Geochemical Behaviour Of Arsenic In Contact With Dolomite

Arsenic is a common contaminant typically found in effluent from gold mine operations and copper smelters throughout the world. The geochemical behaviour of arsenic in contact with dolomite underlying an arsenic containing waste rock pile was investigated. The interaction between the arsenic and the dolomite is an important control in the subsequent transport of the arsenic in the dolomitic aquifer. Rocks with varying dolomite content were tested to investigate the interaction between the arsenic and dolomite. From the modelling and test results it was estimated that in the aquifer, between 60 - 90% of arsenic is present in the solid phase under oxidation conditions at >50 mV. At 50 to -25 mV about 40 - 60% of the arsenic is estimated to be present in the solid phase and below -25 mV about 0 - 10% of arsenic will be present in the solid phase. Although some arsenic is removed by the dolomite in the aquifer the arsenic would still be present above acceptable guidelines for drinking water. The arsenic in the solid phase will be in equilibrium with the aquifer water and could be remobilised 1) under more reducing conditions or 2) with a decrease in arsenic in the aquifer.