on the findings. {List only- not presented}

Abstract

Data acquisition and Management (DAM) is a group of activities relating to the planning, development, implementation and administration of systems for the acquisition, storage, security, retrieval, dissemination, archiving and disposal of data. Data is the life blood of an organization and the Department of Water and Sanitation (DWS) is mandated by the National Water Act (No 36 of 1998) as well as the Water Services Act (No 108 of 1997), to provide useful water related information to decision makers in a timely and efficient manner. In 2009 the DWS National Water Monitoring Committee (NWMC) established the DAM as its subcommittee. The purpose was to ensure coordination and collaboration in the acquisition and management of water related data in support of water monitoring programs. The DAM subcommittee has relatively been inactive over the years and this has led to many unresolved data issues. The data extracted from the DWS Data Acquisition and Management Systems (DAMS) is usually not stored in the same formats. As a result, most of the data is fragmented, disintegrated and not easily accessible, making it inefficient for water managers to use the data to make water related decisions. The lack of standardization of data collection, storage, archiving and dissemination methods as well as insufficient collaboration with external institutions in terms of data sharing, negatively affects the management water resources. Therefore, there is an urgent need to establish and implement a DAM Strategy for the DWS and water sector, in order to maintain and improve data quality, accuracy, availability, accessibility and security. The proposed DAM Strategy is composed of the six main implementation phases, viz. (1) Identification of stakeholders and role players as well as their roles and responsibilities in the DWS DAM. (2) Definition of the role of DAM in the data and information management value chain for the DWS. (3) Development of a strategy for communication of data needs and issues. (4) Development of a DAM life Cycle (DAMLC). (5) Review of existing DAMS in the DWS. (6) Review of current data quality standards. The proposed DAM Strategy is currently being implemented on the DWS Groundwater DAM. The purpose of this paper is to share the interesting results obtained thus far, and to seek feedback from the water sector community.

Abstract

Well-established engineered systems for depth-discrete monitoring in fractured rock boreholes (referred to as a Multilevel System or MLS) are commercially available and offer much diversity in design options, however, they are used infrequently in professional practice and have seen minimal use in groundwater research. MLSs provide information about hydraulic head and hydrochemistry from many different depths in a single borehole and, therefore, magnify greatly the knowledge value of each borehole. Conventional practice globally is devoted to standard monitoring wells, either alone as longer single screened wells or in clusters or nests with a few wells screened at different depth intervals. These are the mainstay of the groundwater science and engineering community and severely limit prospects for each borehole to provide the information needed to solve the complex problems typically posed by fractured rock. This paper outlines the nature and evolution of MLS technologies and points to recent literature showing how MLSs add important insights that cannot be obtained using conventional wells. Also, it reviews commercially available MLS technologies, which present a range of robust options with each system having different characteristics and niches depending on characterization and monitoring goals and site conditions. The paper also describes refined MLS criteria aimed at improving the cost effectiveness and expanding capabilities of MLSs, so as to improve their accessibility for high resolution data acquisition in the context of both groundwater system characterization and long-term monitoring.

Abstract

Understanding the hydrogeochemical processes that govern groundwater quality is important for sustainable management of the water resource. A study with the objective of identifying the hydrogeochemical processes and their relation with existing quality of groundwater was carried processes in the shallow aquifer of the Lubumbashi river basin. The multivariate statistical approach includes self organizing maps (SOM'S) of neural networks, hierarchical cluster (HCA) and principal component analysis of the hydrochemical data were used to define the geochemical evaluation of aquifer system based on the ionic constituents, water types, hydrochemical facies and groundwater factors quality control. Water presents a spatial variability of chemical facies (HCO3- - Ca2+ - Mg2+, Cl- - Na+ + K+, Cl- - Ca2+ - Mg2+ , HCO3- - Na+ + K+ ) which is in relation to their interaction with the geological formation of the basin. The results suggests that different natural hydrogeochemical processes like simple dissolution, mixing, weathering of carbonate minerals and of silicate weathering and ion exchange are the key factors. Added to this is the imprint of anthropogenic input (use of fertilizers, septic practice poorly designed and uncontrolled urban discharges). Limited reverse ion exchange has been noticed at few locations of the study.

Abstract

Modelling of groundwater systems and groundwater-surface water interaction using advanced simulation software has become common practice. There are a number of approaches to simulate Lake-aquifer interactions, such as the LAK Package integrated into MODFLOW, the high conductivity and fixed stage approaches. LAK and the high conductivity approaches were applied and compared in simulating Lake- aquifer interaction in the Lake Sibayi Catchment, north-eastern, South Africa using the finite difference three-dimensional groundwater flow model, Visual MODFLOW Flex under steady state conditions. The steady state model consisted of two layers: an upper layer consisting of the Sibayi, KwaMbonambi, Kosi Bay and Port Durnford Formations which have similar characteristics, and a lower model layer representing the karst, weathered and calcareous Uloa Formation. The bottom model boundary is constrained by the impermeable Cretaceous bedrock. The model area covers the surface and groundwater catchments of Lake Sibayi which is constrained in the east by the Indian Ocean. A no-flow boundary condition is assigned to the northern, western and southern sides and a constant head boundary is assigned to the eastern side. The Mseleni River and neighbouring plantations were modelled using the River and Evapotranspiration boundary conditions respectively. Input parameters for the various boundary conditions were obtained from the previously developed high resolution conceptual model, including recharge

Abstract

Identifying and characterising the vertical and horizontal extent of chlorinated volatile organic compound (CVOC) plumes can be a complex undertaking and subject to a high degree of uncertainty as dense non-aqueous phase liquid (DNAPL) movement in the subsurface is governed most notably by geologic heterogeneities. These heterogeneities influence hydraulic conductivity allowing for preferential flow in areas of higher conductivity and potential pooling or accumulation in areas of lower conductivity. This coupled with the density-induced sinking behaviour of DNAPL itself and the effects of groundwater recharge in the aquifer result in significant challenges in assessing the distribution and extent of CVOC plumes in the subsurface. It has been recognized that high resolution site characterization (HRSC) can provide the necessary level of information to allow for appropriate solutions to be implemented to mitigate the effects of subsurface contamination. Although the initial cost of HRSC is higher, the long-term costs can be substantially reduced and the remedial benefits far greater by obtaining a better understanding of the plume characteristics upfront. The authors will discuss a case study site in South Africa, where ERM has conducted HRSC of a CVOC plume to characterise the distribution of the source area and plume architecture in order to assess the potential risk to receptors on and off-site. The source of impact resulted from the use of a tetrachloroethene (PCE)-based solvent in an on-site workshop. The following methods of characterization were employed:
- Conducting a passive soil gas survey to identify and characterise potential source zones and groundwater impacts;
- Vertical characterisation of the hydrostratigraphy, contaminant distribution and speciation in real time using a Waterloo Advanced Profiling System (APS) with a mobile on-site laboratory;
- Using the Waterloo APS data to design and install groundwater monitoring wells to delineate the vertical and lateral extent of contamination; and
- Conducting a vapour intrusion investigation including sub-slab soil gas, indoor and outdoor air sampling to estimate current risk to on-site employees.
In less than a year, the risk at the site is now largely understood and the strategies for mitigating the effects of the contamination can be targeted and optimised based on the information gained during the HRSC assessment.

