Conference Abstracts

All Abstracts were presented at the Groundwater Conferences

Displaying 1 - 50 of 795 results

Title	Presenter Name	Presenter Surname	Conference year	Keywords
An Approach To Determining The Most Suitable Combination Of Groundwater Impact Mitigation Measures With The Use Of A Gold Tailings Case Study	Pieter F	Labuschagne	2019	impact mitigation measures
Abstract The mitigation of groundwater impacts related to gold mining tailings disposal within the Orkney-Klerksdorp region was assessed and presented as a case study. The most pressing concern for the facility owners is the potential for pollution of water resources in the vicinity of the mines, especially after mine closure. The key focus of this paper is to describe how methods were applied to characterise the aquifer and keeping the source-pathway-receptor principles in mind. Characterisation also involves lessons learn by comparing pre-tailings deposition and post-tailings deposition aquifer bahviour. Ultimately the process followed in this paper has led to the development of a logical approach to estimate groundwater liability costs in a typical tailings environment. The link between hydrogeology, geotechnical engineering and civil engineering was identified as a critical foundation for the development of a successful groundwater management strategy
Groundwater Monitoring During An Underground Coal Gasification Process	Johan	van Dyk	2015
Abstract Underground Coal Gasification (UCG) is an emerging, in-situ mining technology that has the advantage to access a low cost energy source that is currently classified as not technically or economically accessible by means of conventional mining methods. As such it offers significant potential to dramatically increase the world's non-recoverable coal resource. Groundwater monitoring in the South African mining industry for conventional coal mining as an example, is well established, with specific SANS, ASTM and ISO Standards dedicated for the specific environment, location and purposes. In South Africa a major impact of the coal mining industry can be a reduction in the groundwater quantity and quality. South-Africa's groundwater is a critical resource that provides environmental benefits and contributes to the well-being of the citizens and the economic growth. Groundwater supplies the drinking water needs of a large portion of the population; in some rural areas it represents the only source of water for domestic use. Utilization and implementation of groundwater monitoring programs are thus non-negotiable. The groundwater quality management mission, according to the Department of Water and Sanitation in South-Africa, is set in the context of the water resources mission and is as follows: "To manage groundwater quality in an integrated and sustainable manner within the context of the National Water Resource Strategy and thereby to provide an adequate level of protection to groundwater resources and secure the supply of water of acceptable quality." The scope of this paper is to propose an implemention strategy and a fit-for-purpose groundwater monitoring program for any Underground Coal Gasification commercial operation. It is thus important to pro-actively prevent or minimise potential impacts on groundwater through long-term protection and monitoring plans. A successful monitoring program is one that consists of (1) an adequate number of wells, located at planned and strategic points; (2) sufficient groundwater sampling schedules; and (3) a dedicated monitoring program and quality control standard. In order to have an efficient monitoring program and to prevent unnecessary analysis and costs, it is also critical to determine upfront what parameters have to be monitored for the specific process and site conditions.
The Value Of Monitoring: Case Study Of An Artesian Borehole	Neville	Paxton	2019	Monitoring
Abstract Groundwater monitoring, especially from the end users' point of view, is often considered an add-on, or even unnecessary overhead cost to developing a borehole. Simply measuring groundwater level over time can however tell a story on seasonal rainfall fluctuations as well as the response of an aquifer to the removal of an abstracted volume of water. In this case an artesian borehole of high yield and exceptional quality was drilled in an area of minimal groundwater use because of known poor quality and low yields. The borehole was drilled in two stages with the deeper drilling resulting in significantly higher yields and the artesian flow. Sediment free water, deep artesian water strikes and a lack of flow around the casing led to the conclusion that capping at surface would control the visible artesian flow of 4 L/s. A slight drop in pressure indicated that subsurface leakage may however be occurring. Neighbouring boreholes with automated water level monitoring provided data showing a correlation of drop in water level to the second deeper drilling event. The artesian borehole was yield tested and this too was visible in the water level monitoring data. Hereafter it became apparent that each activity performed at the artesian borehole had an impact on the monitoring boreholes, and that a subsurface leak was causing local depressurization of a semi-confined to confined aquifer. An initial attempt to save the artesian borehole was unsuccessful, resulting in the necessary blocking and abandonment of a high yielding, superior quality borehole. If monitoring data was not available the local drop in water level would never have been noticed with disastrous effect and no evidence for the cause. Simple water level monitoring has averted this and kept neighbourly relations and ground water levels intact
Groundwater Protection Zoning- A case study of the Rawsonville research site.	Shuaib	Dustay	2015	groundwater protection zones
Abstract Currently limited progress is made in South Africa (and Africa) on the protection of groundwater used for drinking water. To achieve the objective of water for growth and development and to provide socio-economic and environmental benefits of communities using groundwater, significant aquifers and well fields must be adequately protected. Groundwater protection zoning is seen as an important step in this regard. Till today, limited case studies of groundwater protection zoning exists in Africa. A case study at the Rawsonville research site is conducted in this research project. Generic protection zones can be delineated at the site using published reports and database data. However, due to the complexity of the fractured rock at the research site, these would be of limited value and would not provide adequate protection for the well field Baseline data was collected by conducting a hydro census and through aquifer tests. An inventory of the activities that can potentially impact water quality was done and aquifer characteristics such as transmissivity and hydraulic conductivity were determined through various types of aquifer testing. Fracture positions were identified using fluid logging and fracture flow rates were also measured using fluid logging data. A conceptual model and preliminary 3D numerical model were created to try to understand groundwater movement at the research site. The knowledge gained will be used to guide information gathering and monitoring that can be used to build a more detailed numerical model and implement a trustworthy groundwater protection plan at a later stage. The expected results will have applicability to groundwater management in general. The protection plan developed during this project can be used as a case study to update and improve policy implementation. {List only- not presented}
Determination Of Water Retention For Ash Dumps And Implications On Groundwater Contamination	Gundo	Mathoho	2019	contamination
Abstract Burning of coal for electricity production has resulted in vast amounts of ash being deposited in ash dumps. Rain water and ash water conditioning results in the wetting of ash dumps and if the water retention capacity is exceeded there is a possibility of leaching to soil and underlying aquifers. In this study two different coal ash are used to determine the water retention as excess amount of process water at power stations ash dumps can lead to impeding the desired water balance, which can be critical for maintain various plant processes. The nonlinear relationship between soil water content and matrix suction of a porous material under unsaturated conditions is described by the soil water characteristic curve (SWCC). The SWCC for a given material represents the water storage capability enabling the determination of varying matric suction such as prediction of important unsaturated hydraulic processes including soil permeability, shear strength, volume change with respect to the water content changes. This paper presents an alternative, cost effective and rapid method for measuring and subsequent estimating of the soil-water characteristics of any soil type. Several methods are available to obtain the measurements required for defining soil-water characteristics. However, obtaining the required measurements for a SWCC is generally difficult since there is no laboratory or field instrument, capable of measuring a typical complete plant available water suction range accurately. Due to high methodological effort and associated costs of other methods, a simplified evaporation method which was implemented in the HYPROP (Hydraulic Property analyzer, UMS, 2012) becomes a possible alternative. It relies on the evaporation method initially proposed Schindler (1980). A typical work range for a HYPROP system is 0 to 100 KPa as read out from the two high capacity tensiometers installed at different heights within a saturated sample column. For a dry coal ash dump to be optimally used as sinks, input water applications should be matched with evaporation rates and capillary storage. This will ensure the moisture storage of the ash dump is not exceeded and consequently avert leachate generation at the base of the ash dump. The field capacity of waste materials is of critical importance in determining the formation of leachate in landfills which in this case is the coal ash dump facility. It is the field capacity limit when exceeded which give rise to leachate generation consequently promoting a downward movement of generated leachate.he study found that it is possible to use the Hyprop together with an empirical based fitting model to define a complete SWCC along a dewatering path. The study found the Brooks-Corey model as the suitable representative of the Hyprop measured data, confirmed by AICc and RMSE analysis. The Brooks-Corey estimated retention function parameters within +/- 1% error. A mean value of 35.3% was determined as the water retention or field capacity value for Matimba Coal ash. If the ash dump is operated in excess of this value, chances of groundwater pollution are high.
