The long mining history in Namibia has resulted in numerous abandoned mines scattered throughout the country. Past research around the Klein Aub abandoned Copper mine highlighted environmental concerns related to past mining. Considering that residents of Klein Aub depend solely on groundwater, there is a need to thoroughly investigate groundwater quality in the area to ascertain the extent of the contamination. This study made considerable effort to characterise groundwater quality using a comprehensive approach of quality assessment and geostatistical analysis. Onsite parameters reveal that pH ranges between 6.82-7.8, electrical conductivity ranges between 678 - 2270 μS/cm, and dissolved oxygen ranges between 1.4 -5.77 mg/L. With an exemption of two samples, the onsite parameters indicate that water is of excellent quality according to the Namibian guidelines. The stable isotopic composition ranges from −7.26 to -5.82‰ and −45.1 to -35.9‰ for δ18O and δ2H, respectively—the groundwater plots on and above the Global Meteoric Water Line, implying no evaporation effect. Hydrochemical analyses show bicarbonate and chloride as dominant anions, while calcium and sodium are dominant cations, indicating groundwater dissolving halite and mixing with water from a recharge zone.
The heavy metal pollution index of the groundwater is far below the threshold value of 100, which signals pollution; it contrasts the heavy metal evaluation index, which clustered around 3, implying that the heavy metals moderately affected groundwater. Copper, lead and Arsenic were the main contributors to the values of the indices.