Abstract

In the following study, the soil and groundwater regime of the Rietvlei wetland near Cape Town are characterised. This has been done by means of logging the subsurface material during the construction of 8 shallow wells, complimented with field observations, and surveying the dug wells. The water stemming from these wells was sampled and analysed for Oxygen 18 and Deterium. Downhole salinity logs of the wells were also undertaken and rainfall samples were analysed for the aforementioned stable isotopes. Results indicate a distinct relationship between elevation and soil structure. Through the use of the water table method, it was found that the relationship between elevation and soil moisture had a direct impact on spatially distributed groundwater recharge on an event basis. Furthermore, higher salinities were found with depth in groundwater in the same wells which had higher recharge values. Isotopic results indicate that groundwater all stems from rainfall, with the exception of Well 8 is influenced by the river due to its proximity to the surface water body. The various water chemistries and soil profiles have a direct impact on the type of flora and its distribution throughout the study area. This study managed to conceptualize the relationship between groundwater, soil profiles and the various plant types surviving in the Rietvlei wetland. Future studies can focus on computer based approaches in order to predict how changes in groundwater characteristics caused by natural or anthropogenic factors would affect other ecohydrological processes within the wetland. These findings can be incorporated in decision making processes concerning groundwater management.

Abstract

Three dimensional numerical flow modelling has become one of the best tools to optimise and management wellfields across the world. This paper presents a case study of simulating an existing wellfield in an alluvial aquifer directly recharged by a major perennial river with fluctuating head stages. The wellfield was originally commissioned in 2010 to provide a supply of water to a nearby Mine. Ten large diameter boreholes capable of abstracting ±2 000 m3 /hour were initially installed in the wellfield. The numerical groundwater flow model was used to evaluate if an additional 500 m3 /hour could be sustainably abstract from the alluvial aquifer system. A probabilistic river flow assessment and surface water balance model was used to quantify low and average flow volumes for the river and used to determine water availability in the alluvial aquifer over time. Output generated indicated that the wellfield demand only exceeded the lowest 2% (98th percentile) of measured monthly river flow over a 59 year period, thereby proving sufficient water availability. Conceptual characterisation of the alluvial aquifer was based on previous feasibility studies and monitoring data from the existing hydrogeological system. Aquifer parameters was translated into the model discretisation grid based on the conceptual site model while the MODFLOW River package was used to represent the river. Actual river stage data was used in the calibration process in addition to water levels of monitoring boreholes and pump tests results. The input of fluctuating river water levels proved essential in obtaining a low model error (RMSE of 0.3). Scenario modelling was used to assess the assurance of supply of the alluvial aquifer for average and drought conditions with a high confidence and provided input into further engineering designs. Wellfield performance and cumulative drawdown were also assessed for the scenario with the projected additional yield demand. Scenario modelling was furthermore used to optimise the placement of new boreholes in the available wellfield concession area.

Abstract

With the revision of the European Drinking Water Directive (Directive on the quality of water intended for human consumption 2020/2184) in December 2020, the preparation of Water Safety Plans (WSP) is foreseen according to the guidelines of WHO. Within the EU Interreg Adrion MUHA project, a decision support tool (DST) has been developed to provide a holistic approach to drinking water infrastructure risk analysis. The project mainly addresses four water-related risks: accidental pollution, floods, droughts and earthquakes. The core of the DST is the inventory of hazardous events (causes, their consequences and impacts) for each component of the drinking water supply chain: (1) drinking water source - catchment area, (2) water supply system, and (3) domestic distribution system. For each identified potential hazard, the type of hazard was determined (e.g., biological, chemical, radiological, or physical hazard (including turbidity), inadequate availability of water supplied to customers, safety to personnel, external harm to third parties, including liability). The DST was tested in the partner countries (Italy, Slovenia, Croatia, Serbia, Montenegro and Greece) to verify the resilience of the measures and elaborate the WSP.

In the end, the REWAS-ADRION strategy was elaborated, aiming to increase the resilience of drinking water supplies to floods, droughts, accidental pollution, and earthquake-related failures by improving the water safety planning mechanism based on the concept of inter-agency cooperation to support water utilities, civil protection organizations, and water authorities.

Abstract

Implementation of a mining project in South Africa involved dewatering of a fractured rock aquifer at considerable depth below ground level. Groundwater quality within this aquifer is not suitable for domestic use due to high levels of salinity. Numerous geological investigations in the area indicate that the target aquifer is confined, with a different piezometric head to the shallower aquifers. However, regulators and other interested and affected parties expressed concern regarding the potential mixing of more saline groundwater from the deeper aquifer to be dewatered with groundwater from shallower aquifers, which are extensively used for farming and domestic purposes.
A large database of groundwater quality monitoring data collected over 16 years was available to investigate the degree of mixing between the deeper more saline and shallower freshwater aquifers. The groundwater chemistry of selected boreholes with known geological profile, depth and construction was used to develop groundwater fingerprinting criteria for each of the aquifers in the area. These fingerprinting criteria were then applied to private and exploration boreholes in the area in order to identify the main aquifer from which groundwater was being sourced. Once the boreholes were classified in terms of groundwater origin, an attempt was made to identify indicators of mixing with deeper, more saline groundwater from the aquifer being dewatered.
Groundwater fingerprinting allowed identification of impacts related to the mining operations. The data showed that there was no upward mixing of water related to dewatering operations, but rather that surface spillages and disposal schemes may have resulted in minor changes in shallow groundwater quality. {List only- not presented}

Abstract

Gold Mining activities the past 60 years at AngloGold Ashanti polluted the groundwater underlain by 4000 ha of land at the Vaal River and West Wits operations in South Africa. Sulphide material in Tailings Storage Facilities, Waste Rock Dumps and extraction plants produce Saline Mine Drainage with Sulphate, minor salts and metals that seep to the groundwater and ultimately into surface water resources. Water regulation requires mines to prevent, minimise/ reduce or eliminate pollution of water resources. The waste philosophy has matured from tolerate and transfer to treat and termination of pollution sources. The impact of the pollution was determined and possible technologies to treat the impact were evaluated. Source controls of proper water management by storm water management, clean dirty water separation, lined water conveyance structures and reduced deposition of water on waste facilities is crucial. The aquifer character determines the possible remediation technology. From the possible technologies phytoremediation, physical interception and re-use of this water was selected. In future possible treatment of the water would be considered. This paper explain the strategy and report on the phased implementation of these plans and the expected results. The establishment of 750 ha of woodlands as phytoremediation, interception trenches of 1250 m, 38 interception boreholes and infrastructure to re-use this water in 10 water management areas is planned. The total volume of 15 Ml/day would be abstracted for re-use from the boreholes and trenches. The woodlands can potentially attenuate and treat 5 ml/day. The established woodlands of 150 ha proof successful to intercept diffused seep over the area of establishment and reduce the water level and base flow. The 2 implemented trenches of 1000 m indicate a local decline in the water level with interception of shallow groundwater within 1-2 m from surface. The 2 production interception well fields abstracting 50 and 30 l/s respectively indicate a water level decline of between 2 to 14 m with regional cones of depression of a few hundred meters to intercept groundwater flow up to 20 meter. Predictions from groundwater modelling indicate that these schemes can minimise pollution during the operational phase and protect downstream water resources. Predictions from modelling indicate that the pollution sources need to be removed to ensure long term clean-up to return the land to save use. The gold and uranium prize is securing the removal of the sources through re-processing of the tailings and waste rock dumps. After removal of the sources of pollution the remediation schemes would have to be operated for 20 years to return the groundwater to an acceptable standard of stock watering and industrial water use. The water quality is observed by a monitoring network of approximately 100 observation boreholes.