Stampriet Transboundary Aquifer System	Kwazikwakhe	Majola	2015

Ground Water Management in South Africa: Challenges and Constraints	Courage	Mlambo	2015
Abstract Water scarcity is a growing issue in South Africa. The consumption of water is rising and as such, water is becoming a scarce and valuable resource. Given the circumstances that South Africa is facing, improving the use of ground water could help tackle water scarcity in South Africa. Groundwater has been an important source of water and it can bring socio-economic benefits if properly used. Studies have proved that groundwater resources play a fundamental role in the security and sustainability of livelihoods and regional economies throughout the world. However, in South Africa, groundwater still remains a poorly managed resource and this hinders socio-economic development. This paper examines the current state of ground water management in South Africa. The paper also examines how ground water in South Africa is currently allocated and used, and explores some of the consequences of current water management arrangements. {List only- not presented}
Development of United Nations Framework Classification for Resources (UNFC) for Groundwater Resources Management	Peter	van der Keur	2023	SDGs, UNFC, common pool resources, subsurface geo-resources, sustainable groundwater resources management
Abstract There is an urgent need to support the sustainable development of groundwater resources, which are under increasing pressure from competing uses of subsurface geo-resources, compounded by land use and climate change impacts. Management of groundwater resources is crucial for enabling the green transition and attaining the Sustainable Development Goals. The United Nations Framework Classification for Resources (UNFC) is a project-based classification system for defining the environmental-socio-economic viability and technical feasibility of projects to develop resources and recently extended for groundwater. UNFC provides a consistent framework to describe the level of confidence in groundwater resources by the project and is designed to meet the needs of applications pertaining to (i) Policy formulation based on geo-resource studies, (ii) Geo-resource management functions, (iii) Business processes; and (iv) Financial capital allocation. To extend use in groundwater resources management, supplemental specifications have been developed for the UNFC that provide technical guidance to the community of groundwater professionals to enhance sustainable resource management based on improved decision-making. This includes addressing barriers to sustainably exploiting groundwater resources, avoiding lack of access to water and also related to ‘common pool resources’ in which multiple allocations are competing with domestic water supply (e.g. geo-energy, minerals, agriculture and ecosystems, and transboundary allocation of natural resources). UNFC for groundwater resources is designed to enhance governance to protect the environment and traditional users while ensuring socio-economic benefits to society. Consequently, it is a valid and promising tool for assessing both the sustainability and feasibility of groundwater management at local, national and international levels.
Water resource management in tectonically active volcanic regions: Towards an in-depth understanding of Mt. Fuji’s hydrogeology	Stephanie	Musy	2023	SW-GW interactions; tracers; modelling
Abstract Mt. Fuji is the iconic centrepiece of a large, tectonically active volcanic watershed (100 km2 ), which plays a vital role in supplying safe drinking water to millions of people through groundwater and numerous freshwater springs. Situated at the top of the sole known continental triple-trench junction, the Fuji watershed experiences significant tectonic instability and pictures complex geology. Recently, the conventional understanding of Mt. Fuji catchment being conceptually simple, laminar groundwater flow system with three isolated aquifers was challenged: the combined use of noble gases, vanadium, and microbial eDNA as measured in different waters around Fuji revealed the presence of substantial deep groundwater water upwelling along Japan’s tectonically most active fault system, the Fujikawa Kako Fault Zone [1]. These findings call for even deeper investigations of the hydrogeology and the mixing dynamics within large-scale volcanic watersheds, typically characterized by complex geologies and extensive networks of fractures and faults. In our current study, we approach these questions by integrating existing and emerging methodologies, such as continuous, high-resolution monitoring of dissolved gases (GE-MIMS [2]) and microbes [3], eDNA, trace elements, and integrated 3-D hydrogeological modelling [4]. The collected tracer time series and hydraulic and seismic observations are used to develop an integrated SW-GW flow model of the Mt. Fuji watershed. Climate change projections will further inform predictive modelling and facilitate the design of resilient and sustainable water resource management strategies in tectonically active volcanic regions
A Decision Support System to Assess Climate Change Impacts on Rural Communities	Musiiwa	Luruli	2015
Abstract Climate change contributes to the way in which people live. Natural resources such as groundwater, wood and surface water form a great part of livelihood in rural communities and are used extensively in rural areas where basic services have not yet been provided. The effect of climate change to all these natural resource may impact the lives of those in rural communities. Climate change is already starting to affect some of the poor and most vulnerable communities around the world. The aim of the dissertation is to develop a framework to assess the vulnerability of rural communities to climate change, with a specific focus groundwater and issues relating to gender. A questionnaire and interviews were used to collect data about rural communities' level of awareness climate change, their attitudes toward coping with climate change impact, level of education, income scale and how does this affect their security. Hyrodocensus was taken around the village to determine the rivers, dams, boreholes, abandoned boreholes and wells. Water samples were collected and analysed. The response rate was higher in females than in male's stakeholders (54% vs 46%).the results show that woman were mostly doing the hard work to complete daily basic activities. Education was found to be of high school level and incomes were low. The framework was developed with basic need showed that the area was at risk of poverty .Boreholes was found and water quality was analysed to be adequate for drinking water purpose. More information will be discussed on presentation.
Geochemical Simulation of Drain Water Quality in Gold Tailings	Terry R	Harck	2017	geochemistry, modelling
Abstract This paper presents data obtained from sampling and geochemical analysis of gold tailings and associated pool and drain water. Inverse geochemical modelling using PHREEQC indicated geochemical processes operating in the tailings between the pool and drains. These included pyrite oxidation and dissolution of various minerals identified in the tailings. The processes were incorporated into an ensemble geochemical model to calculate post-closure sulphate concentration in tailings seepage. The ensemble model included a spreadsheet model to calculate oxygen flux at various depths in the tailings column, and a one-dimensional transport model in PHREEQC. The calculated oxygen flux was applied to each cell in the tailings column to determine the amount of sulphide oxidation and the release of acidity into the tailings pore water. The rate of vertical transport of pore water in the column was determined from physical characterisation of the tailings particle size and saturated hydraulic conductivity. The model results indicate elevated sulphate concentrations and acidity moving as a front from the top of the column downwards. The modelled sulphate concentration of 1 500 to 1 900 mg/L 8-16 years after closure compared well with measurements of drain water quality at a tailings dam decommissioned approximately 16 years ago. This provided some credibility to the modelled result of 2 300 mg/L sulphate up to 50 years post-closure. However, the tailings moisture content, infiltration rate, and pyrite oxidation rate in the model were based on literature values, rather than site-specific measurements.
