ion of multivariate statistical analysis as a support for the delineation of groundwater bodies: a case study in coastal plain areas of Campania Region (Southern Italy)

The identification of hydrogeological boundaries and the assessment of groundwater’s quantitative and qualitative status are necessary for delineating groundwater bodies, according to the European Guidelines. In this context, this study tries to verify the current delineation of groundwater bodies (GWBs) through hydrogeochemical methods and multicriteria statistical analyses. The areas of interest are three GWBs located in the northern part of Campania Region (Southern Italy): the Volturno Plain, a coastal plain constituted of fluvial, pyroclastic and marine sediments; the Plain of Naples, an innermost plain of fluvial and pyroclastic sediments and the Phlegrean Fields, an active volcanic area with a series of monogenic volcanic edifices. Hydrogeochemical methods (i.e., classical and modified Piper Diagram) and multivariate statistical analyses (i.e., factor analysis, FA) were performed to differentiate among the main hydrochemical processes occurring in the area. FA allowed the handling many geochemical and physical parameters measured in groundwater samples collected at about 200 sampling points in the decade of the 2010s. Results reveal five hydrogeochemical processes variably influencing the chemical characteristics of the three GWBs: salinization, carbonate rocks dissolution, natural or anthropogenic inputs, redox conditions, and volcanic product contribution. Hydrogeochemical methods and FA allow the identification of areas characterised by one or more hydrogeochemical processes, mostly reflecting known processes and highlighting the influence of groundwater flow paths on water chemistry. According to the current delineation of the three GWBs, some processes are peculiar to one GWB, but others are in common between two or more GWBs.