Conference Abstracts

All Abstracts were presented at the Groundwater Conferences

Displaying 101 - 150 of 795 results
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Abstract

The mineral-rich basin of the West African region has vast reserves of gold, diamond as well as iron ore deposits. Throughout the regional geological setting characterised by structural variations and intrusive belts with metamorphic mineral-rich sequences covered by saprolite soils, one common chemical constituent remains a constant in the water reserves. Arsenic is in high concentrations throughout the region with chemical ranges commonly above the various country guidelines as well as international IFC and WHO standards. The aqueous chemical species is associated with arsenopyrite-rich mineralogy of the regional greenstone belts and highly weathered soils.

This conference presentation investigates the natural source of the arsenic through baseline data, as well as the effect of mining on the already high concentrations of arsenic in both the groundwater and surface water. Natural levels of various chemical species in the regional area are already high at baseline level. One of the main research questions is thus whether mining and other anthropogenic activities will have  an impact on the environment or will  the changes to concentrations be so insignificant to allow the ecosystems and water users to continue in their current ways without any effect. Various case studies in Burkina Faso, Liberia, Sierra Leone and other countries have been combined to investigate the arsenic-rich resources of the West African region through groundwater specialist investigative methods with emphasis on geochemical modelling of the fluid–rock and fluid–fluid interactions leading to the aqueous chemical conditions in the region.

Abstract

Artesian boreholes are a common feature worldwide in confined aquifers. However, the hydraulic testing of these boreholes and estimation of aquifer properties from such tests still pose a challenge for hydrogeologists. Common hydraulic tests, such as step-drawdown or constant discharge rate tests  require  a  static water  level  at the  start  of  the  test,  and  the measurement of  drawdown (increasing over time) and abstraction rate (fixed for a period of time). Usually, when undertaking a pumping test in an artesian borehole, the drawdown is measured from ground level, and the drop in hydraulic head between static pressure and ground level is often ignored. This also implies that the starting time of the test is not at the static water level. A constant head test, set at ground level, is the other option. However, the decrease in flow rate is not only dependent on the hydraulic properties of the aquifer, but also masked by pipe hydraulic effects within the well. This kind of test would also limit the available drawdown to be utilised for the test. 

Hence,  it was  required  to  develop a method for undertaking hydraulic tests in  strong artesian boreholes allowing for the drawdown to fluctuate between above and below ground and avoiding the pitfalls described above. The solution is a specially designed and constructed well-head for the installation of the pump and monitoring equipment prior to the hydraulic test. The standard tests are slightly modified and will only be carried out after sealing the well-head and reaching static hydraulic pressure. 

The recommended well-head construction and subsequent hydraulic tests were carried out at a strong artesian borehole in the Blossoms Well-field, south of Oudtshoorn in the Western Cape of South Africa.

Abstract

The thermal springs of Swaziland and adjacent KwaZulu-Natal have, over the years, attracted attention from hydrogeologists, hydrochemists and structural geologists. While some of the springs in Swaziland are well known amenities, others are less well-visited and some difficult to access. There are eleven warm springs in Swaziland, discharging between 1 and 10 l/s from Precambrian age rocks; all are situated at or near valley bottoms. The springs have surface discharge temperatures of between 25 and 52 oC and total dissolved solids concentrations of less than 400 mg/l. In all cases the water is meteoric in origin. Geothermometry indicates that maximum temperatures up to 100 oC are achieved during circulation. If the average geothermal gradient is about 20 oC/km as recorded in a deep mine at Barberton, then this would require circulation up to a depth of several kilometres. However, it is likely that circulation bottoms at about 1 km, as pressure of overburden inhibits dilation of fractures at such depths, and the excess temperature may derive from a locally enhanced geothermal gradient. The discharge water is young, with 14C ages of between 4 000 and 5 000 years.

Abstract

The effluent at the eMalahleni water reclamation plant is being processed through reverse osmosis which improves the quality of the mine water to potable standards. Brine ponds are generally used for inland brine disposal and this option has been selected for the eMalahleni plant. Limited capacity to store the brines requires enhanced evaporation rates and increased efficiency of the ponds. This study aims to establish the physical behaviour of the brine from the eMalahleni plant in an artificial evaporation environment. This includes the actual brine and synthetic salts based on the major components.

An experimental unit was designed to accommodate and manipulate the parameters that affect the evaporation rate of brines and distilled water under certain scenarios. Two containers, the one filled with 0.5M of NaCl and the other with distilled water were subjected to the same environmental conditions in each experimental cycle. Each container had an area of a 0.25 m² and was fitted with identical sensors and datalogger to record the parameter changes. The energy input was provided by infra-red lights and wind-aided electrical fans. This equipment used in these experiments was to simulate actual physical environmental conditions. 

The rate of evaporation was expected to be a function of humidity, wind, radiation, salinity and temperature. The experiments showed the type of salt and thermo-stratification of the pond to be significant contributors to the evaporation rate. The results also showed that the NaCl solution absorbed more heat than the water system. The difference in evaporation observed was ascribed to a difference in the heat transfer rate, which resulted in a higher temperature overall in the brine container than in the water container under similar applied conditions. This effect remained despite the introduction of 2 m/s wind flow over the tanks as an additional parameter. The wind factor seemed to delay evaporation due to its chilling effect upon the upper layers of the ponds, initially hindering the effective transfer of radiative heat into the ponds.

 

Abstract

In recent years there is an increased awareness of hydrocarbon contamination in South Africa, and the need for remediating sites affected by these contaminants. Hydrocarbon contamination of groundwater can be caused by a large variety of activities at industrial, mining or residential areas. Once these contaminants are discovered in groundwater where it poses risks to human health and/or the environment, remediation is often required. Remediation of groundwater has become a booming industry for groundwater practitioners and often there is an attitude of more sophisticated and expensive solutions are better. This paper will show that this attitude is not always the best solution, but rather recommend an approach where a combination of low cost/low maintenance system need to be investigated and applied to reach clean-up goals. Determination of natural attenuation potential and on-going monitoring forms an integral part of this type of solution.

Abstract

POSTER Water is an invaluable resource without which life would cease to exist. Supply in South Africa has become limited due to increases in demand brought upon by population growth, urbanisation and industrialisation. In Southern Africa, water systems are considerably degraded by mining, industry, urbanisation and agricultural activity and a large amount of the fresh surface water has already been utilised. The stresses on this resource will unlikely make the current usage sustainable in years to come. In order to provide for basic needs for the future, groundwater as a resource will have to play a major role. It is for this reason that groundwater integrity needs to be preserved. 

Hydrocarbon contamination is a huge threat to groundwater as it contains toxic substances that are insoluble in water. These toxins are carcinogenic and mutagenic, and have a major impact on human health and ecosystem stability. When spilled, hydrocarbons will move downward through the unsaturated zone under the influence of gravity and capillary forces, trapping small amounts in the pore spaces. Accumulation will result in added weight along the water table, forcing the entire surface to be displaced downward. Some of the components can dissolve in the groundwater and move as a plume of contaminated water by diffusion and advection within the saturated zone. The transport of contaminants from petroleum hydrocarbon spills needs to be described in terms of a multiphase flow system in the unsaturated zone, taking into account contaminant movement in each of the three phases: air, water and free light non-aqueous phase liquid. Petroleum hydrocarbon behaviour in the subsurface is additionally complicated by the presence of multiple compounds, each with different properties. The net result is that some hydrocarbon fractions are transported faster than others and a contamination plume of varying intensity may spread over a large area.

The aim of this study is to develop a methodology to map and simulate the movement of groundwater that has been contaminated by hydrocarbons and to determine the fate of the water quality through decomposition. Associated remediation options will be determined thereafter.

Abstract

The assessment and prediction of mine water rebound has become increasingly important for the gold mining industry in the Witwatersrand basin, South Africa. The cessation of dewatering lead to large volumes of contaminated surface discharges in the western parts of the basin. Towards the eastern extremity of the Witwatersrand basin the detached Evander Goldfield basin has been mined since the early 1950s at depths between 400 and 2000 metres below ground, while overlain by shallower coal mining operations. The hydrogeology of the Evander basin can be categorised by a shallow weathered-fractured rock aquifer comprising of the glacial and deltaic sediments of the Karoo Supergroup, while the deeper historically confined fractured bedrock aquifer consist predominantly of quartzite with subordinate lava, shale and conglomerate of the Witwatersrand Supergroup. The deep Witwatersrand aquifer has been actively been dewatered for the last 60 years with a peak rate of 60 Ml per day in the mid late 1960s. Modelling the impacts of mine dewatering and flooding on a regional scale as for the Evander basin entails challenges like the appropriate discretisation of mine voids and the accurate modelling of layered aquifer systems with different free groundwater surfaces on a regional scale. To predict the environmental impacts of both the historic and future deep mining operations, the detailed conceptual model of the aquifers systems and a 3-dimensional model of the mine voids were incorporated into a numerical groundwater model to simulate the dewatering and post-closure rebound of the water tables for the basin. The presented model could serve as an example for the successful modelling of mine dewatering and flooding scenarios for other parts of the Witwatersrand basin.