Abstract

As we look at the legislation set out in the driving policies and its guiding frameworks, the need for able institutions to implement strategies that promise and deliver social growth and development, are highlighted. It is only possible to define an 'able institution' through its ability to fulfil its function and enable stakeholders to be part of the decision-making process. (Goldin, 2013) It is this relationship with the collection of stakeholders, in particular strategic water resource stakeholders, their linkages as well as the identification of specific stakeholder issues, that are critically reviewed. The recent Groundwater Strategy (2010) identified key strategic issues/themes. Each chapter listed a number of well thought out recommended actions that address specific challenges in each theme. It is the need for strategic direction (to put these strategies in place "plans into action") and to articulate the specific vision in the right context to the different stakeholders, (internal as well as external) that requires thinking. It is also the uptake of this information by publics (social action and intervention) and the impact of new learning that will need to be measured. This paper will present on a study where the groundwater sector and all its stakeholders are strategically examined to understand the process of communal thinking in the current environmental conditions. It would draw from current communication practices, style, strengths, sector experiences and trends and also reference specific and unique experiences as with the recent WRC Hydrogeological Heritage Overview: Pretoria project. {List only- not presented}

Abstract

Groundwater levels in E33F quaternary catchment are at their lowest level ever. The impact of climatic variation and increasing abstraction were determined to be the main factor. There are 115 registered groundwater users in E33F and the monthly abstraction volumes are not being measured. There is a need to use land use activities as well as the population to estimate groundwater use. The main objective is to use non-groundwater monitoring data to estimate groundwater use in order to protect the aquifer and ecosystem in general in varying climatic condition. Land use activities information was used to estimate groundwater use in E33F quaternary catchment. The estimated groundwater use volumes were compared to allocated and measured volumes. For domestic groundwater use estimation, population data and an estimation 100 litre per person per day were used. The water requirements for the types of crops being cultivated together with the area (m2) were used to estimate groundwater use volumes for irrigation. The number and type of live stocks were used with the water requirements for each livestock type to estimate the groundwater use volumes. 96 % of groundwater users are using groundwater for irrigation purposes with 9 966 105 m3/a allocated for irrigation. Mining, industries, domestic and livestock are allocated 100 200 m3/a. The estimated groundwater use volume for irrigation is 30 960 000 m3/a, which is three times higher than the allocated volume. Groundwater use volume for domestic use is estimated to be 38 225 m3/a which is higher than the 31 000 m3/a allocated. The total estimated groundwater use volume in E33F is estimated to be 30 998 225 m3/a, which is three times higher than the allocated groundwater use volume of 10 066 305 m3/a. This estimation could be higher as only registered boreholes were used and estimations from mining, Industries and live stocks were excluded due to lack of data

Abstract

Until 1998 groundwater was managed separately from surface water and was seen as a private resource. The National Water Act of 1998 (Act 36 of 1998) (NWA) was forward thinking in that it saw groundwater as an integrated part of the water resource system and as a common resource to be managed by the Department of Water and Sanitation (DWS) as custodian. Various tools had been provided to manage the water resources equitably, sustainably and efficiently. A limited understanding of groundwater and the prevalence to revert to engineering principles when managing water resources had led to an Act that is mostly written with surface water in mind. The tools and principles that had been tested for surface water was used directly for groundwater without considering the practicalities in applying and enforcing the NWA. This did not provide too many problems, as groundwater was not considered a viable, sustainable water resource, and the use of groundwater was mostly limited to private use for garden irrigation, in agriculture for irrigation and for bulk supply in a number of small towns where surface water was not available. This has changed drastically during the recent drought that affected the whole country, but especially the Western Cape. Groundwater was suddenly seen as the solution to the problem of water availability. The problem was that the understanding of groundwater has not increase sufficiently over the years, and water resources management is still skewed to hydrology principles that apply to surface water. Groundwater sustainability is at the heart of the questions of scale and measurements. The Department has been flooded by the large number of water use licence applications that have been submitted by municipalities, industries and agriculture as a result of the drought. This article will look at groundwater resource assessment and allocation methodology in a South African context.

Abstract

Edible vegetable oil (EVO) substrates have been successfully used to stimulate the in situ anaerobic biodegradation of groundwater contaminated chlorinated solvents as well as numerous other anaerobically biodegradable contaminants like nitrates and perchlorates at a many commercial, industrial and military sites throughout the United States of America and Europe. EVO substrates are classified as a slow release fluid substrate, and comprise of food grade vegetable oil such as canola or soya bean oil. The EVO substrate serves as an easily biodegradable source of carbon (energy) used to create a geochemically favorable environment for the anaerobic microbial communities to degrade specific contaminants of concern. EVO substrate's can either be introduced into the subsurface environment as pure oil, in the form of light non aqueous phase or as an oil/water emulsion. The emulsified vegetable oil substrates holds several benefits over non-emulsified vegetable oil as the fine oil droplet size of the commercially manufactured emulsified oils can more easily penetrate the heterogeneous pore and fracture spaces of the aquifer matrix. The use of this technology to stimulate in situ biodegradation of groundwater contaminants is still relatively unknown in South Africa. This paper will give an overview of the EVO technology and its application, specifically looking at the advantages of using this relatively inexpensive, innocuous substrate based technology to remediate contaminated groundwater within fractured rock environments commonly encountered in South Africa. {List only- not presented}

Abstract

This paper presents data obtained from sampling and geochemical analysis of gold tailings and associated pool and drain water. Inverse geochemical modelling using PHREEQC indicated geochemical processes operating in the tailings between the pool and drains. These included pyrite oxidation and dissolution of various minerals identified in the tailings. The processes were incorporated into an ensemble geochemical model to calculate post-closure sulphate concentration in tailings seepage.

The ensemble model included a spreadsheet model to calculate oxygen flux at various depths in the tailings column, and a one-dimensional transport model in PHREEQC. The calculated oxygen flux was applied to each cell in the tailings column to determine the amount of sulphide oxidation and the release of acidity into the tailings pore water. The rate of vertical transport of pore water in the column was determined from physical characterisation of the tailings particle size and saturated hydraulic conductivity.

The model results indicate elevated sulphate concentrations and acidity moving as a front from the top of the column downwards. The modelled sulphate concentration of 1 500 to 1 900 mg/L 8-16 years after closure compared well with measurements of drain water quality at a tailings dam decommissioned approximately 16 years ago. This provided some credibility to the modelled result of 2 300 mg/L sulphate up to 50 years post-closure. However, the tailings moisture content, infiltration rate, and pyrite oxidation rate in the model were based on literature values, rather than site-specific measurements.

Abstract

The redox state of groundwater is an important variable for determining the solubility and mobility of elements which can occur in different redox states at earth surface conditions, such as Fe, Mn, Cr, As, U, N, S, V etc. Eh-pH diagrams are potentially invaluable for understanding and predicting the behaviour of these redox species yet, unlike pH, redox is seldom a routine field parameter due to the difficulties in measurement and interpretation.
This paper discusses the potential use and limitations of field measurements of the redox state of groundwater with specific reference to the geochemical behaviour of dissolved iron in the Table Mountain Group (TMG) aquifer. As part of an investigation into iron cycling within the TMG aquifer, the redox state of groundwater was estimated through three different methods, namely direct in-situ measurement of Eh, direct measurement of DO and calculation from iron speciation in groundwater. Comparison of the results from the three methods highlights the potential value of collecting redox data, but also the complexity of controls on redox potential. The redox measurements allowed the determination of the controlling reactions on iron mobility within the TMG, but only by using the iron speciation method to calibrate the in-situ values and thereby identify which redox pair was controlling redox equilibrium. As this requires measurement of redox ion pairs in solution, it is unlikely to become a routine method for redox assessment, unless the specific redox state of an element is critical in understanding its mobility. For the majority of groundwater site investigations, measurement of the dissolved oxygen content of groundwater is probably sufficient as a first pass.

Abstract

Underground Coal Gasification (UCG) is an emerging, in-situ mining technology that has the advantage to access a low cost energy source that is currently classified as not technically or economically accessible by means of conventional mining methods. As such it offers significant potential to dramatically increase the world's non-recoverable coal resource.