Practical Solutions for Academic Based Applications – Understanding the importance of correct aquifer test data interpretations	Jorette	Van Rooyen	2021	Gw-Sw interaction, test-pumping, FC, Monitoring
Abstract It has become increasingly apparent that understanding fractured rock mechanics as well as the interactions and exchanges between groundwater and surface water systems are crucial considering the increase in demand of each in recent years. Especially in a time where long term sustainability is of great importance for many water management agencies, groundwater professionals and the average water users. Previous callow experience has shown that there is a misunderstanding in the correct interpretation and analyses of pumping test data. The fracture characterisation (FC) method software provides a most useful tool in the overall understanding of a fractured rock aquifer, quantification of the aquifer’s hydraulic (flow regime and flow boundary conditions) and physical properties, only if the time-drawdown relationships are correctly interpreted and when the theoretical application principles are applied. Interpretation is not simply a copy and paste of the aquifer test data into the software to get a quick answer (especially when project time constraints are considered), however, recent experiences with numerous field examples, required intricate understanding of the geological environment, intended use and abstraction schedules coupled with the academic applications on which the software was based for correct interpretation. Through the application of correct interpretation principles, a plethora of flow information becomes available, of which examples will be provided in the presentation itself. By achieving this, flow can be conceptualised for inputs into a conservative scale three-dimensional numerical flow model and calibrated based on measurable data in a fraction of the time of a conventional regional model. Although higher confidence levels are achieved with these practical solutions, monitoring programmes are still required to provide better insight of the aquifer responses to long-term abstraction and recovery.
A fresh look at the National Water Balance	Andries	Wilke	2015
Abstract The national water balance is primarily based on the availability of surface water and the historic allocation thereof. The changes that are required the next 20 years to ensure sustainable development of the nation will be painful, but is unfortunately at present not part of the public discussion, it is essentially ignored in favour of more "popular water topics".This paper intends to look at a few core aspects, they include the current water allocation in the national water balance, the relative value of the utilisation, the position of groundwater resources in changing the current relative allocation and the current groundwater utilisation. The paper further intends to be a less formal presentation of these aspects with the required data, references and conclusions available for distribution afterwards.
Building Of A Gravity Lysimeter To Represent An Ash Backfilled Opencast Coal Mine.	Kamohelo	Mokoena	2019	Poster, Lysimeter, coal mine
Abstract Millions of tons of coal ash are produced across the globe, during coal combustion for power generation. South Africa relies largely on coal for electricity generation. The current disposal methods of coal ash are not sustainable, due to landfill space limitations and operational costs. One way/means of disposing of coal ash that could provide environmental and financial benefits; is to backfill opencast mines with the ash. However, a limited number of studies have been conducted to assess the feasibility of this method in South Africa. Thus the aim of the experiment is to monitor bulk ash disposal under field conditions to improve the understanding of the geochemical and hydrogeological processes occurring during the actual deposition of coal ash in opencast coal mines. To achieve the aim (1) a gravity lysimeter will be built containing both mine spoils and coal ash representing field conditions; (2) the factors (CO2, water level and moisture content) affecting acid mine drainage will be monitored in the lysimeter and (3) the change in the quantity and quality of the discharge released from the lysimeter.
Study on the Relationship between Water Quality and Wetland Plant Community in Huixian Karst Wetland	L	Shen	2023	Huixian Karst Wetland, Water quality, Wetland Plant Community
Abstract Huixian Karst National Wetland Park is the most typical karst wetland in the middle and low latitudes of the world and has become an internationally important wetland. The relationship between water quality and aquatic organisms in Huixian Wetland is a hot research topic in wetland ecology. This article focuses on the relationship between the current water quality situation in Guilin Huixian Karst Wetland and the growth of wetland plants. Sixteen sampling points are set up in the wetland to monitor and analyze water quality in wet, normal, and dry seasons. The Kriging index interpolation method is used to obtain a comprehensive water quality interpolation map in the survey area during normal water periods and in combination with the wetland plant survey sample data and the landscape status. A comprehensive analysis of the relationship between wetland plant growth and water quality. The results show that the centre of Huixian Wetland receives recharge from surrounding groundwater, which is greatly affected by the surrounding water quality. The comprehensive water quality is relatively good in the dry season, relatively poor in the normal season, and the worst in the wet season. Agricultural production, non-point source pollution, rural domestic sewage, and human interference affect wetland water quality, which directly affects the structure and function of plant communities and the ecological service function of wetlands.
Physico-Chemical Assessment of Groundwater in the Orange Water Management Area	Olma Tsakani	Makonto	2015
Abstract The groundwater quality of the Orange Water Management Area (OWMA) was assessed to determine the current groundwater status. Groundwater is of major importance in the Orange Basin and constitutes the only source of water over large areas. Groundwater in the OWMA is mainly used for domestic supply, stock watering, irrigation, and mining activities. Increase in mining and agricultural activities place a demand for the assessment of groundwater quality. The groundwater quality was assessed by collecting groundwater samples from farm boreholes, household boreholes, and mine boreholes. Physical parameters such as pH, temperature and Electrical Conductivity (EC) were measured in-situ using an Aquameter instrument. The groundwater chemistry of samples were analysed using Inductively Coupled Plasma Mass Spectrometry, Ion Chromatography, and Spectrophotometer for cations, anions and alkalinity respectively. The analyses were done at Council for Geoscience laboratory. The results obtained indicated high concentration of Nitrate (NO3), EC, sulphate (SO4), Iron (Fe), and dissolved metals (Chromium, Nickel, Copper, Zinc, and Lead). The concentrations were higher than the South African National Standards (SANS) 241 (2006) drinking water required guideline. The OWMA is characterised by the rocks of the Karoo Supergroup, Ventersdorp Supergroup, Transvaal Supergroup, Namaqua and Natal Metamorphic Province, Gariep Supergroup, and Kalahari Group. Groundwater is found in the sandstones of the Beaufort Group. Salt Mining occurs in the Namaqua Group, hence the high concentration of EC observed. High EC was also found in the Dwyka Group. The salt obtained from the pans underlain by the Dwyka Group rocks has relatively high sodium sulphate content, this probably results from oxidation of iron sulphate to sulphate. Therefore, high concentration of SO4 is due to the geology of the area. High concentration of NO3 is due to agricultural activities, whereas high concentration of EC, Fe, SO4 and dissolved metals is due to mining activities.