Abstract

The Palla Road well-field is located in the Central District of Botswana approximately 160 km from Gaborone and 50 km from Mahalapye. The aim of this project was to review and update the existing groundwater model developed in the late 1990s of the Palla Road well-field in order to assess the viability of long-term groundwater abstraction due to the increasing water demands in the region. The  main  hydrogeological  units  recognised  in  the  project  area  comprise  of  aquifer  systems developed in the Ntane Sandstone Formation and formations of the Middle Ecca Group with minor aquifers developed in Mosolotsane Formation and the Stormberg Basalt. The finite-difference model boundary covers an area of 3 702 km2  and was set-up as a three-dimensional semi-uniform grid comprising of four layers. Eight recharge and 14 hydraulic conductivity zones in accordance with the geological  model  were  distinguished.  Steady  state calibration  was  accomplished  by  varying the hydraulic conductivity values, while keeping the recharge rates constant in order to achieve a unique solution. Transient calibration of the model covered three larger stress periods namely: (1) initial condition (pre-1988), (2) abstraction period (1988 to 2012) and  (3) predicted model simulations (2013 to 2036).

The calibrated groundwater flow model was used to assess the impacts associated with  the  proposed  abstraction  scenarios  for  the  Palla  Road  and  Chepete  well-fields  with consideration  of  potential  cumulative  impacts  due  to  the  Kudumatse  well-field.  Three  basic scenarios comprising certain sub-scenarios based on the future water demand for the Palla Road and Kudumatse region were considered. The model simulations show that the abstraction scenario 2a, namely simultaneous abstractions from the Chepete/Palla Road and Kudumatse well-fields, poses a risk to the sustainability of downstream water resources. The maximum simulated drawdown in the central and  southern parts of the Palla Road well-field  reach 14 m after six years of  pumping. Although outflow diminishes after a six-year period, it is restored to approximately 80-90% after the simulated recovery period. The presented 3-D multi-layer model can be used as a tool to determine the optimal abstraction rates while giving cognisance to the sustainability of the resource.

Abstract

The so-called apparent increase of transmisivity (T) or hydraulic conductivity (K) with scale is an artifact and does not exist in the field. The reason for the apparent increase of T with scale is due to the use of the “not applicable” random log Gaussian stochastic models that are used by geohydrologists. In the petroleum field, where deterministic methods are applied, the apparent increase of T with aquifer volume does not occur. Groundwater practitioners have to change their view and use models that do not show this effect.

Abstract

The article presents the application of a water balance model as a preliminary tool for investigating groundwater–surface water (GW–SW) interactions along an alluvial channel aquifer located in a semi-arid climate in the central province of South Africa. The model is developed based on the conservation of mass; solute and stable isotopic mixing of the model components. Discharge measurements were made for the river segment inflow and outflow components using stream velocity-area technique. The Darcy equation was used to calculate the groundwater discharge from the alluvial channel aquifer into the river segment. Electrical conductivity (EC) and δ2H isotope were measured for the inflow and outflow components of the model as indicators of solute and stable isotopic ratios. Measurements were conducted during a low river flow once-off period in October 2011, thus offering a great opportunity to assess GW–SW exchanges when other potential contributors can be regarded as negligible. The model net balance shows that the river interval is effectively losing water. The mass and solute balance approach provided close to a unique solution of the rate of water loss from the model. The model outcome provides a platform from which to develop appropriate plans for detailed field GW–SW interaction investigations to identify the mechanism through which the river is losing water.

 

Abstract

Data acquisition and Management (DAM) is a group of activities relating to the planning, development, implementation and administration of systems for the acquisition, storage, security, retrieval, dissemination, archiving and disposal of data. Data is the life blood of an organization and the Department of Water and Sanitation (DWS) is mandated by the National Water Act (No 36 of 1998) as well as the Water Services Act (No 108 of 1997), to provide useful water related information to decision makers in a timely and efficient manner. In 2009 the DWS National Water Monitoring Committee (NWMC) established the DAM as its subcommittee. The purpose was to ensure coordination and collaboration in the acquisition and management of water related data in support of water monitoring programs. The DAM subcommittee has relatively been inactive over the years and this has led to many unresolved data issues. The data extracted from the DWS Data Acquisition and Management Systems (DAMS) is usually not stored in the same formats. As a result, most of the data is fragmented, disintegrated and not easily accessible, making it inefficient for water managers to use the data to make water related decisions. The lack of standardization of data collection, storage, archiving and dissemination methods as well as insufficient collaboration with external institutions in terms of data sharing, negatively affects the management water resources. Therefore, there is an urgent need to establish and implement a DAM Strategy for the DWS and water sector, in order to maintain and improve data quality, accuracy, availability, accessibility and security. The proposed DAM Strategy is composed of the six main implementation phases, viz. (1) Identification of stakeholders and role players as well as their roles and responsibilities in the DWS DAM. (2) Definition of the role of DAM in the data and information management value chain for the DWS. (3) Development of a strategy for communication of data needs and issues. (4) Development of a DAM life Cycle (DAMLC). (5) Review of existing DAMS in the DWS. (6) Review of current data quality standards. The proposed DAM Strategy is currently being implemented on the DWS Groundwater DAM. The purpose of this paper is to share the interesting results obtained thus far, and to seek feedback from the water sector community.

Abstract

A multi seam open pit coal mine is planned to be developed in the Moatize Basin of Mozambique. The proposed project includes a new coal mine and coal handling facility to produce up to six million tons per annum of coking and thermal coal for the export market, which will have a life of mine of approximately 30 years. The mine will require 65 l/s for the first five years to supplement their process water make-up. Geo Pollution Technologies Ltd was appointed to investigate the feasibility of supplying groundwater to the mine. Due to the complexity of the Revuboe River during flooding and other difficulties abstracting water directly from the river, abstraction of groundwater from the alluvial aquifer next to the Revuboe River was selected as bulk water supply to the mine as it proved to be a sustainable source of water at other mining operations in the area. The benefits of the alluvial aquifer is the potential volume of water in storage and the zero losses to evaporation and seepage.

Taking into consideration the information gathered from previous groundwater and geophysical studies done in the area, a number of boreholes were sited based on geophysical results, alluvial material thickness and the energy of the river. Four of the six initial borehole positions had to be changed due to unforeseen access restrictions and concerns from the community. After the borehole positions were cleared and finalised, six boreholes were drilled up to a depth of roughly two meters below the bottom of the alluvial aquifer, which is on average 20 meters thick. The boreholes were logged in terms of geology and hydrogeology and cased to allow maximum water inflow from the aquifer. Due to one of the six boreholes being dry, five of the boreholes were subjected to 24 hour pump testing. The discharge rates varied between 4 and 20 l/s. The pump test results were interpreted using the Flow Characteristic method and final yields of between 5 and 30 l/s were achieved. The bulk water supply target of 65 l/s were exceeded by 9 l/s, with a final supply from the five holes combined of 74 l/s sustainably for the next five years.

Abstract

The Cedarville Flats aquifer located in the Upper Umzimvubu River Basin, Eastern Cape Province is a source of water supply for an important agricultural region in South Africa. The hydrogeology of this important aquifer is investigated to understand the occurrence, circulation, recharge and quality of groundwater. To this end, local and regional geology, borehole lithological logs, borehole yields, aquifer hydraulic characteristics (including aquifer thickness, water level, hydraulic conductivity, transmissivity and storage coefficient), hydrometeorological, hydrochemicaland environmental isotope data were collected and interpreted. The results show that the alluvial aquifer is made up of sand, gravel, boulders and clay and its thickness reaches 51 meters in places. Median hydraulic properties indicate that the Cedarville Flats primary aquifer is the most productive aquifer compared to the underlying Molteno and Burgersdorp Formations. It has an estimated median borehole yield in the order of 6 l/s as compared to 2 l/s for the Burgersdorp and 1.5 liters for the Molteno Formations. The aquifers in the area receive an estimated 7% of rainfall recharge. The groundwaters of the area are characterized by low ionic concentration with EC and TDS ranging from 235 to 285 ?S/cm and from 65 to 151 mg/l, respectively. The hydrochemical data further indicate a groundwater hydrochemical facies of either Ca-Na-Mg-HCO3 or Na-Ca-Mg-HCO3 highlighting a typically less evolved recharge area groundwater having short residence time and hence less water-rock interaction. Springs and artesian wells show a relatively depleted stable isotope and very low to dead tritium signals indicating high altitude recharge and longer circulation path and residence times compared to wells tapping the water table aquifer which indicate young water with recharge coming from the immediate surrounding area. Similarity in hydrochemical and stable isotope signatures between the streams that drain across the alluvial flats and the shallow groundwaters mean that there is a close interconnection between surface water and groundwater in the area.

Abstract

The manner in which municipal and industrial wastes generated are disposed in the urban areas in Nigeria is worrisome. The practice of dumping solid wastes in abandoned burrow-pits or valley and the discharge of liquid wastes directly on soils or surface water without any form of treatment has resulted in soil and water pollution. The continuous release of dangerous gases into the atmosphere by industries unabated has contributed to air pollution. These inadequate waste disposal techniques have created serious environmental and health challenges. Due to increasing population growth rate, urbanization, industrialization and economic growth, there has been a phenomenal increase in the volume of wastes generated daily and handling of these wastes have constituted an environmental problem. The need to manage these wastes in an environmentally-friendly manner that will guarantee safety of the soil and water resources lead to the present study. The newly designed waste management landfill incorporates advanced features such as complex multiple liner construction to facilitate organic decomposition and maintain structural integrity. The multiple protective layers and regular monitoring ensure that the waste management landfills exist in harmony with their surrounding environments and communities. These features that enhances maximum protection of soil and water from contamination by plume by decaying waste is lacking in the un-lined open waste dumps been practiced in the country. Pollution abatement, waste reduction, energy saving, health and economic benefits are some of the advantages of the newly designed sanitary landfill system.

