Anticipated Shale Gas Development could intensify possible natural hydraulic connectivity between deep groundwater reservoirs and shallow aquifers in the Karoo. This project attempts to test geochemical evidence of natural mixing between old groundwater from deep aquifers and young groundwater from shallow aquifers using selected isotopic signatures in conjunction with borehole yields. Borehole yields were determined using slug tests. All isotopes (δ18O, δ2H, δ13C, 3H and 14C) were analysed in the laboratory of Environmental Isotope Group of iThemba Laboratories in Gauteng.

The Table Mountain Group is a major fractured rock aquifer system throughout the Western Cape, with many interconnected but semi-independent parts, each having its own recharge area, flow paths and discharge area. Groundwater is known to travel long distances and reach great depths, including through the Olifants River syncline, such as at The Baths hot spring near Citrusdal. Stable isotope compositions of rain and groundwater in the Cederberg and Olifants River Mountains were measured over a period of 2-3 years.

Limpopo Province is one of the wealthiest areas of South Africa with respect to geothermal spring occurrences, which were classified according to the residing mountains: Soutpansberg, Waterberg and Drakensberg. Mphephu, Sagole, Siloam and Tshipise geothermal springs fall within the Soutpansberg. This study is aimed at understanding the origin and age, geochemical processes controlling the water chemistry. Analyses of major ion hydrochemistry and environmental isotopes (?18O, ?2H and ?3H) were undertaken, which is supported by conventional hydrogeological information.

Industrial areas are major sources of surface and groundwater pollution. As a result, constant monitoring of water quality is of vital importance to detect pollution incidences in time and to take corrective actions. This integrated hydrogeological, hydrochemical and environmental isotopes (?2H, ?18O, 3H) study has been undertaken to investigate the hydrogeological conditions around the Kusile coal-fired power station located in the quaternary catchment B20F. The study area is characterized by mainly weathered and fractured and fractured aquifer systems.

Modie LT; Stephens M