Groundwater monitoring in the South African mining industry for conventional coal mining as an example, is well established, with specific SANS, ASTM and ISO Standards dedicated for the specific environment, location and purposes. In South Africa a major impact of the coal mining industry can be a reduction in the groundwater quantity and quality. South-Africa's groundwater is a critical resource that provides environmental benefits and contributes to the well-being of the citizens and the economic growth. Groundwater supplies the drinking water needs of a large portion of the population; in some rural areas it represents the only source of water for domestic use. Utilization and implementation of groundwater monitoring programs are thus non-negotiable.

The groundwater quality management mission, according to the Department of Water and Sanitation in South-Africa, is set in the context of the water resources mission and is as follows:

"To manage groundwater quality in an integrated
and sustainable manner within the context of the National
Water Resource Strategy and thereby to provide an
adequate level of protection to groundwater resources
and secure the supply of water of acceptable quality."

The scope of this paper is to propose an implemention strategy and a fit-for-purpose groundwater monitoring program for any Underground Coal Gasification commercial operation. It is thus important to pro-actively prevent or minimise potential impacts on groundwater through long-term protection and monitoring plans. A successful monitoring program is one that consists of
(1) an adequate number of wells, located at planned and strategic points;
(2) sufficient groundwater sampling schedules; and
(3) a dedicated monitoring program and quality control standard.

In order to have an efficient monitoring program and to prevent unnecessary analysis and costs, it is also critical to determine upfront what parameters have to be monitored for the specific process and site conditions.

Abstract

The national water balance is primarily based on the availability of surface water and the historic allocation thereof. The changes that are required the next 20 years to ensure sustainable development of the nation will be painful, but is unfortunately at present not part of the public discussion, it is essentially ignored in favour of more "popular water topics".This paper intends to look at a few core aspects, they include the current water allocation in the national water balance, the relative value of the utilisation, the position of groundwater resources in changing the current relative allocation and the current groundwater utilisation. The paper further intends to be a less formal presentation of these aspects with the required data, references and conclusions available for distribution afterwards.

Abstract

The main purpose of this paper is to present a case study where a water balance concept was applied to describe the expected groundwater safe yield on a sub-catchment scale. The balance considers effective recharge based on local hydrogeology and land cover types, basic human needs, groundwater contribution to baseflow, existing abstraction and evaporation. Data is derived from public datasets, including the WRC 90 Water Resources of South Africa 2012 Study, 2013-2014 South African (SA) National Land Cover and Groundwater Resource Assessment Ver. 2 (GRAII) datasets. The result is an attempt to guide a new groundwater user regarding the volume of groundwater that can be abstracted sustainably over the long-term.

Abstract

Simple and cost-effective techniques are needed for land managers to assess and quantify the environmental impacts of hydrocarbon contamination. During the case study, hydrocarbon plume delineation was carried out using hydrogeological and geophysical techniques at a retail filling station located in Gauteng.

Laboratory and controlled spill experiments, using fresh hydrocarbon product, indicate that fresh hydrocarbons generally have a high electrical resistivity, whilst biodegraded hydrocarbons have a lower resistivity. This is attributed to the changes from electrically resistive to conductive behaviour with time due to biodegradation. As such, it should be possible to effectively delineate the subsurface hydrocarbon plume using two-dimensional (2D) Electrical Resistivity Tomography (ERT). As part of the case study, two traverses were conducted using an Electric Resistivity Tomography (ERT) survey with an ABEM SAS1000 Lund imaging system. The resultant 2D tomographs were interpreted based on the resistivity characteristics and subsurface material properties to delineate the plume. Localised resistivity highs were measured in both models and are representative of fresh hydrocarbons whereas areas of low resistivity represented areas of biodegraded hydrocarbons.

More conventional plume delineation techniques in the form of intrusive soil vapour and groundwater vapour surveys as well as hydrochemical anlayses of the on-site monitoring wells were used to compare the results and to construct the detailed Conceptual Site Model. During the investigation, four existing monitoring wells located on the site and additional two wells were installed downgradient of the Underground Storage Tanks (USTs) in order to determine the extent of the plume.

In conclusion, a comparison was found between the groundwater results and geophysical data obtained during the case study and it was concluded that ERT added a significant contribution to the Conceptual Site Model.

Abstract

Many groundwater models are commissioned and built under the premise that real world systems can be accurately simulated on a computer - especially if the simulator has been "calibrated" against historical behavior of that system. This premise ignores the fact that natural processes are complex at every level, and that the properties of systems that host them are heterogeneous at every scale. Models are, in fact, defective simulators of natural processes. Furthermore, the information content of datasets against which they are calibrated is generally low. The laws of uncertainty tell us that a model cannot tell us what will happen in the future. It can only tell us what will NOT happen in the future. The ability of a model to accomplish even this task is compromised by a myriad of imperfections that accompany all attempts to simulate natural systems, regardless of the superficial complexity with which a model is endowed. This does not preclude the use of groundwater models in decision-support. However it does require smarter use of models than that which prevails at the present time. It is argued that, as an industry, we need to lift our game as far as decision-support modeling is concerned. We must learn to consider models as receptacles for environmental information rather than as simulators of environmental systems. At the same time, we must acknowledge the defective nature of models as simulators of natural processes, and refrain from deploying them in a way that assumes simulation integrity. We must foster the development of modelling strategies that encapsulate prediction-specific complexity supported by complexity-enabling simplicity. Lastly, modelers must be educated in the mathematics and practice of inversion, uncertainty analysis, data processing, management optimization, and other numerical methodologies so that they can design and implement modeling strategies that process environmental data in the service of optimal environmental management.

Abstract

Water resource management and risk management rely heavily on the availability of data and information. This includes the volumes of water needed, the volumes of water available, where the available water is and where it would be needed, etc. Historical records help to determine past use and gives a way to predict future use in the case of water resource planning while it helps to predict the possibility of floods and droughts when it comes to risk management. Rainfall data can provide valuable data for both water resource planning and risk management, since it is the input to the hydrologicalcycle. It is possible to determine dry and wet cycles using the cumulative deviation from mean that is calculated from the measured rainfall data. This was done for the Gnangara Mound in Australia, with the results giving a fair representation of the dry and wet cycles in the area. Data measured over a period of about 30 years for the Zachariashoek sub-catchment analyzed in the same fashion provided wet-dry cycles of about 8 years. The rainfall measurements had been taken at various settings around the catchment, and varied from place to place and differed from that measured at the WeatherSA stations in the vicinity. This article will draw a comparison between the Zachariashoek data and the WeatherSA data to determine whether the WeatherSA data followed the same patterns for the wet-dry cycles observed in Zachriashoek. It will then analyse the longer data record available for the WeatherSA data from 1920 to 2012. It is expected that the shorter wet-dry cycles seen in Zachariashoek will become part of longer wet-dry cycles that can be used in water resource planning and risk management. Rainfall is also dependent on a number of factors

Abstract

Arsenic is a common contaminant typically found in effluent from gold mine operations and copper smelters throughout the world. The geochemical behaviour of arsenic in contact with dolomite underlying an arsenic containing waste rock pile was investigated. The interaction between the arsenic and the dolomite is an important control in the subsequent transport of the arsenic in the dolomitic aquifer. Rocks with varying dolomite content were tested to investigate the interaction between the arsenic and dolomite. From the modelling and test results it was estimated that in the aquifer, between 60 - 90% of arsenic is present in the solid phase under oxidation conditions at >50 mV. At 50 to -25 mV about 40 - 60% of the arsenic is estimated to be present in the solid phase and below -25 mV about 0 - 10% of arsenic will be present in the solid phase. Although some arsenic is removed by the dolomite in the aquifer the arsenic would still be present above acceptable guidelines for drinking water. The arsenic in the solid phase will be in equilibrium with the aquifer water and could be remobilised 1) under more reducing conditions or 2) with a decrease in arsenic in the aquifer.