Abstract

Characterization of Groundwater Potential in the northern parts of the Limpopo Province, South Africa: Results from Integrated Geophysical Studies across the Sagole and Tshipise Hot Springs.
The Sagole and Tshipise hot springs are located in the northern Limpopo Province of South Africa. The geology of the area consists of dykes, dolerite sills, quartzite and undifferentiated meta-sediments. Regional-scale airborne magnetic data and satellite images were used for mapping structures and lithological boundaries in order to identify permeable zones that are associated with thermal groundwater aquifers. Various filtering techniques were used to enhance the magnetic signatures that correspond to structural features. Modeling of airborne magnetic data indicated that the heat source depth was an anticlinal structure at a depth range of 3 km to 5 km. Based on results of interpretation of the magnetic and satellite images, ground follow-up targets were identified. Detailed ground geophysical surveys were carried out across the identified targets using the frequency-domain electromagnetic (EM), electrical resistivity tomography (ERT) and magnetic methods.
{List only- not presented}

The result of interpretation of magnetic data was combined with two-dimensional modeling EM and (ERT). Modeling of the electrical conductivity of the subsurface layers was constrained using existing borehole data. Interpretation of the airborne magnetic data revealed the presence of number of NE-SW striking lineaments that transect the metasedimentary rocks of the Soutpansberg Supergroup. In addition, these structures are manifested by a number of hotsprings that are aligned along major lineaments. The interpretation of 2D modeling of ERT data revealed a highly conductive layer with a depth ranging from surface to 40 m that may be attributed to elevated moisture content. Two-Dimensional modeling of frequency-domain electromagnetic data was carried out to delineate lateral and vertical variation of electrical conductivity. Electrical conductivity values in the range 50 mS/m to 100 mS/m were obtained, indicating the presence of water bearing zones or fractures. Results of the study have shown that hot water rises to the surface along near vertical faults or fractures.

Keywords: Aquifer, geophysics, groundwater, thermal spring

Abstract

Static indicator tests, such as acid-base accounting, are commonly used to provide an indication of ARD potential of backfill material in opencast coal mines. This potential for acidity is then commonly incorporated into numerical models, wrongfully, as a constant contamination source with the maximum possible sulphate being released from the pit, ad infinitum, which is, obviously, not the case. Dynamic tests on the other hand, are considered superior, but are expensive and time consuming. The proposed alternative approach is geochemical modelling, illustrated by a case study in the Mpumalanga coal fields. A decommissioned colliery near Carolina, Mpumalanga, was recently confronted with the prediction of the impacts that its backfilled opencasts might have on groundwater in the long term with regards to acid and contaminant generation, demanding a more realistic and well-defined conceptual and numerical approach than the simple minimum screening method. This study utilised the integration of a well-defined conceptual model, mineralogical data, acid-base accounting data, leaching test data, literature and groundwater monitoring data to address the long term hydrogeochemical evolution of groundwater at the colliery, using transiently calibrated geochemical and numerical flow models. Using the mineralogical data available from samples collected, as well as the sulphur content identified by ABA, a standard error was calculated for the abundances of all mineral phases present along with mean weight percentages, defining the likely boundaries of mineral abundances. Using these values along with reactive surface areas calculated from average grain sizes, using a collapsing core model, as well as rate constants from literature, the fluid rock interaction in the leaching tests was simulated and calibrated against leaching test results in the geochemical model, by varying mineral abundances, reactive surface areas and rate constants within the statistically acceptable boundaries. Once a calibrated mineral assemblage was identified using this method, the assemblage was geochemically modelled in the natural environment, after calculation of fluid to rock ratios, which in this case was purely potential backfill porosity vs. recharge due to the natural groundwater level being below the pit base, as well as potential oxygen fugacity. The calculated concentrations of constituents were then introduced into a transiently calibrated numerical flow and transport model via recharge concentrations, to also chemically calibrate this model. The chemical calibration was successful within a 20 mg/L range, illustrating the reliability of the conceptual and geochemical models, but also the reliability of predicted numerical modelling results. Based on the available data and modelling results, the colliery would not have a future impact on groundwater with regards to ARD and metals. However, elevated major cation and anion concentrations are expected, calculated within order of magnitude accuracy, and can be managed according to dynamic and realistic models, instead of a static worst case scenario.

Abstract

In order to meet the increasing national and international demand for coal, substantial expansion plans for existing as well as new coal mines were put forward in recent years. The mine developments are often proposed in environmentally sensitive areas and require an appropriate assessment of potential environmental impacts, including impacts on groundwater dependent ecosystems. This paper describes the development of a conceptual and numerical groundwater model as part of a wetland reserve determination in the Witbank coalfields. The model was used to assess potential mining related impacts on the shallow groundwater flow, including surface seepages and spring discharges feeding hill slope and valley bottom wetlands as well as pans. A number of shallow monitoring boreholes were sited, drilled and tested in the focus area around a pan to characterise the shallow perched and weathered aquifers. While these aquifers were generally found to be very low to low yielding, higher yields were encountered in a coarser grit layer intersected by two of the eight boreholes. The grit layer represents a potential preferential groundwater flow path towards the pan and was subsequently further delineated based on the exploration drilling logs from the mine. The different aquifers, the target coal seam, and over 60 mapped hill slope and valley bottom wetlands as well as pans, were incorporated into a numerical groundwater flow model. A free seepage boundary was assigned to the entire surface area to evaluate if the model is able to represent the observed seepages and spring discharges. The simulation of unsaturated flow processes (Richard's equation) was found to be crucial for the representation of discharges from perched aquifers. Following a satisfactory calibration of the model, different open cast mine layouts were then incorporated into the model to assess their impacts on the groundwater contribution to wetlands. The presented quantitative simulation of groundwater contributions towards wetlands and pans based on site specific groundwater investigations and data is considered a best practice example in assessing the groundwater component for a wetland reserve determination.

Abstract

The management of groundwater inflows into an opencast colliery in Mpumalanga is normally fairly easily achievable due to low inflow volumes and high evaporation rates. But, when flooded underground mine workings are encountered, groundwater inflow complexity increases dramatically. Understanding, predicting and managing groundwater inflow under these conditions can be challenging and highly complex. While normal opencast inflows are easily modelled these connected mines are pushing numerical models to their limits. This case study aims to illustrate an approach based on a finite difference model that has been used successfully in a South African coal mine. Based on a study at a colliery near Ermelo, Mpumalanga, the understanding and conceptualisation of the aquifer geometry, geological structures, hydrogeology, defunct underground mine geometry and interconnection between opencasts and the underground, proved to be vital, not only in calibration of the model, but also in the construction of the various layers and calculation of flow volumes between the various sources and sinks. This also aided greatly in constant source contaminant transport modelling to trace which mining areas may have a contamination effect on each other or the surrounding aquifer. In constructing the numerical flow model, the underground mine geometry was found to intersect various layers in the MODFLOW based model and pinching out in some areas. Due to the requirement of MODFLOW that layers should be continuous with no pinchouts to the model boundaries, this presented a notable challenge in the model construction. Therefore, mine geometry was divided into various slices, fitting within the hydrogeological layers, but still retaining the original geometry. The layers were then further divided laterally using different materials to represent the mine hydraulic properties and aquifer properties respectively, ensuring that the lateral distribution of materials also represents the underground mine geometry accurately. Using this model construction, the calculated mean residual head for the simulation of the current situation was found to be less than 3m while the simulation of the current mining situation with no underground mine present, yielded a mean residual head of approximately 10m. Additionally, inflows measured in the opencast penetrating the underground were measured at approximately 1000m3/d while the calibrated model calculated inflows of 1160m3/d, while simulating the current mining situation including the defunct underground. The current decant from the defunct underground, to the southeast of the site, was calculated as 1.9 L/s by the model while the measured rate was just over 1 L/s. Also, as expected, the dewatering of the opencast penetrating the flooded, defunct underground mine, was calculated to predominantly impact an underground mine compartment, isolated by underground seals, as opposed to the aquifer, which has a much lower hydraulic conductivity. {List only- not presented}

Abstract

Slightly more out of the box idea is the use of anthropogenic aquifers as storage and chemical conditioners.  This concept was first introduce by Eland Platinum Mine(EPM) and reported on in previous papers.  At EPM water is used through a serious of natural aeration and aerobic storage facilities to reduce nitrate levels.  In 2013 another group introduced pilot studies by virtue of abstraction in support of the water conservation and demand management strategy; which has proven that it could enable the operations to overcome water shortage periods and reduce pressure on Rand Water (RW). The pilot sites would deliver water into the dirty water circuit, but within five to ten years it may further be used to overcome months with zero potable water supply. .  In platinum mines the more the aquifers are used the cleaner the water becomes, simply because introduced pollutants are not constant sources and country rock is mostly inert.  In the future these aquifers have the potential to become larger storage facilities protected from floods and limited evaporation losses. It is foreseen that some of the mines in the western belt may have more water stored in primary aquifers than water stored within major water dams. Yields from these aquifers for individual aquifers may be up to 450 m3/hour and storage of 18 Mm3.  . Why then this paper if we are already using it?  The issue is that the true value of these aquifers an only be unlocked when they are  used as recharging aquifers and thereby actively storing dirty water within a dirty water aquifer.  Once we are able to undertake this the positive environmental gains such of environmental overflows, condition dirty water, reduction of pollution and significant reduction of the use of potable water from RW. {List only- not presented}