Dewatering Impacts of a South African Underground Coal Mine	Paul JH	Lourens	2017	coal mine, hydrocensus, dolerite contact zones, Monitoring, over-abstraction
Abstract The University of the Free State investigated the possible dewatering of boreholes situated on the farm properties in the vicinity of an underground coal mine. The investigation consisted of three phases. Phase one was a hydrocensus on the farm properties. Phase two consisted of borehole yield determination by conducting pumping tests on the boreholes (where possible) identified in the hydrocensus phase. Phase three included a visit to the underground mine workings, where water samples were collected at different groundwater inflow locations (especially water flowing in at the ventilation shaft). The monthly groundwater monitoring data of the underground coal mine was also incorporated for interpretation purposes. It appears that the water levels of the boreholes outside the mining boundaries are not affected. The water levels of the monthly monitored boreholes stabilized or even started recovering over the last few years. It also seems as though the larger streams in the area drains the groundwater as most of the deeper water level areas coincides with the presence of the streams. Most of the boreholes have typical borehole yields that is to be expected from Karoo formations i.e. between 0.5 and 1.5 L/s. An interesting observation is that a number of the boreholes with deep water levels are situated along dolerite contact zones at the western side of the mine. This may also be a geological structure resulting from the impact of a meteorite? From the available data it appears that the boreholes along this structure have the same chemical character as the water flowing down the ventilation shaft, strengthening the belief that the water from the shaft originates from this structure (or structures). To determine the origin of the water flowing down the ventilation shaft, a detailed study of the structure to the west of the shaft is recommended. The farmers in the area should carefully monitor their water use in the boreholes, as over-abstraction can result in total failure of some of the boreholes.
The Management of Groundwater resources using GIS/Cartography splay)	Freda	Jonck	2015
Abstract The Department of Water Affairs and Sanitation is the custodian of the Water Resource in South Africa. The Western Cape Regional Office, Geotechnical Service Sub Directorate, is responsible for management of groundwater resources in two Water Management Areas (WMA), Olifants Doorn-Berg and Breede-Gouritz. Twenty-nine monitoring routes comprising 800 sites in total are monitored across the Western Cape Region. The purpose of this paper is to create awareness of groundwater related databases and the type of information products used in assessing the status of data bases and groundwater resources. This is to assist and support the scientists, technicians, managers, external stakeholders and/or general public. The main question that needs to be answer is: "What is the current groundwater data management situation in the Regional office?" With the GIS as platform, geographical information was generated from existing data bases to answer questions such as, what is being monitored, where is it being monitored, who is monitoring it, why is it being monitored and when is it being monitored? These questions are applicable to the Region, Water Management Areas, the monitoring route and geosites. Graphical time-series information generated from available data, in combination with the generated geographical information, showed the gaps, hot spots and what is still needed for all the facets of groundwater management (from data acquisition to information dissemination) processes. The result showed the status of data bases, need for data in areas of possible neglect, training gaps, inadequate structure and capacity, instrumentation challenges, need for improvement of commitment and discipline, as well as many other issues. The information generated proves to be an easy tool for Scientists, Technicians and Data Administrators to assist them to be on top of the groundwater resource management in their area of responsibility. The expansion of the use of GIS as a groundwater management tool is highly recommended. This will ensure better understanding of the resource: "The Hidden Treasure".
Reliability of laboratory testing of groundwater samples	Venetia	Mitchell	2015
Abstract Resources required for groundwater sampling includes but not limited to pumping equipment, trained manpower and technical resources specific to the sampling function. Bearing these expenses in mind, choosing a laboratory for testing the water samples collected should be a carefully considered purchase. Choosing a testing facility that cannot deliver an efficient, reliable and technically sound service could render the sampling futile. Water samples submitted to a laboratory for testing are received from third party sources more than ninety percent (90%) of the time and sampling techniques and sample integrity cannot be verified by the laboratory. However, the validity, reliability and integrity of the laboratory testing are within the control of the testing facility. These aspects of a laboratory are usually controlled within a quality management system where established policies and procedures form the basis of such a system. This system maintains a foundation for technical competence and customer service at the laboratory. There are numerous testing facilities available to Consultants requiring chemical and microbiological groundwater testing, each with varying levels of integrity and technical ability. It is imperative to maintain confidence in the validity of results of analyses from a laboratory and this assurance can be understood through an examination of a facility's management system. An established quality management system would comprise a policy statement, associated technical methods and technical and administrative procedures. This system would be formally documented and audited as part of the on-going laboratory's management system. In some instances, laboratories formalise this into an accreditation of the laboratory to an international standard, such as ISO 17025:2005. The assurance that the results of analyses from any laboratory are of sound technical integrity would depend on factors such as - personnel training, - accommodation and environmental conditions under which the tests are carried out, - validation of the methodology applied (including the uncertainty of measurement), - the calibration and maintenance of the equipment used, - understanding the traceability of and measurement undertaken, - handling and preservation of the sample on receipt and while in the laboratory. Each of these factors plays a critical role in the integrity of results of analyses and should be interrogated when trying to understand the reliability and competence of the laboratory of choice.{List only- not presented}
Geochemical Behaviour Of Arsenic In Contact With Dolomite	Johan	Fourie	2017	Arsenic, geochemical, dolomites
Abstract Arsenic is a common contaminant typically found in effluent from gold mine operations and copper smelters throughout the world. The geochemical behaviour of arsenic in contact with dolomite underlying an arsenic containing waste rock pile was investigated. The interaction between the arsenic and the dolomite is an important control in the subsequent transport of the arsenic in the dolomitic aquifer. Rocks with varying dolomite content were tested to investigate the interaction between the arsenic and dolomite. From the modelling and test results it was estimated that in the aquifer, between 60 - 90% of arsenic is present in the solid phase under oxidation conditions at >50 mV. At 50 to -25 mV about 40 - 60% of the arsenic is estimated to be present in the solid phase and below -25 mV about 0 - 10% of arsenic will be present in the solid phase. Although some arsenic is removed by the dolomite in the aquifer the arsenic would still be present above acceptable guidelines for drinking water. The arsenic in the solid phase will be in equilibrium with the aquifer water and could be remobilised 1) under more reducing conditions or 2) with a decrease in arsenic in the aquifer.