Abstract

Water scarcity is a global challenge, particular in South Africa, which is a semi-arid country. Due to the continuing drought, appropriate groundwater management is of great importance. The use of groundwater has increased significantly over the years and has become a much more prominent augmentation component to the supply chain especially in rural communities. However, the approach used to develop groundwater resources, specifically in rural areas, can be improved in numinous ways to ensure drilling of successful boreholes that could meet water demands. A recent study done in the Thaba Nchu area focused on an adapted approach, which resulted in drilling successful boreholes that would be able to sustain their augmentation role in the long term. The adapted approach involves (i) a hydro-census that includes local knowledge and focused field observations, (ii) study of aerial photographs and geological maps on a regional scale, rather than on a village scale area, (iii) an optimised geophysical investigation to identify and map geological structures to drill production boreholes, (iv) conducting aquifer pump test to determine an optimum sustainable yield, (v) collecting water samples to determine if water quality is suitable for its specific use (vi) providing a monitoring program and abstraction schedule for each borehole. The adapted approach highlights the following improvements: (i) drilling of new production boreholes during times of bounty to allow for better time management on the project; (ii) including an experienced geohydrologist during planning phases, (iii) including a social component focussing on educating local communities on the importance of groundwater and introducing them to the concept of citizen's science, (iv) establishing a communication channel through which villagers can report any mechanical, electrical, quantity or quality issues for timeous intervention. Through applying these small changes to established components of development of groundwater resources, budgets and time management were optimised and additional communities could be added to the project without additional costs. This approach not only emphasised ways to improve the awareness and potential of groundwater resources, but also affects the economical-, social- and environmental welfare in rural communities.

Abstract

Industrial Management Facilities represent a hazard to the down gradient surface water and groundwater environment. The assessment of the risks such facilities pose to the water environment is an important issue and certain compliance standards are set by regulators, particularly when the potential for an impact on the water environment has been identified. This paper will aim to describe how the contamination was conceptualized, estimated, limitations and how it is technically not feasible to establish one limit or compliance value of known contamination in different aquifers.

Abstract

When conducting water quality monitoring, questions arise on which water quality guidelines to use and where to apply them. For example, the use of South African Water Quality Guidelines (SAWQG) for Domestic usage compared to the use of the South African National Standards (SANS) for Potable Water Quality when monitoring drinking water quality. The World Heath Organization (WHO) published a set of water quality guidelines for drinking water which can also be used instead of SANS. Using various water quality guidelines to assess water quality can give different outcomes on the state of water quality of a particular site. For example, SANS water quality guidelines are less strict when compared to the SAWQG target values, however, SAWQG are comprised of different sets of standards for different usages. SAWQG distinguish between drinking water, livestock and irrigation, aquatic systems and industrial usage while SANS are only used for potable or bottled water. The International Finance Corporation (IFC) that is part of the World Bank Group published the Environmental, Health, and Safety (EHS) Guidelines for Environmental Wastewater and Ambient Water Quality, guidelines set specifically for wastewater and ambient water quality. Utilizing this poster, I will explain when to use which guidelines with different types of water samples. I will also discuss the stringent water use license limits applied at some sites compared to the national standards of South Africa.

Abstract

Understanding the hydrogeochemical processes that govern groundwater quality is important for sustainable management of the water resource. A study with the objective of identifying the hydrogeochemical processes and their relation with existing quality of groundwater was carried processes in the shallow aquifer of the Lubumbashi river basin. The study approach includes conventional graphical plots and multivariate analysis of the hydrochemical data to define the geochemical evaluation of aquifer system based on the ionic constituents, water types, hydrochemical facies and groundwater factors quality control. Water presents a spatial variability of chemical facies (HCO3- - Ca2+ - Mg2+, Cl- - Na+ + K+, Cl- - Ca2+ - Mg2+ , HCO3- - Na+ + K+ ) which is in relation to their interaction with the geological formation of the basin. The results suggest that different natural hydrogeochemical processes like simple dissolution, mixing, and ion exchange are the key factors. Limited reverse ion exchange has been noticed at few locations of the study. At most, factor analyses substantiate the findings of conventional graphical plots and provide greater confidence in data-interpretation. {List only- not presented}

Abstract

A standard methodology for establishing a groundwater baseline for unconventional gas projects in South Africa did not exist at the time the current study was undertaken. The study was therefore aimed at filling this gap, specifically focusing on hydraulic fracturing and underground coal gasification (UCG) operations.

An extensive literature review was conducted to establish the baseline methodology. The latest literature on hydraulic fracturing and UCG was reviewed to determine how these activities may potentially impact on the groundwater environment. The literature review further examined the role that geological structures, such as dolerite intrusives, may be play in the migration of contaminants associated with unconventional gas projects. The literature review then focused on questions such as what size the study area should be, what geological and hydrogeological investigations need to be conducted before embarking on the sampling events, which chemical parameters need to be included in the groundwater analyses, whether the drilling of dedicated boreholes are required to collect representative groundwater samples, and how to collect representative samples for these different chemical parameters.

In this paper, the proposed methodology is presented in the form of a flow diagram to be used to guide future groundwater baseline projects in South Africa.

Abstract

Water has been recognized and acknowledged as a fundamental natural resource that sustains environmental diversity, social and economic development (Liu et al., 2017; Fisher et al., 2017). With increasing populations, climate change and limited monitoring networks for both ground and surface water, freshwater resources are becoming difficult to assess due to rapid changes in water supply and uses. Several efforts have been devoted towards the monitoring and management of water resources and discovery of alternative sources of freshwater. One of the more recent efforts is using gravity information to track changes in water storage on the earth's surface. The Gravity Recovery and Climate Experiment (GRACE) mission (https://www.nasa.gov/mission_pages/Grace/index.html) holds great potential for assessing our water resources in areas with little monitoring data. The increasing interest in the use of GRACE as a water resource information and monitoring tool, is due to its cost effectiveness and user-friendly system which affords a broad understanding of the world we live in and its processes, specifically in water resource management and hydrological modelling. South Africa's National Water Act (NWA) of 1998 highlights the importance of the sustainable development of water resources. However, it is difficult to sustainably manage South Africa's groundwater resources due to the difficultly in measuring and understanding our complex aquifers. The challenges in establishing sustainable monitoring of groundwater resources and its Reserve, are due to insufficient knowledge about the contribution that groundwater makes to surface water, and methods which reliably monitor groundwater resources. The GRACE is a joint satellite mission by the Deutschen Zentrum fur Luftund Raumfahrt (DLR) in Germany and the United States National Aeronautics and Space Administration (NASA). The satellite was launched on 17 March 2002 and provides monthly temporal differences of earth's gravity field and its mean gravity field (Schmidt et al., 2008). It can afford insights into the location of groundwater resources, and their changes. GRACE can however, only determine the change in total water storage and therefore information on other components of the water balance are required to isolate the groundwater component. Therefore, the integrated Pitman Model is ideal to be applied together with GRACE and the Model can isolate surface water, soil moisture and groundwater into various components. Many studies have evaluated GRACE-derived groundwater storage changes as a response to drought (Famiglietti et al. 2011; Scanlon et al., 2012), while Thomas et al. (2017b) evaluated a groundwater drought index based on GRACE observations in an effort to understand and identify groundwater drought. Typically, GRACE is applied at scales of 150 000 km2, however Thomas et al., (2017) has developed a recent method that allows for the application of his GRACE derived Groundwater Drought Index (GGDI) at smaller scales. This study applies Thomas et al. 2017 GGDI in South Africa to the Crocodile, Sedgefield and Doring catchments, in hopes to to evaluate drought characterisation using data from GRACE satellites, focusing on the total water storage deficits to characterise groundwater drought occurrence.

