The National Environmental Management Waste Act, 59 of 2008 (NEMWA) clearly identifies the status and risk of contaminated sites and provides a legislative mechanism for remediation activities to be implemented and controlled. The Draft National Framework for the Management of Contaminated Land (henceforth Framework) provides national norms and standards for the practical implementation of remediation activities in compliance with NEMWA. A soil-screening value (SSV) for the protection of water resources is based on a two-phase equilibrium partitioning and dilution model which includes a dilution factor (DF) and partitioning coefficient (Kd) which converts the water quality guideline to a total soil-screening value. This paper presents a methodology to use soil-specific Kd values to improve the accuracy of the new South African guideline for contaminated land.
Appropriate Phase 1 screening assessments are important due to the potential consequence it holds. Some uncertainty exists in the Phase 1 screening values due to variability in Kd values for different soil. This study shows that the Kd values selected for the Framework is not representative of typical South African soils. Cu Kd values exceed the value provided by the Framework in all soils, but are lower that the Framework V Kd value in all soils. For Pb, low clay content weathered soils have lower Kd, but higher clay content soils are up to four orders of magnitude higher that the Kd in the Framework. Furthermore, due to the large variability (three to four orders of magnitude for Cu and Pb) point estimates of a single Kd value cannot be used for all soil types. However, for V only one order of magnitude variation is found.
A way of addressing the uncertainty would be to determine the water soluble portion during the assessment. This would dramatically increase the certainty with which screening is conducted and could prevent significant inappropriate screening. Additional cost incurred be offset by saving as a result of unnecessary Phase 2 assessments or the reduction of undetected risks that later could impact the environment.
Phase 1 screening could also be improved by including soil classification and some basic soil properties in the site assessment and adjusting Kd values, accordingly. Soil properties that can be used are typically clay content, pH and organic matter content. From these properties more appropriate Kds can be estimated for use in setting screening values.