GIS-PMWIN, A Preprocessor In ArcGIS For Groundwater Modeling With PMWIN	Haili	Jia	2015
Abstract PMWIN5.3 has been one of the most commonly used software for groundwater modeling because of its free source and the adoption of popular core program MODFLOW. However, the fixed formats required for data input and lack of GIS data support have posted big challenges for groundwater modelers who are dealing with large areas with complicated hydrogeological conditions. In South Africa, most geological and hydrogeological data have been captured and stored in GIS format during various national research projects such as WR2005, NGA and etc. Therefore, a proper linkage between PMWIN and ArcGIS is expected to do the preprocessing for modeling in PMWIN. Visual Basic for Application (VBA) embedded in ArcGIS 9.3 was used to develop the linkage. Based on the conceptualization of the study area, the model dimension, discretization and many value setting processes can be easily carried out in ArcGIS other than directly in PMWIN. Then the grid specification file and other input files can be exported as the PMWIN-compatible files. The functions of move, rotation, refinement, sub-model, deleting and inserting row(s) or column(s) of the model have also been developed to avoid the inconvenience aroused from model modification. The linkage can be used with a higher version of PMWIN or ArcGIS. It has been applied to several gold fields in the Witwatersrand gold basin to simulate the groundwater flow and mass transportation for various conditions and scenarios. One of the applications will be presented in this paper. It has been proved that the linkage is efficient and easy to use. {List only- not presented}
The Roussillon coastal aquifer: using multiple-point statistics and multi-model ensemble to characterize geological uncertainty impact on water resources estimation	Valentin	Dall’ Alba	2023	Coastal aquifer, Groundwater Modelling, Multi-model ensemble, Uncertainty analysis
Abstract Coastal groundwater is a vulnerable resource, estimated to sustain the water needs of about 40% of the world’s population. The Roussillon aquifer is a regional aquifer near Perpignan (southern France). It covers over 800 km2 of land and is used for irrigation, drinking water, and industrial purposes. The aquifer has experienced significant piezometric lowering in the last decades, weakening the regional resource. An important aspect of modelling the hydrodynamic of this aquifer is the need to integrate data from agriculture and drinking water abstraction, natural and anthropogenic recharge, and account for the aquifer’s complex sedimentary arrangement. An ensemble of groundwater models has been constructed to understand the spatial evolution of the saline/freshwater interface and evaluate the impact of groundwater abstraction. Three sets of physical parameter modelling approaches were used. The first is based on the direct interpolation of pumping tests. The second uses sequential indicator simulations to represent the geological uncertainty. The third is based on a detailed conceptual geological model and multiple-point statistics to represent the detailed geological structure. These models provide parameter fields that can be input for the transient state hydrodynamic simulations. Overall, the ensemble approach allowed us to understand the Roussillon plain’s hydrological system better and quantify the uncertainty on the possible evolution of the main groundwater fluxes and water resources over the last 20 years. These models can help to inform management decisions and support sustainable water resource development in the region.
Problematic modelling and setting compliance values for contaminated groundwater in fractured rock aquifers -South Africa	Morne	Burger	2015	industrial risk, contamination
Abstract Industrial Management Facilities represent a hazard to the down gradient surface water and groundwater environment. The assessment of the risks such facilities pose to the water environment is an important issue and certain compliance standards are set by regulators, particularly when the potential for an impact on the water environment has been identified. This paper will aim to describe how the contamination was conceptualized, estimated, limitations and how it is technically not feasible to establish one limit or compliance value of known contamination in different aquifers.
Hydrogeochemical processes in the shallow aquifer of the Lubumbashi river basin: multivariate statistical approach	Antoine	Lumu Moussa	2015
Abstract Understanding the hydrogeochemical processes that govern groundwater quality is important for sustainable management of the water resource. A study with the objective of identifying the hydrogeochemical processes and their relation with existing quality of groundwater was carried processes in the shallow aquifer of the Lubumbashi river basin. The study approach includes conventional graphical plots and multivariate analysis of the hydrochemical data to define the geochemical evaluation of aquifer system based on the ionic constituents, water types, hydrochemical facies and groundwater factors quality control. Water presents a spatial variability of chemical facies (HCO3- - Ca2+ - Mg2+, Cl- - Na+ + K+, Cl- - Ca2+ - Mg2+ , HCO3- - Na+ + K+ ) which is in relation to their interaction with the geological formation of the basin. The results suggest that different natural hydrogeochemical processes like simple dissolution, mixing, and ion exchange are the key factors. Limited reverse ion exchange has been noticed at few locations of the study. At most, factor analyses substantiate the findings of conventional graphical plots and provide greater confidence in data-interpretation. {List only- not presented}
Establishing A Groundwater Baseline For Unconventional Gas Projects In South Africa	M	Lourens	2017	Unconventional gas, hydraulic fracturing, Methodology, geological structures, baseline, Fracking
Abstract A standard methodology for establishing a groundwater baseline for unconventional gas projects in South Africa did not exist at the time the current study was undertaken. The study was therefore aimed at filling this gap, specifically focusing on hydraulic fracturing and underground coal gasification (UCG) operations. An extensive literature review was conducted to establish the baseline methodology. The latest literature on hydraulic fracturing and UCG was reviewed to determine how these activities may potentially impact on the groundwater environment. The literature review further examined the role that geological structures, such as dolerite intrusives, may be play in the migration of contaminants associated with unconventional gas projects. The literature review then focused on questions such as what size the study area should be, what geological and hydrogeological investigations need to be conducted before embarking on the sampling events, which chemical parameters need to be included in the groundwater analyses, whether the drilling of dedicated boreholes are required to collect representative groundwater samples, and how to collect representative samples for these different chemical parameters. In this paper, the proposed methodology is presented in the form of a flow diagram to be used to guide future groundwater baseline projects in South Africa.
Integrated Modelling: A Tool For Urban Groundwater Management On The Cape Flats, Cape Town	Benjamin	Mauck	2015
Abstract There is growing concern that South Africa's urban centres are becoming increasingly vulnerable to water scarcity due to stressed surface water resources, rapid urbanisation, climate change and increasing demand for water. Given South Africa's water scarcity, global trends for sustainable development, and awareness around the issues of environmental degradation and climate change, there is a need to consider alternative water management strategies. Water Sensitive Urban Design (WSUD) is an approach to sustainable urban water management that attempts to achieve the goal of a 'Water Sensitive City'. The concept of a Water Sensitive City seeks to ensure the sustainable management of water using a range of approaches such as the reuse of water (stormwater and wastewater), exploiting alternative available sources of supply, sustainable stormwater management and improving the resource value of urban water through aesthetic and recreational appeal. Therefore, WSUD attempts to assign a resource value to all forms of water in the urban context, viz. stormwater, wastewater, potable water and groundwater. However, groundwater is often the least considered because it is a hidden resource, often overlooked as a form a water supply (potable and non-potable) and it is often poorly protected. The management of urban groundwater and understanding the impacts of WSUD on groundwater in South African cities is challenging, due to complex geology, ambiguous groundwater regulations and management, data limitations, and lack of capacity. Thus, there is a need for an approach to assess the feasibility of management strategies such as WSUD, so that the potential opportunities and impacts can be quantified and used to inform the decision making process. An integrated modelling approach, incorporating both surface and subsurface hydrological processes, allows various urban water management strategies to be tested due to the complete representation of the hydrological cycle. This integration is important as WSUD is used to manage surface water, but WSUD known to utilise groundwater as a means of treatment and storage. This paper assesses the application, calibration and testing of the integrated model, MIKE SHE, and examines the complexities and value of establishing an integrated groundwater and surface water model for urban applications in South Africa. The paper serves to demonstrate the value of the application of MIKE SHE and integrated modelling for urban applications in a South African context and to test the models performance in Cape Town's unique conditions, accounting for a semi-arid climate, complex land use, variable topography and data limitations. Furthermore, this paper illustrates the value of integrated modelling as a management tool for assessing the implementation of WSUD strategies on the Cape Flats, helping identifying potential impacts of WSUD interventions on groundwater and the potential opportunities for groundwater to contribute towards ensuring to Cape Town's water security into the future.