Abstract

The International Association of Hydrogeologists and UNESCO's International Hydrological Programme have established the Internationally Shared (transboundary) Aquifer Resource Management (ISARM) Programme. This multiagency cooperative program has launched a number of global and regional initiatives designed to delineate and analyze transboundary aquifer systems and to encourage riparian states to work cooperatively toward mutually beneficial, sustainable aquifer development and management. The Stampriet Transboundary Aquifer System was selected as one of the three case studies funded by UNESCO. The Stampriet Aquifer System is located in the arid part of the countries (Botswana, Namibia and South Africa) where groundwater is a sole provider for water resource. The area is characterised by the Kalahari (local unconfined aquifer) and Nossob confined aquifer

Abstract

Water management is a difficult and complex business requiring appropriate institutional arrangements as well as guidance and support from government, which is often unable to act effectively to address day-to-day water resource management (WRM) issues. Theoretically, water as a 'common pool resource' is best managed by users self-organised at a local level and within a basin framework. Water users and other stakeholders have detailed and up-to-date local knowledge as well as an interest in ensuring effective management to share water equitably between different users and to control pollution. This approach is supported by South Africa's National Water Act (NWA), which provides for the establishment of Catchment Management Agencies (CMAs) to perform a range of WRM activities within the framework of a National Water Resource Strategy (NWRS).
Hence, water resource management in general and conjunctive use in particular requires cross sector and cross level cooperative governance. Relevant institutions include the DWA at national and regional level, the CMA, if established, provincial departments that might impact on the water resources, water user associations, water services authorities, water services providers, water boards, and individual water users. These institutions are responsible for various activities and often require some level of inter- and intra-institutional cooperation. Ideally, multiple organisations, policies, legislation, plans, strategies and perspectives should be involved in water-related decision-making, which in turns creates complex leadership challenges. Globally, the lack of sustainable groundwater management can be ascribed to poor governance provisions. These include, but are not limited to, institutional arrangements and political will, including fragmented and overlapping jurisdictions and responsibilities, competing priorities, traditional approaches, rights and water pricing systems, diverging opinions, incomplete knowledge, data as well as uncoordinated information systems. Adding the poor operational and maintenance issues, decision-makers often view groundwater as an unreliable resource and are hesitant to make significant investments in groundwater infrastructure and capacity.
The recent Worldbank and WRC report on groundwater governance in South Africa revealed that the technical, legal, institutional and operational governance provisions were found to be reasonable at the national level but weak concerning cross-sector policy coordination. At the local level, basic technical provisions such as hydrogeological maps and aquifer delineation with classified typology are in place but other governance provisions such as institutional capacity, provisions to control groundwater abstraction and pollution, cross-sector policy coordination and the existence and implementation of groundwater management action plans are weak or non-existent.
It appears from this review that the major hindrances for sustainable groundwater governance and more so for integrated water resource management and conjunctive use scenarios are the discrepancy between groundwater and surface water provisions in the relevant legislation, associated guidelines and their implementation at regional and local, and the lack of skills and clear responsibilities for implementing water resource management actions at municipal level. This is demonstrated with several case studies.

Abstract

When considering how to reduce contamination of petroleum hydrocarbons in shallow aquifers, it is important to recognize the considerable capacity of natural processes continuously at work within the secondary sources of contamination. This natural processes are technically referred to as Monitored Natural Attenuation (MNA), a process whereby petroleum hydrocarbons are deteriorated naturally by microbes. This approach of petroleum hydrocarbon degradation relies on microbes which utilise oxygen under aerobic processes and progressively utilises other constituents (sulphates, nitrates, iron and manganese) under anaerobic processes. MNA process is mostly evident when light non-aqueous phase liquids (LNAPLs) has been removed while the dissolved phase hydrocarbon compounds are prominent in the saturated zone. The case studies aim at determining feasibility and sustainability of Monitored Natural Attenuation process at different sites with varying geological setting.

Abstract

Shale gas in South Africa can be a game changer for the Karoo and South Africa economy but it may have a devastating effect on the environment. The Karoo communities is highly reliable on groundwater for their stock, irrigation and also for domestic use. Knowing the process and the potential impacts of gas-well drilling and fracturing on shallow groundwater systems beforehand different appropriate studies can be done before any hydraulic fracturing can took place in South Africa. The biggest concerns with hydraulic fracturing is that the fracturing fluids will flow and discharge into shallow aquifers due to the high pressure used or the produced water mixed with deep saline water may discharge into the environment. This paper presents a baseline dataset that will be a reference point against which any future changes in groundwater concentrations can be measured. The Karoo basin with its numerous dolerite intrusions make it unique and different from other countries. These dolerite intrusions are associated with high yielding boreholes because of the fractured contact. The Karoo Basin may be under artesian conditions, which imply that any pollutant might migrate upwards in the Karoo. The understanding of key attributes for characterising groundwater of Karoo Aquifers is most importantly the depth to water level, the yield, and groundwater quality.. The understanding of these characteristics will help to close possible legislative loopholes regarding fracturing. This paper establish an interactive database to obtain full understanding of the hydrogeology of the Karoo to be able to quantify how much water is available in the Karoo and who is the users. Not only the quantity of the water in the Karoo, but also quality and age/origin by making use of different isotopes in conjunction with basic macro chemistry. This will allow for a broader picture before any unconventional gas mining in the Karoo takes place and it can be used to identify any future changes in groundwater quality and quantity of the Karoo aquifers.

Abstract

For a long time, professionals regarded social media as a superficial, unprofessional platform where internet users would submerge themselves in a virtual world, detached from real-life issues. Slowly, the myths and stigmas surrounding the use of social media has faded as more and more professionals and scientists have realized that these social platforms could be positively exploited in a professional manner which could be beneficial. In a digital age where information at our fingertips is the norm, professionals should co-evolve and ensure that their work is just as accessible and appealing, without the unnecessary jargon. Currently, science is mostly restricted to a very particular audience and conveyed in one direction only. Using a social media platform such as Twitter-which limits messages to only 140 characters-challenges scientists to convey their work in a very concise manner using simpler terminology. Furthermore, it dismisses the usual one-way form of communication by opening dialogue with fellow Twitter users. At conferences, Twitter can serve as a useful tool for active engagement which will not only "break the ice" between delegates but also ensure that important information is communicated to a much wider audience than only those in attendance. This idea was tested at the 2014 Savanna Science Network Meeting held in Skukuza, Kruger National Park, where the hashtag #SSNM was used. More than 63% of the Twitter users who participated in the #SSNM hashtag were actually not present at the conference. These external "delegates" were interested individuals from five different continents and in different professions besides Science. This highlights how social media can be exploited at conferences to ensure that key messages are conveyed beyond the immediate audience at the event.

Abstract

Preventing the spread of seepage from tailings storage facilities (TSF's) in groundwater is necessary as it often contains toxic contaminants. Experience has shown that seepage from TSFs is inevitable and that zero seepage remains difficult even with complex liner systems. Multiple seepage control methods are often required to minimise seepage to ensure that environmental regulations are met. Control methods can be grouped into either barrier or collection systems. Barrier systems are used to hinder seepage whereas collection systems are used to intercept seepage. A blast curtain, which is the focus of this article, is a type of collection system that is still at a conceptual level but has seen little or no application worldwide. It works in principle, similarly to a curtain drain, but is typically extended to greater depths depending on the aquifer vulnerability. Numerical modeling has shown that this mitigation measure could add another line of defence for seepage control. The depth and effectiveness of the curtain can be optimized with a numerical model to ensure optimal interception of contaminated seepage around the TSF. Depths of up to 30 m in fractured aquifers have been simulated in this study. A blast curtain is constructed by drilling a set of boreholes around a TSF in close proximity to one another and then fracturing the rock using either explosives or fracking methods to create a more permeable zone. This is then combined with a series of scavenger wells or natural seepage to abstract the contaminated water. Numerical simulation has shown that blast curtains are effective especially if groundwater flow is horizontal. The effectiveness decreases if the vertical flow component is significant. A blast curtain can result in the lowering of the water table, however, local depression is a less of a concern than potential groundwater contamination. {List only- not presented}

Abstract

Inadequate characterization of contaminated sites often leads to the development of poorly constructed conceptual site models and consequently, the design and implementation of inappropriate risk management strategies. As a result, the required remedial objectives are not achieved or are inefficient in addressing the identified risks. Unfortunately, it is all too common to find remedial intervention strategies that run for lengthy periods of time at great cost while generating little environmental benefit due to inadequate characterization of site conditions. High resolution site characterization (HRSC) can provide the necessary level of information to allow for development of rigorous conceptual site models, which can be used to develop and implement appropriate risk management solutions for environmental problems. At the outset, the HRSC approach generally has comparatively higher costs than traditional state-of-the-practice assessment methods. However, the project lifecycle costs can be substantially reduced due to development of optimal risk management strategies. In developing countries where there is a lack of legislation relating to soil and groundwater contamination or, a lack of enforcement of legislation which is present, the long-term liabilities related to contaminated sites are often not immediately apparent to the parties responsible for the sites. This often creates a reticence to employ HRSC techniques due to their increased cost, especially when much of the technology must be imported on a project specific basis from either Europe or the United States. The Authors provide information from several case studies conducted in South Africa where HRSC techniques have been employed to gain a greater understanding of subsurface conditions. Techniques employed have included surface-based geophysical techniques such as electrical resistivity tomography (ERT) and multi-channel analysis of seismic waves (MASW), passive soil gas surveys, deployment of Flexible Underground Technologies (FLUTe?) liners, diamond core drilling, fluid electrical conductivity profiling, downhole geophysical logging tools, the Waterloo Advanced Profiling System (APS), and the use of field laboratories. Several of the techniques required importing equipment and personnel from Europe or the US, and in several case studies, were a first to be employed in South Africa, or the continent of Africa for that matter. The Authors present data obtained using the HRSC techniques from the case studies and elaborate on how the information obtained was used to drive effective decision making in terms of managing long term environmental risks at the various sites, which has been positively embraced by local clients. The authors also highlight key challenges in conducting HRSC investigations in an emerging market context.