Abstract

Precision agriculture continuously seeks improved methods to enhance productivity whether it is for greater crop yields or economic viability regarding labour inputs and satisfying the demand in a shorter time span. Soil moisture is one important factor that drives the agricultural industry and is therefore of utmost importance to manage it correctly. A shortage of water may result in reductions in yield, while excess irrigation water is a waste of water resources and can also have a negative impact on plant growth. Knowledge of the spatial distribution of soil moisture is important for determining soil moisture storage and soil hydraulic transport properties. Capturing field heterogeneity without exhaustive sampling and costly sample analysis is difficult. Electromagnetic induction, Frequency Domain Reflectometry, Neutron Scattering and conventional soil sampling have been utilised to determine the spatial variability of soil moisture within a field. Emphasis has been placed on practicality and accuracy of all the methods. Electromagnetics have proven itself to be the primary method to determine soil moisture within the field by comparing the results of the volumetric soil water content present in the field together with a combination of various soil properties such as clay and silt content, sand fraction, concretions, density and soil depth that contribute towards the accumulation of soil water. Electromagnetic induction has the highest resolution of data collected for a specific time period of all considered methods making it economically the best option for soil moisture management within a variable rate irrigation system. Electromagnetic induction has proven to be successful in delineating a field into management zones consisting of different classes based on observed conductivity values. Higher conductive zones are considered with small water demand. Lower conductive zones are considered with a greater water demand through a variable rate irrigation system. These water management zone maps could be informative for modelling, experimental design, sensor placement and targeted zone management strategies in soil science, hydrogeology, hydrology, and agricultural applications.

Abstract

The provision, usage and discharge of water resources are major concerns for coal mines, both underground and opencast. Water resources in a coal mining environment will often account for a significant portion of the daily operational cost. In order to cut costs, the mine will often collect as much runoff as possible to recycle for future use. This on-going recycling of site water and management of the resource demands a complete site water balance model in order to understand the dynamics of the resource within the boundaries of the mine. To improve the understanding of the dynamics of the resource on a much larger scale, and the effect it will have on recharge in an open cast coal mine environment, one must consider alternative modelling approaches which can compensate for such conditions. This amounts to describing recharge as a modelling component in a physically based distributed model. The main goal of this project is to calculate recharge into the main pit at this specific colliery by applying parameters on a quaternary catchment scale. The colliery is located just west of the town of Ogies, Mpumalanga on the peripheral region of the quaternary catchment B20G. The physiography of the quaternary catchment B20F is described as a central Highveld region gently sloping to the north. The geohydrological modeling application MIKE SHE (developed by DHI) was used to develop a fully integrated catchment model. The model was created mainly to simulate the impact of human activities on the hydrological cycle and hence on water resource development and management. Different modules of MIKE SHE that was used during the modelling stage include saturated- and unsaturated flow and a small degree of overland flow.

Key words: Mpumalanga, MIKE SHE, recharge

Abstract

Decades of monitoring, characterising, and assessing nitrate concentration distribution and behaviour in the soil profile and it's pathway into groundwater have resulted in a good understanding of its distribution in the country. While the national distribution is of great importance, site specific conditions determine fate, transport, and ultimately concentration in a specific area. Field experimental work included installation of a barrier containing a cheaply available carbon source to treat groundwater. The "reactor"/ tank with dimensions- 1,37m height, 2.15m diameter used for the experiment was slotted for its entire circumference by marking and grinding through the 5mm thick plastic material. The top section was left open to allow for filling and occasional checking of filled material during the experiment. The tank was packed with Eucalyptus globulus woodchips which was freely available at the site. Concentrations of groundwater nitrate at the site were well over what could be expected in any naturally occurring groundwater systems, and would result only by major anthropogenic activities in unconfined aquifer areas of South Africa. The changes in parameter concentrations with time were measured in order to determine the efficiency and life span of the carbon source used for the experiment. This paper considers 35 months of monitoring at a site where a low technology method was implemented. Field implementation was tested at a site which previously experienced some NH4NO3 spills. Main results from the field work showed that nitrate was totally removed at the treatment zone and surrounding boreholes, and even sulphate and NH4+ were removed during the experiment. This shows that the woodchips were successful in affecting denitrification for 35 months. Data also shows that boreholes further downstream from the tank had reduced NO3-, SO42- and NH4+ levels. Using the available biodegradable carbon for the woodchips based on its composition, a barrier lifespan could be determined. The results of calculations showed that the barrier would be effective for at least another 6.9 years from the period of the last sampling date. A total lifespan of about 10 years can thus be estimated.

Abstract

In the management of water resources especially groundwater resources, implementing existing regulations is one of the much needed aspects ensuring water security through the regulated use. However, such regulations are not regulated to ensure that they served the intended purpose in their original formulation. In South Africa, a study was carried out to assess the relevance and efficient of adhering to procedural requirements during water use licence application (WULA) process. Lived-experiences and observation methods were used to collect data. The department of water and sanitation was used as a case study. Interpretative analysis approach was used to provide the meaning on the analysed information. The WARMS database was accessed where the number of days that WULA process was extracted. The regulation No. 40713 about WULA process was analysed. The five-year-data prior and post the promulgation of regulation No. 40713 were extracted from WARMS database and evaluated in terms of the duration each application took to be processed for WULA. Data on water use for abstractions from all the regions were obtained from WARMS database and assessed. Dates when applications were submitted and when such applications were finalised were analysis per month and per years for temporal analysis. The number of entitlements received during the particular period and the number of applications recommended to be declined and issued were assessed using exploratory data analysis methods. Graphical method was adapted to increase results visualisation on water use entitlements. Key results showed that the process of WULA was generally slow and reasons were provided for such outcome. However, the temporal analysis revealed an increasing trend in the post promulgation of regulation No. 40713 suggesting that regulations when re-regulated serve its intended purpose. Although such findings are not conclusive but they inform a basis for re-regulating enforcement regulations in Southern African countries with issues similar to South Africa on water entitlement.

Abstract

Water monitoring is a key aspect in the mining industry, in terms of gathering baseline data during the pre-construction stage, identifying potential areas of concern and mitigating source pollutants during the operational stage. A proper water monitoring program assists in the monitoring of plume development and water level rebound during the closure phase. The data made available through consistent long term monitoring should not be underestimated. Monitoring the effect that coal mine operations have on the water quality and quantity of surface and groundwater resources is a complex and multidisciplinary task. Numerous methodologies exist for monitoring of this kind. This paper will supply an overview of the water- rock chemistry associated with coal mine environments and the key indicator elements that should be focused on for water monitoring as well a review of the Best Practice Guidelines requirements in terms of water monitoring. Two case studies of coal mines in KwaZulu Natal will be reviewed, the key challenges outlined and mitigation measures implemented. The impact of requirements such as those set out by the Department of Water and Sanitation in terms of strict water quality limits for water containment and waste facilities as specified by Water Use Licences has also created unrealistic non-compliance conditions. The initial approach to creating a water monitoring programme should involve first identifying gaps in previous datasets and delineating potential sources of contamination. The sampling frequency will depend primarily on the water resource being monitored and the water quality analysis will depend on the type of facility. The facilities required for a specific situation will depend on the type and amount of waste generated, potential for leachate formation, vulnerability of groundwater resources and potential for water usage or resource sensitivity.