Management of water-related risks in drinking water supplies	Barbara	Cencur Curk	2023	risk analysis, water-related hazards, water safety plan, water supply system
Abstract With the revision of the European Drinking Water Directive (Directive on the quality of water intended for human consumption 2020/2184) in December 2020, the preparation of Water Safety Plans (WSP) is foreseen according to the guidelines of WHO. Within the EU Interreg Adrion MUHA project, a decision support tool (DST) has been developed to provide a holistic approach to drinking water infrastructure risk analysis. The project mainly addresses four water-related risks: accidental pollution, floods, droughts and earthquakes. The core of the DST is the inventory of hazardous events (causes, their consequences and impacts) for each component of the drinking water supply chain: (1) drinking water source - catchment area, (2) water supply system, and (3) domestic distribution system. For each identified potential hazard, the type of hazard was determined (e.g., biological, chemical, radiological, or physical hazard (including turbidity), inadequate availability of water supplied to customers, safety to personnel, external harm to third parties, including liability). The DST was tested in the partner countries (Italy, Slovenia, Croatia, Serbia, Montenegro and Greece) to verify the resilience of the measures and elaborate the WSP. In the end, the REWAS-ADRION strategy was elaborated, aiming to increase the resilience of drinking water supplies to floods, droughts, accidental pollution, and earthquake-related failures by improving the water safety planning mechanism based on the concept of inter-agency cooperation to support water utilities, civil protection organizations, and water authorities.
A predictive study to better protect groundwater at Underground Coal Gasification site	Venessa	Aphane	2015	underground coal gasification
Abstract Underground coal gasification (UCG) is considered a cleaner energy source as its known effect on the environment is minimal; it is cheaper and a lesser contributor to greenhouse gas emissions when compared to conventional coal mining. It has various potential impacts but the subsidence of the surface as well as the potential groundwater contamination is the biggest concerns. Subsidence caused by UCG processes will impact on the groundwater flow and levels due to potential artificial groundwater recharge. The geochemistry of the gasifier is strongly depended upon site specific conditions such as coal composition/type and groundwater chemistry. Independent of the coal rank, the most characteristic organic components of the condensates is phenols, naphthalene and benzene. In the selection of inorganic constituents, ammonia, sulphates and selected metals and metalloids such as mercury, arsenic, and selenium, are identified as the dominant environmental phases. The constituents of concern are generated during the pyrolysis and after gasification as dispersion and penetration of the pyrolysis take place, emission and dispersion of gas products, migration by leaching and penetration of groundwater. A laboratory-based predictive study was conducted using a high pressure thermimetric gasification analyser (HPTGA) to simulate UCG processes where syngas is produced. The HPTGA allows for simulation of the actual operational gasifier pressure on the coal seam and the use of the groundwater sample consumed during gasification. A gasification residue was produced by gasifying the coal sample at 800 °C temperature and by using air as the input gas. The gasification residue was leached using the high temperature experimental leaching procedure to identify the soluble phases of the gasified sample. The leachate analysis is used to determine the proportion of constituents present after gasification which will be removed by leaching as it is exposed to external forces and how it will affect the environment. The loading to groundwater for the whole gasifier is then determined by applying the leachate chemistry and rock-water ratio to the gasifier mine plan and volumes of coal consumed.
A methodology for uncertainty quantification of dewatering volumes under the context of open-cast mining	C	Rivera Villarreyes	2023	FEFLOW, Groundwater Modelling, mining, PEST, PESTPP
Abstract Groundwater modelling at the mine sites involves assumptions from the geological model, mining stages, parametrization, and fractures, among others. Modelling work mainly focuses on calibrating against historical measurements before operations (pre-mining) or afterwards (transient calibration). Calibration is carried out mainly with gradient-based algorithms. However, the majorlimitation is the number of model runs, since the number of parameters can easily reach hundreds or more. PEST has become the common tool for parameter estimation. The Jacobin calculation required for the Levenberg Marquardt algorithm requires several model runs. This, a limited factor for the calibration and, subsequently, uncertainty quantification. The next generation of PEST, named PESTPP, is gained popularity in the groundwater community. The great advantage of PESTPP,, compared to the classical PEST, is its new module, Iterative Ensemble Smoother (IES). PESTPP-IES covers both parameter estimation and uncertainty quantification in one goal. Its empirical formulation of the Jacobian matrix reduces the number of runs; thus, the numerical bottleneck can be significantly reduced. PESTPP-IES has been extensively tested in an open-pit mine at the geological complex conditions in the Peruvian Andes. The work involves the task of model simplification, e.g., from a regional model to a detailed local pit model, calibration and uncertainty quantification of pit dewatering volumes. Detailed model was kept calibrated based on hydraulic-head measurements, and dewatering volumes were predicted. All these consider transient changes in the mining plan within the same FEFLOW model. Results validate the methodology and practicability in mining applications.
Groundwater and Surface Water Interaction Study for the Ingula Wetland	Christie	Terrell	2015
Abstract The Bedford Dam is the upper storage dam for the Ingula Pumped Storage Scheme and is situated in the Ingula/Bedford Wetland. This wetland has a high structural diversity which supports a unique assemblage of plants and invertebrates. The flow regulation and water purification value is of particular importance as the wetland falls within the Greater Vaal River catchment. Concern was raised with respect to the potential negative impact of the newly constructed dam on the dynamic water balance within the wetland. An assessment of the extent to which groundwater drives / sustains the wetland systems and the water requirements needed to sustain the wetland processes was determined. This includes establishing the impact of the Bedford Dam on the groundwater and wetland systems as well as providing recommendations on management and monitoring requirements. The hydropedological interpretations of the soils within the study area indicate that baseflow to the wetland is maintained through perennial groundwater, mainly recharged from infiltration on the plateau, and was confirmed through isotope sampling and hydrometric measurements. It is apparent that the surface flows in the main wetland are fed by recent sources, while the subsurface layers in the wetland are sustained by the slower moving near-surface and bedrock groundwater. The movement of groundwater towards the wetland is hindered by the numerous dykes creating a barrier to flow. Nevertheless, there seems to be a good connection between the groundwater sources in the upland and the surface drainage features that conduct this water to the contributing hillslopes adjacent to the main wetland. The surface flows of the main wetland are sustained by contributions from tributary fingers. The discharge out of the wetland is highly seasonal
Hydrogeochemical processes in the shallow aquifer of the Lubumbashi river basin: multivariate statistical approach	Lumu	Moussa Antoine	2015
Abstract Understanding the hydrogeochemical processes that govern groundwater quality is important for sustainable management of the water resource. A study with the objective of identifying the hydrogeochemical processes and their relation with existing quality of groundwater was carried processes in the shallow aquifer of the Lubumbashi river basin. The multivariate statistical approach includes self organizing maps (SOM'S) of neural networks, hierarchical cluster (HCA) and principal component analysis of the hydrochemical data were used to define the geochemical evaluation of aquifer system based on the ionic constituents, water types, hydrochemical facies and groundwater factors quality control. Water presents a spatial variability of chemical facies (HCO3- - Ca2+ - Mg2+, Cl- - Na+ + K+, Cl- - Ca2+ - Mg2+ , HCO3- - Na+ + K+ ) which is in relation to their interaction with the geological formation of the basin. The results suggests that different natural hydrogeochemical processes like simple dissolution, mixing, weathering of carbonate minerals and of silicate weathering and ion exchange are the key factors. Added to this is the imprint of anthropogenic input (use of fertilizers, septic practice poorly designed and uncontrolled urban discharges). Limited reverse ion exchange has been noticed at few locations of the study.