Abstract

South Africa is classified as a semi-arid region where the evapotranspiration sometimes exceeds the annual recharge through rainfall which leads to more drought periods. Combine the before mentioned issue with the water shortages and the impact of mining on water in South Africa, the focus therefore then needs to be placed on the proper estimation of recharge from rainfall and subsequent water management of these water sources. The Ermelo region in Mpumalanga was chosen for the investigation into calculating recharge from rainfall, using water balance methods as the basis on which recharge is calculated. The Ground Water Balance, Saturated Volume Fluctuation, Ground water level fluctuation and Cumulative Rainfall Departure methods was used to calculated recharge and then compare the different methods and their values with each other to compile an accurate estimation of recharge in the area. The data was analysed for each of the methods and then plotted and compared on a simple x-y chart. A new equation was formulated whereby any recharge from the previously mentioned methods can be normalized against the new formula for a more accurate recharge value. As a secondary objective a recharge intensity map was compiled for the area showing the areas of potentially high recharge.

Keywords: South Africa, Ermelo, Recharge Estimation, Water balance methods, Ground Water Balance, Saturated Volume Fluctuation, Ground water level fluctuation, Cumulative Rainfall Departure, Intensity maps.

Abstract

2-D Electrical Resistivity Tomography (ERT) and hydrochemical study have been conducted at El Sadat industrial city. The study aims at investigating the area around the waste water ponds to determine the possibility of water percolation from the wastewater (oxidation) ponds to the Pleistocene aquifer and to inspect the effect of this seepage on the groundwater chemistry. Pleistocene aquifer is the main groundwater reservoir in this area, where El Sadat city and its vicinities depend totally on this aquifer for water supplies needed for drinking, agricultural and industrial activities. In this concern, 7 ERT profiles were measured around the wastewater ponds.

Besides, 10 water samples were collected from the ponds and the nearby groundwater wells. The water samples have been chemically analyzed for major cations (Ca+2, Na+, K+, Mg+2), major anions (Cl-, CO3-2, HCO3-, SO4-2), nutrients (NO2-, NO3-, PO4-3) and heavy elements (Cd, V, Cr, Zn, Ni, Cu, Fe, Mn, Pb). Also, the physical parameters (pH, Alkalinity, EC, TDS) of the water samples were measured. Inspection of the ERT sections shows that they exhibit lower resistivity values towards the water ponds and higher values in opposite sides. Also, the water table was detected at shallower depths at the same sides of lower resistivity. This could indicate a wastewater infiltration to the groundwater aquifer near the oxidation ponds. Correlation of the physical parameters and ionic concentrations of the wastewater (ponds) samples with those of the groundwater samples indicates that; the ionic levels are randomly varying and no specific trend could be obtained. Also, the wastewater samples shows some ionic levels lower than those detected in other groundwater samples. Besides, the nitrate level is higher in samples taken from the cultivated land than the wastewater samples due to the over using of nitrogen fertilizers. Then, we can say that the infiltrated water from wastewater ponds are NOT the main controller of the groundwater chemistry in this area, but rather the variable ionic concentrations could be attributed to local, natural and anthropogenic processes.

Abstract

When planning an experimental setup in the laboratory, it is very important and possible to control all the variables so that one can manipulate particular variables at a given time. Experimental setups under natural conditions could be a challenging task. The success of an experiment depends to a large extent on the correct understanding of the functioning of a natural system. If the conceptual understanding of the natural system is erroneous, it is likely that unexpected results could be achieved. This was the case with the artificial recharge pilot project that was done in 2008 and 2009 at the Langebaan Road wellfield just outside Hopefield in the Western Cape. Years of research gave scientists a fairly good idea of the way in which the aquifer system functioned, especially since the establishment of the well field. This provided information of the response of the aquifer unit to large scale abstraction. The Langebaan Road aquifer unit is a multilayered system with a lower aquifer composed of Elandsfontyn gravel overlaying a bedrock layer of either granite of the Vredenburg or Darling plutons of the Cape Granite Suite or Malmesbury shale. The bedrock was considered impermeable. The upper aquifer layer was composed of mostly the Varswater Formation with peat and clay of the Elandsfontyn Formation forming the confining layer between the two aquifer layers. The extent of the different layers of the aquifer unit was plotted with a fair amount of accuracy and the clay layer was considered to be continuous between the two aquifer layers. Monitoring data for the area was done since 1974 with a gap in data-set between 1991 and 2001. Despite all the data from geophysical work, boreholes drilled, and the monitoring record, the research done prior and during the artificial recharge pilot project in 2008 and 2009 the aquifer units did not respond quite as anticipated. The Artificial Recharge (AR) pilot project team concluded that the aquifer units responded in a particular manner as opposed to the expected response according to the data and conceptual model at hand. It was thus clear that there are gaps in the conceptual model of the aquifer systems in the bigger Lower Berg River Valley that include the Langebaan Road, Elandsfontein and other aquifers that needed to bridge before another pilot test is attempted. Although the artificial recharge pilot project did not yield the expected results, valuable lessons were learned. This article will look at the conclusions and recommendations of the research done on the pilot project and attempt to evaluate the monitoring data (water levels, chemistry and rainfall) from the period just before the beginning of the AR pilot project. The monitoring data would be manipulated using the following techniques

Abstract

Decades of monitoring, characterising, and assessing nitrate concentration distribution and behaviour in the soil profile and it's pathway into groundwater have resulted in a good understanding of its distribution in the country. While the national distribution is of great importance, site specific conditions determine fate, transport, and ultimately concentration in a specific area. Field experimental work included installation of a barrier containing a cheaply available carbon source to treat groundwater. The "reactor"/ tank with dimensions- 1,37m height, 2.15m diameter used for the experiment was slotted for its entire circumference by marking and grinding through the 5mm thick plastic material. The top section was left open to allow for filling and occasional checking of filled material during the experiment. The tank was packed with Eucalyptus globulus woodchips which was freely available at the site. Concentrations of groundwater nitrate at the site were well over what could be expected in any naturally occurring groundwater systems, and would result only by major anthropogenic activities in unconfined aquifer areas of South Africa. The changes in parameter concentrations with time were measured in order to determine the efficiency and life span of the carbon source used for the experiment. This paper considers 35 months of monitoring at a site where a low technology method was implemented. Field implementation was tested at a site which previously experienced some NH4NO3 spills. Main results from the field work showed that nitrate was totally removed at the treatment zone and surrounding boreholes, and even sulphate and NH4+ were removed during the experiment. This shows that the woodchips were successful in affecting denitrification for 35 months. Data also shows that boreholes further downstream from the tank had reduced NO3-, SO42- and NH4+ levels. Using the available biodegradable carbon for the woodchips based on its composition, a barrier lifespan could be determined. The results of calculations showed that the barrier would be effective for at least another 6.9 years from the period of the last sampling date. A total lifespan of about 10 years can thus be estimated.

Abstract

Mining is becoming a problem in the Western Cape - different kinds of mining and other resources, different problems than in other parts of the country. The West Coast had been declared a development corridor and a mining priority area. It is an arid to semi-arid area, where surface water is scarce, and rainfall relatively low and decreasing as one moves north. Some areas have significant volumes of good quality groundwater available, with potential impacts by the mining activities. This would play the importance of different resources off against the other. Most see resources as minerals, such as gold, silver, phosphate, and others where the value of these resources is measurable. Resources are also human capital, time, water, air, a healthy environment. It is more difficult to measure the value of the second group, as some of them have more than just a Rand and cent value. The value of resources is mostly done by measuring its monetary value, i.e. how much you will get when you sell the resource to a customer, providing the way the value of most resources is measured, i.e. resource economics. Economics is an area that most scientists are not familiar with as it contains a way thinking, of rules and laws unrelated to the way they have been taught. Supply and demand determines the value of a commodity, with scarce resources normally fetching higher prices. The value of the second group of resources is more difficult to determine. When does a resource become a strategic resource? This would be a resource that has a limited supply, does not get regenerated through natural processes and that is needed for defence, energy supply and others important for the stability of a country. There are also a category of resources we cannot live without such as water, and air - pure, fresh air and water. Without it life on this planet will cease to exist. This could be termed critical resources. What do you do if the occurrence of two very important critical resources overlaps, where the extraction of the one will lead to irreparable damage to the other? This article will look at one site where a strategic resource occurs at the same site as an important water resource. It will compare the potential value of the mineral resource with the value of the water resource in the aquifer measured at the current value of water as available to the public. It will also take into account the value of the water resource from the perspective of a healthy functioning ecosystem and a RAMSAR site. This analysis becomes more valuable when considering the potential effects of climate change in the area and the cost of desalination.