Abstract

This study was aimed at developing an integrated groundwater-surface water interaction (GSI) model for a selected stretch of the Modder River by considering the following five different aspects of the GSI: 1) the distribution of different aquifer systems (structural connectivity) along the river 2) the hydraulic connectivity between the aquifer systems, 3) the volumes of water abstracted from the aquifers by streamside vegetation, 4) the volumes of water replenished to the groundwater system through rainfall recharge, and 5) the exchange fluxes between the various components of the groundwater-surface water system. The distribution of the aquifer systems was investigated by means of a) geo-electrical surveys, and b) in situ slug tests while their hydraulic connectivity was investigated by hydrogeochemical routing. The volumes of water abstracted by streamside vegetation were estimated by the quantification of the transpiration from individual plants and the groundwater recharge was estimated by a root zone water balance. The water exchange fluxes between the groundwater and surface water were determined from a simple riparian zone groundwater budget. The results of the geo-electrical surveys and slug tests allowed the delineation of the riparian area aquifers (RAA) and the terrestrial area aquifers (TAA) on both the south-eastern and north-western sides of the river. Based on the results of hydrochemical analyses, saturation indices and inverse mass balance modelling, the GSI involves flow of water from the TAA to the RAA, and finally to the river on the south-eastern side while it involves flow from the river into the RAA with a limited exchange with the TAA on the south-eastern side. The dominant vegetation on the study area was found to be the Acacia karroo and Diospyros lycioides. The close similarities in isotope compositions of the xylem sap and the borehole water samples suggested that the Acacia karroo sourced its water from the groundwater storage while differences in isotope compositions suggested that the Diospyros lycioides did not source water from the groundwater storage at the time of measurement. The results of groundwater recharge estimation in the study area highlighted the fact that both the antecedent moisture and the rainfall amounts determine whether recharge to the groundwater system will take place. Finally, the results of baseflow estimation indicated that the river is a gaining stream along the south-eastern reach while acting as a losing stream along the north-western reach.

Abstract

Coastal groundwater is a vulnerable resource, estimated to sustain the water needs of about 40% of the world’s population. The Roussillon aquifer is a regional aquifer near Perpignan (southern France). It covers over 800 km2 of land and is used for irrigation, drinking water, and industrial purposes. The aquifer has experienced significant piezometric lowering in the last decades, weakening the regional resource. An important aspect of modelling the hydrodynamic of this aquifer is the need to integrate data from agriculture and drinking water abstraction, natural and anthropogenic recharge, and account for the aquifer’s complex sedimentary arrangement. An ensemble of groundwater models has been constructed to understand the spatial evolution of the saline/freshwater interface and evaluate the impact of groundwater abstraction.

Three sets of physical parameter modelling approaches were used. The first is based on the direct interpolation of pumping tests. The second uses sequential indicator simulations to represent the geological uncertainty. The third is based on a detailed conceptual geological model and multiple-point statistics to represent the detailed geological structure. These models provide parameter fields that can be input for the transient state hydrodynamic simulations. Overall, the ensemble approach allowed us to understand the Roussillon plain’s hydrological system better and quantify the uncertainty on the possible evolution of the main groundwater fluxes and water resources over the last 20 years. These models can help to inform management decisions and support sustainable water resource development in the region.

Abstract

Monitored Natural Attenuation (MNA) refers to the monitoring of naturally occurring physical, chemical and biological processes. Three lines of evidence are commonly used to evaluate if MNA is occurring, and this paper focusses on the second line of evidence: The geochemical indicators of naturally occurring degradation processes and the site-specific estimation of attenuation rates.

The MNA geochemical indicators include the microbial electron acceptors (e.g. dissolved oxygen, nitrate and sulphate) and the metabolic by-products (manganese (II), iron (II) and methane). In addition, redox and alkalinity are important groundwater indicators. So as to properly assess the geochemical trends a groundwater monitoring well network tailored to assessing and defining the contaminant plume is required.

The expressed assimilative capacity (EAC) is used to estimate the capacity of the aquifer to degrade benzene, toluene, ethylbenzene and xylene (BTEX compounds) using the concentrations of geochemical indicators. Using the EAC, the groundwater flow through a perpendicular cross-section of the source area, and the source mass, the life of the contaminant source can be made.

A practical example of the performance monitoring of MNA using geochemical parameters is described for a retail service station in KwaZulu-Natal, which has groundwater impacted by a petroleum hydrocarbon plume. This includes a description of the monitoring well network, the geochemical measurements, the calculation of the EAC, and the estimated life of the contaminant source.

Abstract

Geochemical investigations for a planned coal mine indicated that the coal discard material that would be generated through coal processing would have a significant potential to generate acid rock drainage. A power station is planned to be developed in close proximity to the coal mine, and the potential for co-disposal of coal discard with fly-ash material required examination. Fly-ash is typically highly alkaline and has the potential to neutralise the acidic coal discard material. In order to investigate whether this was a viable option, the geochemical interaction between the coal discard and fly-ash was investigated. Geochemical data, including acid-base accounting, total chemical compositions, leach test data and kinetic test data, were available for the coal discard material and the fly-ash. Using these data as inputs, a geochemical model was developed using Phreeqci to predict the pH of leachate generated by mixing different ratios of coal discard and fly-ash. The ratio of coal discard to fly-ash was established that would result in a leachate of neutral pH. Using this prediction, a kinetic humidity cell test was run by a commercial laboratory for a total of 52 weeks using the optimal modelled ratio of discard and fly-ash. Although leachate pH from the kinetic test initially reflected a greater contribution from fly-ash, the pH gradually decreased to the near-neutral range within the first 20 weeks, and then remained near-neutral for the remainder of the 52-week test. During this period, sulphate and metal concentrations also decreased to concentrations below those generated by either the fly-ash or coal discard individually. The addition of fly-ash to the coal discard material provided sufficient neutralising capacity to maintain the near-neutral pH of the co-disposal mixture until the readily available sulphide minerals were oxidized, and the oxidation rates decreased. At the end of the test, sufficient neutralising potential remained in the humidity cell to neutralise any remaining sulphide material. The results of this investigation suggested that, under optimal conditions, co-disposal of fly-ash with coal discard is a viable option that can result in reduced environmental impacts compared to what would be experienced if the two waste materials were disposed of separately.

Abstract

The Gravity Recovery and Climate Experiment (GRACE) satellites detect minute temporal variation in the earth's gravitational field at an extraordinary accuracy, in order to make estimation of the total water storage (TWS). GRACE provides a unique opportunity to study and monitor real time water variation in the hydrologic stores (snow, groundwater, surface water and soil moisture) due to increases or decreases in storage. The GRACE monthly TWS data are being used to estimate changes in groundwater storage in the Vaal River Basin for a period (2002 to 2014). The Vaal River Basin has been selected, because it is one of the most water stressed catchments in South Africa; it is well-renowned for its high concentration of industrial activities and urbanized zones. Therefore, in order to meet future water demands, it is critical to monitor and calculate changes in groundwater storages as an important aspect of water management, where such a resource is a key to economic development and social development. Previous studies in the Vaal River Basin were mostly localised focusing mainly on groundwater quality and to a lesser extent groundwater assessment. Hydrological models have been generated for the whole of South Africa, but many of these models do not take into account the groundwater component. Thus, there is a significant gap in the understanding of surface and ground water dynamics in the Vaal River Basin. The paucity of data and monitoring networks are often the limitation in calculating changes in water storage over a large area, particularly in Africa. In this scenario GRACE is a good approach to estimate changes in hydrological storages as it covers large areas and generates real time data. It does not require information on soil moisture, which is often difficult to measure. The accuracy of calculating change in groundwater storage lies in the processing of GRACE data and smoothing radii. For this study, smoothing radii of 1500, 900, 500, 300, 150 and 1 km are used. Currently the associated error with different smoothing radii is unknown. The preliminary results indicate that the study area experienced a loss in TWS of -31.58 mm equivalent water height over a period of 144 months in TWS at 300 km smoothing radius. The change in groundwater storage is calculated by incorporating hydrologic components to the TWS (work in progress). The results obtained from this study will be compared to existing hydrological models and results generated from models applicable to the semi-arid region of South Africa. It is anticipated that this satellite observation technique, GRACE, will provide an accurate estimate of change in groundwater storage. Furthermore, it will show the usefulness of satellite based techniques for improving our understanding of groundwater dynamics, which will improve water management practices.