The importance of rainfall data in water resource planning and risk management	Nicolette	Vermaak	2015	rainfall data
Abstract Water resource management and risk management rely heavily on the availability of data and information. This includes the volumes of water needed, the volumes of water available, where the available water is and where it would be needed, etc. Historical records help to determine past use and gives a way to predict future use in the case of water resource planning while it helps to predict the possibility of floods and droughts when it comes to risk management. Rainfall data can provide valuable data for both water resource planning and risk management, since it is the input to the hydrologicalcycle. It is possible to determine dry and wet cycles using the cumulative deviation from mean that is calculated from the measured rainfall data. This was done for the Gnangara Mound in Australia, with the results giving a fair representation of the dry and wet cycles in the area. Data measured over a period of about 30 years for the Zachariashoek sub-catchment analyzed in the same fashion provided wet-dry cycles of about 8 years. The rainfall measurements had been taken at various settings around the catchment, and varied from place to place and differed from that measured at the WeatherSA stations in the vicinity. This article will draw a comparison between the Zachariashoek data and the WeatherSA data to determine whether the WeatherSA data followed the same patterns for the wet-dry cycles observed in Zachriashoek. It will then analyse the longer data record available for the WeatherSA data from 1920 to 2012. It is expected that the shorter wet-dry cycles seen in Zachariashoek will become part of longer wet-dry cycles that can be used in water resource planning and risk management. Rainfall is also dependent on a number of factors
Variability In Borehole Responses During Yield Testing: Case Studies Deviating From Ideal Drawdown Curves.	Reuben	Lazarus	2019	yield-testing, theory vs practice, realistic aquifers
Abstract The expectation that during yield tests, a borehole will react within the expected framework of the existing numerical models, is often not met within real-world scenarios. This is mainly due to the observation that the Theis solution for confined aquifers, Neuman solution for unconfined aquifer and Barker Generalised Radial Flow Model for hydraulic tests in fractured rocks all include idealised assumptions regarding the physical aspects of a hypothetical. In order to interpret the data from a yield test these methods, along with the Flow Characteristic method for sustainable yield estimates, are commonly used. However, as these assumptions are not always met, the analysis is usually focused on time periods within the test that approximate these solutions. In some cases, the extent to which these assumptions are not met can produce drawdown data that is not well described by the usual analytical models used to analyse this data. This study addresses some of the shortcomings experienced during testing in non-ideal aquifers, as well as briefly describing some tests where small budgets, short deadlines, a lack of information and/or unforeseen circumstances resulted in similar challenges to analyses. This study does not present new solutions to drawdown data analyses, but rather discusses how the mentioned solutions were used during testing to accommodate for the shortcomings experienced.
OFF-SOURCE: A network to address the potential use of offshore freshened groundwater as an unconventional source of potable water in coastal cities.	H	Wazaz	2023	Offshore groundwater, COST Action, scientific networking, unconventional water resources, Transboundary aquifer
Abstract One-third of the world faces water insecurity, and freshwater resources in coastal regions are under enormous stress due to population growth, pollution, climate change and political conflicts. Meanwhile, several aquifers in coastal regions extending offshore remain unexplored. Interdisciplinary researchers from 33 countries joined their effort to understand better if and how offshore freshened groundwater (OFG) can be used as a source of potable water. This scientific network intends to 1) estimate where OFG is present and in which volumes, 2) delineate the most appropriate approaches to characterise it, and 3) investigate the legal implications of sustainable exploitation of the offshore extension of transboundary aquifers. Besides identifying the environmental impact of OFG pumping, the network will review existing policies for onshore aquifers to outline recommendations for policies, action plans, protocols and legislation for OFG exploitation at the local to international levels. Experienced and early-career scientists and stakeholders from diverse disciplines carry out these activities. The Action leads activities to foster cross-disciplinary and intersectoral collaboration and provides high-quality training and funded scientific exchange missions to develop a pool of experts to address future scientific, societal, and legal challenges related to OFG. This interaction will foster new ideas and concepts that will lead to OFG characterisation and utilisation breakthroughs, translate into future market applications, and deliver recommendations to support effective water resource management. The first exchange mission explored the Gela platform carbonate reservoir (Sicily), built a preliminary 3D geometrical model, and identified the location of freshened groundwater
Groundwater Assessment using Borehole Magnetic Resonance	Benjamin	Birt	2019	magnetic resonance
Abstract Hydraulic behaviour of an aquifer is defined in terms of the volumes of water present, both producible and not (specific yield and specific retention), and the productivity of the water (hydraulic conductivity). These parameters are typically evaluated using pumping tests, which provide zonal average properties, or more rarely on core samples, which provide discrete point measurements. Both methods can be costly and time-consuming, potentially limiting the amount of characterisation that can be conducted on a given project, and a significant measurement scale difference exists between the two. Borehole magnetic resonance has been applied in the oil and gas industry for the evaluation of bound and free fluid volumes, analogous to specific retention and specific yield, and permeability, analogous to hydraulic conductivity, for over twenty years. These quantities are evaluated continuously, allowing for cost-effective characterisation, and at a measurement scale that is intermediate between that of core and pumping tests, providing a convenient framework for the integration of all measurements. The role of borehole magnetic resonance measurements in hydrogeological characterisation is illustrated as part of a larger hydrogeological study of aquifer modeling. Borehole magnetic resonance has been used for aquifer and aquitard identification, and to provide continuous estimates of hydraulic properties. These results have been compared and reconciled with pumping test and core data, considering the scale differences between measurements. Finally, an integrated hydrogeological description of the target rock units has been developed.
Investigation The Effect Of Excess Pumping On The Groundwater Salinity In Semi-Arid Aquifers Using Predicted Future Scenarios	Mohammed	Seyam	2019	Hydrological Modeling, Groundwater Quality, Salinity, Prediction scenario
Abstract The groundwater quality in semi-arid aquifers can be deteriorated very rabidly due to many factors. The most important factor affecting the quality of groundwater quality in Gaza Strip aquifer is the excess pumping that resulting from the high population density in the area. The goal of this study to investigate the future potential deterioration in groundwater salinity using scenario analysis modeling by artificial neural networks (ANN). The ANN model is utilized to predict the groundwater salinity based on three future scenarios of pumping quantities and rates from the Gaza strip aquifer. The results shows that in case the pumping rate remains as the present conditions, chloride concentration will increase rapidly in most areas of the Gaza Strip and the availability of fresh water will decrease in disquieting rates by year 2030. Results proved that groundwater salinity will be improved solely if the pumping rate is reduced by half and it also will be improved considerably if the pumping rate is completely stopped. Based on the results of this study, an urgent calling for developing other drinking water resources to secure the water demand is the most effective solution to decrease the groundwater salinity.