Abstract

The Table Mountain Group (TMG) Formation in the Uitenhage region, in the Eastern Province of South Africa, has many groundwater users, which could result in the over-exploitation of the underlying aquifer. Consequently, several investigations have been conducted to help in the planning and management of groundwater resources within the region. Traditionally, these investigations have considered groundwater and surface water as separate entities, and have been investigated separately. Environmental isotopes, hydrochemistry and feacal colifom bacteria techniques have proved to be useful in the formulation of interrelationships and for the understanding of groundwater and surface water interaction. The field survey and sampling of the springs, Swartkops River and the surrounding boreholes in the Uitenhage area have been conducted. After full analysis of the study, it is anticipated that the data from the spring, Swartkops River and the surrounding boreholes show interannual variation in the isotope values, indicating large variation in the degree of mixing, as well as to determine the origin and circulation time of different water bodies. ?D and ?18O value for the spring ranges from ?18.9? to ?7.4?, and 5.25? to 4.82?, respectively, while ?D values for borehole samples range from ?23.5? to ?20.0? and ?18O values range from ?5.67? to ?5.06?. In the river sample, ?D values ranges from ?12.1? to ?4.2?, ?18O from ?3.7? to ?1.13?, respectively. The entrobacter aerogen and E.Coli bacteria were detected in the samples. E. coli population for spring and the artesian boreholes indicated low value while the shallow boreholes had higher values are relatively closer to those of the middle ridges of the Swartkops River. The EC values for the spring samples averages at 14 mS/m, borehole samples ranges from 21 mS/m to 1402 mS/m, and surface water ranges from 19 mS/m to 195 mS/m. Swartkops River is an ephemeral, therefore it is expected that diffuse recharge occurs into the shallow aquifer.

Abstract

POSTER The study aims at using hydrogeochemical model to establish groundwater quality in shallow and deep aquifers in Heuningnes Catchment which is located within Bredasdorp in the Western Cape Province. The catchment is positioned at latitude of 34o42'50"S and longitude 20o07'13"E. The area is about 1400km2 has vleis, lakes and pans and its predominant formation is sedimentary rocks of Table Mountain and Bokkeveld Groups sitting on a crystalline basement of the Malmesbury granites. Comprehensive characterisation of the hydrogeochemical evolution is lacking and the current study argues that the use of hydrogeochemical Analysis Model (HAM) has potential to establish water-type, water source, water mixing/rock-water interactions, salinity, saturated adsorption ratio and hardness-softness of that predominant hydrochemical facies in the study area in addition to assessing the compliance of such water to WHO and South Africa water quality guidelines for drinking and agricultural use. Groundwater samples will be collected in 45 different locations (wellpoints/shallow wells, boreholes and wetland as end member) using in-situ sampling techniques to measure pH, electrical conductivity, total dissolved solids and temperature. Turbidity, total hardness, calcium, chloride and bicarbonate will be analysed using analytical chemistry methods including titrimetric method. Magnesium, potassium, sodium, nitrate and phosphate analysed by Atomic Absorption Spectrophotometer whilst sulfate will be analysed using spectrophotometer. Graphical methods such as piper diagram will be used to present the results to determine water-type, water freshness/hardness, water source, water mixing/rock-water interactions, salinity, saturated adsorption ratio and hydrogeochemical processes. The results from the present study are envisaged to inform formulation of science-based interventions strategies that will lead to sustainable utilization and management of the water resources in the area to improve the livelihoods of people and environmental integrity.

Key words: Groundwater quality, Heuningnes Catchment, hydrogeochemical Analysis Model, Piper diagrams, Hydrogeochemistry

Abstract

In this study, petroleum hydrocarbon contamination assessment was conducted at a cluster of petroleum products storage and handling facilities located on the Southern African Indian ocean coastal zone. The Port Development Company identified the need for the assessment of the soil and groundwater pollution status at the tank farms in order to develop a remediation and management plan to address hydrocarbon related soil and groundwater contamination. Previous work conducted at the site before consisted out of the drilling and sampling of a limited number of boreholes. The current investigation was triggered by the presence of free phase product in the coal grading tippler pit located ~350 m down gradient and south-east and east of the tank farms, rendering the operation thereof unsafe. The assessment intended identifying the source of product, distribution and mobility, the extent of the contamination, and the human health risks associated with the contamination. To achieve these, the investigation comprised site walkover and interviews, drilling of 76 hand auger and 101 direct push holes to facilitate vertical soil profile VOC screening and sampling (soil and groundwater) as well as granulomeric analysis to understand grain size distribution within the soil profile. The highest concentrations were associated with the coarse sand layers with the highest permeability. Free phase hydrocarbons product was found in holes adjacent to the pipeline responsible for the distribution of the product form the jetty to the different tanks farms. Of the 57 soil samples, 21 had high values of GRO and DRO, with 22 below Detection Limit and 14 can be described having traces of hydrocarbon. Both TAME and MTBE were detected in most of the water samples taken, including from wells located far down gradient. The groundwater sink, adjacent to the pipeline running from west to east, resulted in the limited lateral spread of MBTE in this area, with limited movement towards the sea. The depth of the soil contamination varies over the sites. Based on the site assessment results it was concluded that most of the groundwater contamination, which is a mixture of different product types, is associated with the pipeline responsible for transporting product from the jetty to the different petroleum companies. {List only- not presented}

Abstract

Define chemical signatures from river waters collected in the Crocodile (West) and Marico Water Management Areas, South Africa. Samples were analysed for anion complexes using Ion Chromatography (IC) and major and trace element chemistry using quadrupole Inductively Coupled Plasma-Mass Spectrometry (q-ICP-MS). Results are used to define the various chemical signatures resulting from activities within the study area which include mining, agriculture, industry, residential and domestic, and recreational usage and to differentiate the 'background' that arises from the natural geological heterogeneity. The aim of this characterisation is to fingerprint the chemical signatures of various anthropogenic activities irrespective of background. Results from this investigation have been mapped using GIS to visualise the data across the study area. Based on the results, the contamination sources within the area can be identified and ranked in terms of their contribution to the total effective contamination received at Hartebeespoort Dam. {List only- not presented}

Abstract

Groundwater in South Africa is the most important source of potable water for rural communities, farms and towns. Supplying sufficient water to communities in South Africa becomes a difficult task. This is especially true in the semi-arid and arid central regions of South Africa where surface water resources are limited or absent and the communities are only depended on groundwater resources. Due to a growing population, surface water resources are almost entirely being exploited to their limits. These factors, therefore, increases the demand for groundwater resources and a more efficient management plan for water usage. For these reasons, the relation between the geology and geohydrology of South Africa becomes an important tool in locating groundwater resources that can provide sustainable quantities of water for South Africans. It was therefore decided to compile a document that provides valuable geohydrological information on the geological formations of the whole of South Africa. The information was gathered by means of interviews with experienced South African geohydrologists and reviewing of reports and articles of geohydrological studies. After gathering the relevant information, each major geological unit of South Africa together with its geohydrological characteristics was discussed separately. These characteristics include rock/aquifer parameters and behaviour, aquifer types (primary of secondary), groundwater quality, borehole yields and expected striking depths, and geological target features and the geophysical method used to locate these targets. Due to the fact that 90 % of South Africa's aquifers are classified as secondary aquifer systems, groundwater occurrence within the rocks of South Africa is mainly controlled by secondary fractures systems; therefore, understanding the geology and geological processes (faulting, folding, intrusive dyke/sills & weathering) responsible for their development and how they relate is important. However, the primary aquifers of South Africa (Coastal Cenozoic Deposits) should not be neglected as these aquifers can produce significant amounts of groundwater, such as the aquifer units of the Sandveld Group, Western Cape Province. Drilling success rates and possibility of striking higher yielding boreholes can be improved dramatically when an evaluation of the structural geology and geohydrological conditions of an area together with a suitable geophysical method is applied. The ability to locate groundwater has been originally considered (even today) a heavenly gift and can be dated back to the Biblical story of Moses striking the rock to get water: "behold, I will stand there before thee there upon the rocks thou shalt smite the rock and there shall come water out of it" (Exodus 17:6).

Abstract

Conjunctive use of surface water and groundwater resources offers huge advantages to municipalities. It can significantly increase the resilience of the municipal water supply to drought situations. Optimal use and integration of different sources would result in a yield of the total system that is higher than the combined yield of each source separately. However, integrated water resource management (IWRM) in general and planned conjunctive use of both groundwater and surface water resources in particular have not been successfully implemented yet in South Africa. Six selected case studies of municipalities across South Africa, which utilize both surface water and groundwater for the water supply to specific towns, have undergone a review of their current water governance provisions wrt groundwater, surface water and conjunctive use. The review has been based on a questionnaire for direct interaction with the local government officials, supported by other readily available documents such as municipal Integrated Development Plan (IDP) and Water Services Development Plan (WSDP), municipal websites, Blue Drop and Green Drop Assessment Reports, Municipal Strategic Self-Assessment (MuSSA) and the All Towns Reconciliation Strategy reports. These case studies reveal the different institutional arrangements for water resource management and water supply services that exist in municipalities. The advantages and disadvantages of the institutional arrangements for each case study have been determined. Problem areas identified include split of responsibilities for surface water and groundwater resources between different institutions, lack of financial and HR support within the government spheres, lack of formal and structured stakeholder engagement, insufficient monitoring for both sources, inter alia. Based on this comparative study of different municipalities, a draft framework of optimal institutional arrangements and governance provisions at local government level is developed to support the integration and optimisation of surface water and groundwater supply. The proposed framework is based on three pillars; viz. leadership and clear structures within the responsible local government institution, formal engagement with all relevant internal and external stakeholders and a sufficient monitoring network that supports the stakeholder engagement and decision making.