Abstract

Globally, a growing concern have been that the heavy metal contents of soil are increasing as the result of industrial, mining, agricultural and domestic activities. While certain heavy metals are essential for plant growth as micronutrients, it may become toxic at higher concentrations. Additionally, as the toxic metals load of the soil increases, the risk of non-localized pollution due to the metals leaching into groundwater increases. The total soil metal content alone is not a good measure of risk, and thus not a very useful tool to determine potential risks to soil and water contamination. The tendency of a contaminant to seep into the groundwater is determined by its solubility and by the ratio between the concentration of the contaminant sorbed by the soil and the concentration remaining in solution. This ratio is commonly known as the soil partitioning or distribution coefficient (Kd). A higher Kd value indicate stronger attraction to the soil solids and lower susceptibility to leaching. Studies indicate that the Kd for a given constituent may vary widely depending on the nature of the soil in which the constituent occurs. The Kd of a soil represents the net effect of several soil sorption processes acting upon the contaminant under a certain set of conditions. Soil properties such as the pH, clay content, organic carbon content and the amount of Mn and Fe oxides, have an immense influence on the Kd value of a soil. Kds for Cu, Pb and V for various typical South African soil horizons were calculated from sorption graphs. In most cases there were contrasting Kd values especially when the cations, Cu and Pb, had high contamination levels, the value for V was low. There is large variation between the Kds stipulated in the Framework for the Management of Contaminated land (as drafted by the Department of Environmental Affairs) and the values obtained experimentally in this study. The results further indicate that a single Kd for an element/metal cannot be used for all soil types/horizons due to the effect of soil properties on the Kd. The results for Cu and Pb indicated that the Kds can range in the order of 10 to 10 000 L/kg for Cu and 10 to 100 000 L/kg for Pb. The variation in V Kd was not as extensive ranging from approximately 10 to 1 000 L/kg. {List only- not presented}

Abstract

Groundwater quantity and quality of shallow aquifers have deteriorated in recent years due to rapid development that has created an increased demand for drinking water, which is increasingly being fulfilled by groundwater abstraction. The study evaluates the hydrogeological framework of the Quaternary aquifer of the Kabul basin, Afghanistan, and the impact of urbanization on the groundwater resources around the Kabul city plain. Time series of Landsat satellite LCLU images indicate that the urban area increased by 40% between 2000 and 2020, while the agricultural area decreased by 32% and bare land decreased from about 67% to 52% during this period. The assumed groundwater overdraft 2019 was 301.4×103 m3 /day, while the recharge was 153.4×103 m3 /day, meaning a negative balance of about 54 million cubic meters (MCM) this year. Due to the long-term decline of water levels at 80 90 cm/year, and locally (Khairkhana, Dasht-e-Barchi) 30-50m during 2005-2019, a considerable groundwater drawdown is shown. Groundwater quality, on the other hand, reveals that chloride concentrations and salinity increased throughout the aquifer between 2005 and 2020. The nitrate concentration decreased in most Kabul Plain places over the period. In conclusion, the quantity and quality situation of urban groundwater in Kabul is worrying; urgent scientific and sustainable solutions and measures should be considered to manage this situation.

Abstract

This study focuses on the coastal agricultural area of El-Nil River (Algeria), where anthropogenic activities heavily impact groundwater resources. A multi-tracer approach, integrating hydrogeochemical and isotopic tracers (δ2HH2O, δ18OH2O, δ15NNO3 and δ18ONO3), is combined with a hydrochemical facies evolution diagram and a Bayesian isotope mixing model (MixSIAR) to assess seawater contamination and distinguish the nitrate sources and their apportionment. A total of 27 groundwater samples and 7 surface water samples distributed over the entire study area were collected. Results show classic inland intrusion combined with an upstream seawater impact through the river mouth connected to the Mediterranean Sea. Results from nitrate isotopic composition, NO3 and Cl concentrations, and the MixSIAR model show that nitrate concentrations chiefly originate from sewage and manure sources. Nitrate derived from sewage is related to wastewater discharge, whereas nitrate derived from manure is attributed to an excessive use of animal manure to fertilise agricultural areas. The outcomes of this study are expected to help decision-makers prepare suitable environmental strategies for effective and sustainable water resources management in the study area.

Abstract

Micro-electro-mechanical system (MEMs) technologies coupled with Python data analysis can provide in-situ, multiple-point monitoring of pore pressure at discrete and local scales for engineering projects. MEMs sensors are tiny, robust, inexpensive, and can provide wireless sensing measurements in many electrical and geomechanical engineering applications. We demonstrate the development of MEMs pressure sensors for pore pressure monitoring in open boreholes and grouted in piezometers. MEMs sensors with a 60 m hydraulic head range and centimetre vertical resolution were subject to stability and drawdown tests in open boreholes and in various sand and grouts (permeability 10-8 to 10-2 m/s). The resulting accuracy and precision of the MEMs sensors, with optimal calibration models, were similar to conventional pore pressure sensors. We also demonstrate a framework for estimating in-situ hydrogeological properties for analysis from vented pore pressure sensors. This framework method included Python code analysis of hourly pore pressure data at the millimetre vertical resolution, which was combined with barometric data and modelled earth tides for each borehole. Results for pore pressure analysis in confined boreholes (>50 m depth) included specific storage, horizontal hydraulic conductivity and geomechanical properties. Future improvements in the vertical resolution of MEMs pore pressure sensors and combined these two technologies will enable groundwater monitoring at multiple scales. This could include the deployment of numerous MEMs, at sub-meter discrete scale in boreholes and evaluating local site scale variations in pore pressure responses to recharge, groundwater pumping and excavations in complex sub-surface geological conditions.

Abstract

Due to technical, social, and economic limitations, integrated groundwater management presents a significant challenge in developing countries. The significance of this issue becomes even more pronounced in groundwater management, as this resource is often overlooked and undervalued by decision-makers due to its status as a “hidden resource,” despite the fact that it provides multiple ecosystem services. This study aims to establish the technical hydrogeological foundation in rural basins of central Bolivia through alternative, simplified, and cost-effective methods and tools. The study includes applying geophysical techniques, such as Electrical Resistivity Tomography, to determine the conceptual hydrogeological model of a micro-basin. In addition, a soil water balance approach was applied, characterizing 24 biophysical variables to identify groundwater recharge zones, while global circulation models provided a substitute for unreliable meteorological data. Furthermore, a participatory model was developed to identify recharge areas in upper basin areas within the framework of developing a municipal policy for their protection. The participatory model included local knowledge in all stages of methodology development, considering the characteristics of the local plant communities and the spatial distribution of local rainfall. The research findings have already contributed to resolving socio-environmental conflicts in Bolivia and establishing a foundation for effective water governance by empowering local rural communities. This study has demonstrated the feasibility of using alternative, simplified, and low-cost methods and tools to establish the technical hydrogeological basis, which can inform public policies to promote sustainable groundwater management in developing countries.