This paper presents data obtained from sampling and geochemical analysis of gold tailings and associated pool and drain water. Inverse geochemical modelling using PHREEQC indicated geochemical processes operating in the tailings between the pool and drains. These included pyrite oxidation and dissolution of various minerals identified in the tailings. The processes were incorporated into an ensemble geochemical model to calculate post-closure sulphate concentration in tailings seepage.
The ensemble model included a spreadsheet model to calculate oxygen flux at various depths in the tailings column, and a one-dimensional transport model in PHREEQC. The calculated oxygen flux was applied to each cell in the tailings column to determine the amount of sulphide oxidation and the release of acidity into the tailings pore water. The rate of vertical transport of pore water in the column was determined from physical characterisation of the tailings particle size and saturated hydraulic conductivity.
The model results indicate elevated sulphate concentrations and acidity moving as a front from the top of the column downwards. The modelled sulphate concentration of 1 500 to 1 900 mg/L 8-16 years after closure compared well with measurements of drain water quality at a tailings dam decommissioned approximately 16 years ago. This provided some credibility to the modelled result of 2 300 mg/L sulphate up to 50 years post-closure. However, the tailings moisture content, infiltration rate, and pyrite oxidation rate in the model were based on literature values, rather than site-specific measurements.