Abstract

Coal constitutes 77% of the primary energy needs in the country, with the Waterberg Coalfield estimated to host about 40% of the remaining South African coal resources. The Karoo coals were deposited in a reduced environment that have the potential to produce sulphides within the sediments they are hosted. The sulphur content within the coal can range from 0.1 wt.% to as high as 10 wt.%. Mining generates a disturbance in the natural groundwater levels and affects the surrounding water chemistry when sulphate is produced as a result of pyrite oxidation. Acid base accounting (ABA) was used to determine the balance between the acid producing potential (AP) and acid neutralizing potential (NP). From the analysis the Net Neutralising Potential (NNP) classified samples as either acid or non-acid producing. ARD does not only result in the generation of acid but is accompanied by decreased pH and increased values of specific conductance, dissolved metals and sulphate. The ABA results showed that interburden and coal samples have higher risks of producing acid upon oxidation than overburden samples. Higher concentrations of neutralising minerals are present in overburden samples. ABA indicated that the material 60m below ground surface had a higher acid producing potential than the material above. The analysis from kinetic tests showed the long-term behaviour of different samples, with the electrical conductivity (EC) and pH changing over time. Samples with lower pH continued to produce more sulphate, while calcium continued to increase until it was depleted from the samples. Inductively coupled plasma analysis determined the release of the heavy metals which can be detrimental to the environment, such as As, Co, Ni and Pb. The water demand will increase as mining continues in the area, with inter-catchment transfers identified to overcome local water scarcity issues. ARD poses a big threat to both groundwater and surface water resources.

Abstract

Environmental isotope techniques have been successfully applied in the field of hydrogeology over the last couple of decades and have proved useful for understanding groundwater systems. This paper describes a study of the environmental isotopes for Oxygen (18O) and Hydrogen (1H, 2H-Deutrium, 3H-Tritium) obtained from various points in and around the underground coal gasification (UCG) site in Majuba, South Africa. UCG is an alternative mining method, targeting deep coal seams that are regarded as uneconomical to mine. The process extracts the energy by gasifying the coal in-situ to produce a synthetic gas that can be used for various applications. The site consists of shallow, intermediate and deep aquifer systems at a depth of 70m, 180 and 300m respectively. The intermediate aquifer is further divided into the upper and lower aquifer systems.
Samples were taken from each aquifer system together with supplementary samples from the Witbankspruit and an on-site water storage dam. A total of 15 samples were submitted for isotope analyses. By investigating the various isotopic signatures from all the samples taken, it will be possible to determine if there are similar or contrasting isotopic compositions by deducing possible water source for each sample due to isotopic fractionation caused by physical, chemical and biological processes. This will also be supported by deducing the mean residence time (MRT) for each water source sampled based on the Tritium data as well as the chemistry data already available for different sources. The chemistry data established linkages between the upper and lower intermediate aquifers.{List only- not presented}
Key words: Environmental isotopes, UCG, Water source, Isotope fractionation

Abstract

Accurate parameter estimation for fractured-rock aquifer is very challenging, due to the complexity of fracture connectivity, particular when it comes to artesian flow systems where the potentiometric is above the ground level, such as semi-confined, partially confined and weak confined aquifers in Table Mountain Group (TMG) Aquifer. The parameter estimates of these types of aquifers are largely made through constant-head and recovery test method. However, such a test is seldom carried out in Table Mountain Group Aquifer in South Africa due to a lack of proper testing unit made available for data capturing and appropriate method for data interpretation. An artesian borehole of BH 1 drilled in TMG Peninsula Formation on the Gevonden farm in Western Cape Province was chosen as a case study. The potentiometric surface is above the ground level in rainy season, while it drops to/below ground level during the dry season. A special testing unit was designed and implemented in BH 1 to measure and record the flow rate during the free-flowing period, and the pressure changes during the recovery period. All the data were captured at a function of time for data interpretation at later stage. Curve-fitting software developed with VBA was adopted for parameter estimation based on the constant-head and recovery tests theories. The results indicate that a negative skin zone exists in the immediate vicinity of the artesian borehole, and the hydraulic parameters estimates of transmissivity (T) ranging from 6.9 to 14.7 m2/d and storativity (S) ranging from 2.1*10-5 to 2.1*10-4 appear to be reasonable with measured data collected from early times. However, due to formation losses, the analytical method failed to interpret the data collected at later times. Consequently the analysed results by analytical solution with later stage data are less reliable for this case. The MODFLOW-2000 (Parameter Estimation) package developed by USGS was also adopted to determine these parameters for the same aquifer. It approves that there exist formation losses, which leads to the aquifer response distinctly different at later stage of overflow and recovery tests. The aquifer parameter estimates with early time data of tests by analytical and numerical methods show that there is generally good agreement. However, significant errors could be generated by analytical method applied where there is occurrence of well or formation losses, while these restrictions could be overcome by applying a numerical method.

Abstract

Two ventilation shafts were proposed to be excavated to depths of 100 and 350 m to intersect an underground mine, in the Bushveld Complex. The area is made up of fractured aquifers and the assignment was to identify the exact positions of the permeable zones within the shafts profiles as well as estimate the groundwater inflow rates at every 5 m interval along the shafts profiles. The project was budget and time constrained and therefore the preferred hydrogeological characterisation techniques, particularly the percussion drilling, aquifer testing and numerical modelling could not be conducted. The study was completed by conducting packer tests in HQ sized holes drilled at the exact positions of the proposed shafts. The packer test data was then interpreted using Thiem equation, a modification of Darcy Equation for radial flow, to estimate the steady state inflow rates into the shafts. Transient state flow is more challenging to calculate analytically, as it is time and aquifer storage dependent. However, transient state flow in shafts exists for the first 10 - 15 days only and is short lived. Thereafter, a steady state flow occurs where the rate is nearly fixed for the rest of the life of mine, unless new external stresses, such as mine dewatering, takes place within the radius of influence. Six months later the shafts were excavated and the permeable zones were encountered at the exact positions as predicted using the packer testing. In addition, the inflow rates calculated using analytical modelling was successful in estimating the inflow rates recorded after the shafts were excavated. The packer testing and analytical modelling was therefore effective in assisting the mine to plan the necessary pumps and management plans within the allocated budget and timeframe.

Abstract

Underground coal gasification (UCG) is technology that aspires to exploit coal reserves using in-situ gasification. This mining method gasifies coal seams while extracting a syngas that can be used for electricity generation. Since the bulk of this process occurs in the subsurface, there is a possibility of impacting on regional groundwater quality. This paper seeks to assess this impact on groundwater across different aquifers while taking into account the chemical evolution of these aquifers. Three aquifer systems were identified namely the shallow, intermediate and the deep aquifer which comprises of the coal seam. The water chemistry was reviewed over a two year period during which the gasifier was still active. Alkaline conditions were prevalent across the three aquifers with minor seasonal changes. High levels of dissolved solids were observed especially in the deep aquifer but the quality of water was poor even in background samples. The impact of gasification does have small variation in already unusable water in the deep aquifer which was also characterized by low hydraulic conductivity. Higher hydraulic conductivity values were established in the shallow aquifer. No significant groundwater chemistry change was detected in this aquifer as a result of gasification process.

Abstract

The question about the natural recharge areas for two of the Lower Berg river aquifers units, Elandsfontein Aquifer unit and Langebaan Road aquifer unit, has been keeping geohydrologists working in the area without a definite answer. Tredoux and Engelbrecht have postulated that it must be from the higher grounds around Hopefield, while Woodford hinted that an offshoot fault from the Coleso fault system could also cause the systems to be recharged from the Darling hills. Isotope studies had been done for the proposed Hopefield recharge area, but none has so far been done for the possible Darling recharge system. This paper will look at the studies done up to date and evaluate the data available for the boreholes drilled in the area in an attempt to get a clearer understanding of the two possibilities. It will also identify possible gaps in our knowledge of the area and the steps that would make it possible to fill in the gaps.

Abstract

The subsurface has been likened to a maze due to the intricate and often disconnected pathways contained even in unconsolidated and relatively homogeneous aquifer systems. The weathered fractured aquifers in the Karoo offer unique challenges to those planning monitoring campaigns and provide opportunities for the research community to identify innovative solutions. Careful thought needs to be given to the objectives of monitoring as these can change the requirements of the work. Other important considerations are the location and design of monitoring wells which often needs to be tailored to site specific conditions while the selection of determinands to be analysed introduces yet another layer of complexity. These include questions around the relevant detection limits, representative sampling methods and a host of other aspects. Following prescribed approaches designed for managing traditional industrial processes may not be relevant even though these approaches are based on decades of research and learning from past experience, both good and bad. Careful consideration of the technical detail in advance of beginning any monitoring in the field is essential and even then, as in any hydrogeological assessment, a level of uncertainty will always remain. This presentation will cover the status of planning work on Karoo aquifer characterisation and geochemical assessment of the ambient or baseline conditions. Significant effort continues to be made to tailor fieldwork to site specific conditions and be ready to collect a representative data set when conditions allow. {List only- not presented}

Abstract

POSTER As the National Water Act has evolved to provide for more effective and sustainable management of our water resources, there has been a shift in focus to more strategic management practices. With this shift come new difficulties relating to the presentation of sensitivity issues within a spatial context. To this end it is necessary to integrate existing significant spatial layers into one map that retains the context, enables simple interpretation and interrogation and facilitates decision making. This project shows the steps taken to map and identify key groundwater characteristics in the Karoo using Geographic Information Systems (GIS) techniques. Two types of GIS-based groundwater maps have been produced to assist with interpretation of existing data on Karoo Aquifer Systems in turn informing the management of groundwater risks within Shell's applications for shale gas exploration. Aquifer Attribute and Vulnerability maps were produced to assist in the decision making process. The former is an aquifer classification methodology developed by the project team, while the latter uses the well-known DRASTIC methodology. The overlay analysis tool of ESRI's ArcGIS 10.1 software was used, enabling the assessment and spatial integration of extensive volumes of data, without losing the original detail, and combining them into a single output. This process allows for optimal site selection of suitable exploration target areas. Weightings were applied to differentiate the relative importance of the input criteria. For the Attributes maps ten key attributes were agreed by the project team to be the most significant in contributing to groundwater/aquifer characteristics in the Karoo. This work culminated in the production of a series of GIS-based groundwater attributes maps to form the Karoo Groundwater Atlas which can be used to guide groundwater risk management for a number of purposes. The DRASTIC model uses seven key hydrogeological parameters to characterise the hydrogeological setting and evaluate aquifer vulnerability, defined as the tendency or likelihood for general contaminants to reach the watertable after introduction at ground surface.

Abstract

Based on a modified DRASTIC model and GIS techniques, shallow groundwater vulnerability assessment was carried out in the Federal Capital City of Abuja, Nigeria. The results indicate that the studied area can be divided into three zones, namely: low groundwater vulnerability zone (vulnerability index <100) which covers about 60% of the City; moderate vulnerability zone (vulnerability indexes 100-140) which covers 35% of the City and high vulnerability zone (vulnerability index >140) which covers only 5% of the City. The highest groundwater vulnerability zone mainly locates in the central solid waste disposal site area in the outskirt of the City. The findings correlate well with the results of the physicochemical and microbiological investigation. The general low contamination vulnerability signature of the City may be attributed to absence of industries, limited agricultural activities, and preponderance of clayey top soil which effectively forms the first defence against contamination of the underlying aquifers as well as the presence of central sewage collection facility that covers about 25% of the City.

Abstract

Fine ash is a by-product generated during coal combustion and gasification. It is often disposed of as slurry and stored on tailings dams over long periods of time, where it is exposed to weathering. Weathering causes soluble ions to go into solution and to be transported along preferred pathways through the tailings dam. This study was conducted to assess the leaching behaviour of fresh and weathered fine ash and to evaluate the impact on the underlying aquifers. A kinetic test was conducted over 21 weeks to analyse the leachate composition of progressively-aged fine ash and to calculate the release rates for major ions and trace metals of environmental concern. The leachate composition was compared to the groundwater composition of the underlying aquifers to assess the environmental impact of long term ash leaching. The study showed that the release rate of Ca decreased with increasing depth and age of the fine ash. The release rate of Mg, Na, K, Mo, V, Ba, Cr and Mo increased slightly between 22 m and 28 m in the tailings dam. Aluminium had a decreasing release rate from 28 m depth onwards. It was concluded that fine ash leaching influenced the water composition of the underlying aquifers because similarities were observed in the water type trend. The shallow aquifer south of the tailings dam contained Ca/Mg/SO4/Cl/NO3 water with a significant increase in Ca, Mg, Na, Cl and SO4 over time. These ions were expected to be found in the pollution plume due to their high release rate observed in the fine ash. The deeper aquifer northeast and south of the tailings dam showed a reverse trend of decreasing Ca, Mg and NO3 with time. This is possibly due to decreasing release rates in the aging fine ash and due to the cation exchange capacity (CEC) of the aquifer retarding the movement of Ca and Mg in the pollution plume. The shallower aquifer northwest of the tailings dam showed a decrease in Ca and Mg but an increase in K, while the water composition of the deeper aquifer increased in Ca, Mg, Na, K and Cl. This indicates that the pollution plume moved from the shallower to the deeper aquifer and that most of the Ca and Mg content in the fine ash has been leached from the tailings dam after more than 30 years of storage. The study confirmed that leaching of elements from the fine ash tailings dam had a negative influence on the underlying aquifers and that the clay lining was not sufficient in retaining the leachate.

Abstract

The proposed underground copper mine is one of the first Greenfield developments in the Kalahari Copper Belt. Groundwater resources in the region are scare and saline mainly due to minimal recharge. Management and simulations of groundwater inflows formed an integral part of the new mine design to reduce production losses caused by the inflows and to ensure a safe mining environment. The mine is located is a complex hydrogeological setting characterised by folding and deep water levels. Multiple fractured aquifers are associated with the mining area. Groundwater numerical modelling was performed in Groundwater Modelling System (GMS) using MODFLOW-NWT. Results of the scenarios were used as a management tool to aid in the potential inflow predictive simulations and dewatering management. The numerical model was calibrated by using field measured aquifer parameters and piezometric heads. Numerical simulations assisted in estimating average groundwater inflows at certain stages of the proposed mine development. The simulated mine groundwater inflow volumes were used as input into the design of the dewatering measures to ensure a safe mining environment.

Abstract

The Birimian and Tarkwaian rocks of the Paleoproterozoic West African Shield host some of the most important gold reserves in the world, with Ghana the world's 10th largest gold producer and the region collectively producing more gold than all but five countries in the world. The gold was deposited during successive hydrothermal sulphide alteration events, which were channelled by shear zones and thrusts formed during the regional progressive Eburnean tectono-thermal deformation event. The hydrothermal fluids were auriferous and sulphide-rich, resulting in two distinct types of gold and sulphide mineralisation: (1) gold-bearing quartz- and quartz-ankerite veins, occurring in NNE-SSW trending shear zones or thrust folds, usually in Birimian metasediments, with associated sulphides deposited on the fragmented wall rock and (2) disseminated gold-bearing pyrite and arsenopyrite, occurring in halos within the same shear zones or thrust folds as the quartz veins. The sulphidic nature of the gold deposit leads to a high risk of acid rock drainage (ARD). During operations, inflowing groundwater may carry the ARD into underground workings and opencast pits. Post-closure, as the groundwater rebounds, there is a risk of acidic pit lakes forming or acidic decant of underground mines. However, the occurrence of ARD in such systems can be predicted by a combination of weathering profiling, mineralogical profiling and conventional acid base accounting (ABA). The weathering profile can be divided into three zones, readily distinguishable in borehole core: (i) Oxide Zone, from which both the acid-generating sulphide minerals and the acid-neutralising carbonate minerals have been largely leached, (ii) Transitional Zone, from which the carbonate minerals have been largely leached but the sulphide minerals remain, (iii) a Fresh/Primary Zone, where both sulphide and carbonate minerals occur. The Oxide Zone is generally non acid-generating, the Transitional Zone is acid-generating and the Fresh Zone is potentially acid-generating, depending upon the balance of sulphide vs carbonate minerals. Mineralogical profiles can be prepared from the relative abundance of macroscopic sulphide and carbonate minerals in the borehole core, again providing an assessment of ARD risk. Combined logs can then be prepared from these profiles with acid-generation and neutralisation data from ABAs, illustrating in space where the highest ARD risk zones are located. Using this information, groundwater and mine water management options can be developed for operations and closure, such as prioritisation of open pit backfilling or which levels of an underground mine water should be preferentially excluded from.

Abstract

Worldwide many aquifer systems are subject to hydrochemical and biogeochemical reactions involving iron which limit the sustainability of groundwater schemes. This mainly manifests itself in clogging of the screen and immediate aquifer with iron oxyhydroxides resulting in loss of production capacity of the borehole. Clogging is caused by chemical precipitation and biofouling processes which also manifests in South African wellfields such as the Atlantis and the Klein Karoo Rural Water Supply Scheme. Both wellfields have the potential to provide a sufficient, good quality water supply to rural communities, however clogging of the production boreholes has threatened the sustainability of the scheme as quality and quantity of water is affected. Repeated rehabilitation of the affected boreholes using techniques such as the Blended Chemical Heat Treatment (BCHT) method does not provide a long term solution. Such treatments are costly with varying restoration of original yields achieved and clogging recurs with time. Currently, the research, management and treatment options in South Africa have focused on the clogging processes which are complex and site specific making it extremely difficult to treat and rectify. This project attempts to eliminate the cause of the clogging which is elevated concentrations of dissolved iron. High iron concentrations in groundwater are associated with reducing conditions in the aquifer allowing for dissolution of iron from the aquifer matrix. These conditions can be natural- and/or human-induced. Attempts to circumvent iron clogging of boreholes have focussed on increasing the redox potential in the aquifer to prevent dissolution and facilitate fixation of the iron in the aquifer matrix. Various in situ treatment systems have been implemented successfully overseas for some time. However, in South African in situ treatment of iron has only been a theoretical approach. Based on experience from abroad the most viable option to research and apply elimination of ferrous iron in South African aquifer systems would be through the in situ iron removal treatment The objective of this paper is to set out the experience from abroad and to outline the initial results of this treatment. A pilot plant for testing the local applicability of this method was constructed at the Witzand wellfield of the Atlantis primary aquifer on the West coast of South Africa.