Transport and attenuation of microplastics in saturated sands	Sabastian	Stenzl	2021	Microplastics
Abstract Globally, cumulative plastic production since 1950 is estimated to have reached 2500 Mt of plastic. It is estimated up 60% of this plastic is either resting in landfills or the natural environment, including groundwater settings. Microplastics are small pieces of plastic ranging between 1μm – 5mm in size and have been found in every ecosystem and environment on the planet. Much of the available literature on microplastics is focused on marine environments with few in comparison focused on freshwater environments, and even fewer on groundwater settings. The aim of this study is therefore to investigate the attenuation process responsible for influencing microplastic transport in saturated sands. This research will adapt colloid transport theory and experiments to better understand the movement of microplastics through sandy media. Saturated aquifer conditions will be set up and simulated using modified Darcy column experiments adapted from Freeze & Cherry (1979). Modified microplastics will be injected into the columns as tracers and the effluent concentrations measured by Fourier-transform infrared spectroscopy (FTIR). Breakthrough curves will then be plotted using the effluent concentrations to determine the attachment efficiency (α). It is expected the attachment efficiency will vary by microplastic type and size range. The Ionic strength of the solution flowing through the column and the surface charges of both microplastics and sandy surfaces are likely to influence the degree of attenuation observed. The relationship between different types of microplastics and collector surfaces from a charge perspective and their influence on the degree of attenuation will be evaluated. Given the lack of literature, its ubiquitous presence and postulated effects on human health, this research is significant. Through this research, the transport and attenuation of microplastics through sandy aquifers can be better understood, and in the process inform future research and water resource management.
Integrating reductive dehalogenase enzyme production into reactive transport modelling to simulate chloroethene biodegradation in groundwater pollution plumes	Diego	Di Curzio	2023	Biodegradation; Chloroethenes plume; Reactive Transport Modeling; Enzyme-Based Kinetics; Reductive dehalogenase enzymes; Groundwater
Abstract Degradation of chloroethene in groundwater primarily occurs via microbially-mediated reductive dechlorination (RD). Anaerobic organohalide-respiring bacteria (OHRB) use chloroethenes as electron acceptors to gain energy. They produce reductive dehalogenase enzymes (RDases) to perform this function by transcription of functional genes into mRNA and translation to proteins (metabolic regulation). However, how hydrodynamics and hydrogeochemistry control the metabolic efficiency of OHRB in biodegrading chloroethene is essential for effective bioremediation design yet an under-investigated topic. For this reason, we implemented a virtual experiment (1D reactive transport model) to investigate the effects of site conditions on transcription-translation and, hence, biodegradation processes within chloroethene plumes. In the model, RD was simulated using Enzyme-Based Kinetics, explicitly mimicking the production of RDases via metabolic regulation, calibrated on microcosm experimental data gained from literature. Features of an actual contaminated site (Grindsted, Denmark) were then used to set up the virtual experiment. Here, chloroethene leaked from a former pharmaceutical factory migrates through a sandy aquifer and gets discharged into the Grindsted stream. Preliminary results show that substrate (electron donors) limiting conditions caused by competing electron acceptors and dispersion and high flow rates represent the key factors controlling biodegradation via RDase production.
Estimating Hydraulic Parameters Through The Measurement Of Streaming Potentials	Jemias Clifford	Mazibuko	2019	hydraulic flow
Abstract The hydraulic parameters of heterogeneous aquifers are often estimated by conducting pumping (and recovery) tests during which the drawdown in a borehole intersecting the aquifer is measured over time, and by interpreting the data after making a number of assumptions about the aquifer conditions. The interpreted values of the hydraulic parameters are then considered to be average values that represent the properties of the bulk aquifer without taking into account local heterogeneities and anisotropies. An alternative and more economic approach is to measure streaming potentials in the vicinity of the borehole being tested. The streaming potential method is a non-invasive geophysical method that measures electrical signals generated by groundwater flow in the subsurface through a process known as electrokinetic coupling. This method allows data to be recorded at a high spatial density around the borehole. The interpretation of streaming potential data in terms of aquifer hydraulic parameters is facilitated by a coupled flow relationship which links the streaming potential gradient to the hydraulic gradient through a constant of proportionality called the electrokinetic coupling coefficient. In the current study, field measurements of streaming potentials were taken during the pumping and recovery phases of pumping tests conducted at two sites with dissimilar geological and geohydrological conditions. The recorded streaming potential data were interpreted by calculating the hydraulic head gradient from the streaming potential gradient, and by using the potential field analytical solution for the transient mode, which relates the streaming potential field directly to the average hydraulic conductivity. Hydraulic conductivity values estimated from the streaming potential method were of the same order as values determined from the analysis of drawdown data, with a relative error of 0.2. This study demonstrates that the streaming potential method is a viable tool to compliment pumping tests and provide a spatial representation of the hydraulic parameters.
Integrated System Approach To Evaluate Natural Processes And Hydrodynamics Linked To Groundwater-Surface Water Interaction	Teboho	Shakhane	2015
Abstract This study was aimed at developing an integrated groundwater-surface water interaction (GSI) model for a selected stretch of the Modder River by considering the following five different aspects of the GSI: 1) the distribution of different aquifer systems (structural connectivity) along the river 2) the hydraulic connectivity between the aquifer systems, 3) the volumes of water abstracted from the aquifers by streamside vegetation, 4) the volumes of water replenished to the groundwater system through rainfall recharge, and 5) the exchange fluxes between the various components of the groundwater-surface water system. The distribution of the aquifer systems was investigated by means of a) geo-electrical surveys, and b) in situ slug tests while their hydraulic connectivity was investigated by hydrogeochemical routing. The volumes of water abstracted by streamside vegetation were estimated by the quantification of the transpiration from individual plants and the groundwater recharge was estimated by a root zone water balance. The water exchange fluxes between the groundwater and surface water were determined from a simple riparian zone groundwater budget. The results of the geo-electrical surveys and slug tests allowed the delineation of the riparian area aquifers (RAA) and the terrestrial area aquifers (TAA) on both the south-eastern and north-western sides of the river. Based on the results of hydrochemical analyses, saturation indices and inverse mass balance modelling, the GSI involves flow of water from the TAA to the RAA, and finally to the river on the south-eastern side while it involves flow from the river into the RAA with a limited exchange with the TAA on the south-eastern side. The dominant vegetation on the study area was found to be the Acacia karroo and Diospyros lycioides. The close similarities in isotope compositions of the xylem sap and the borehole water samples suggested that the Acacia karroo sourced its water from the groundwater storage while differences in isotope compositions suggested that the Diospyros lycioides did not source water from the groundwater storage at the time of measurement. The results of groundwater recharge estimation in the study area highlighted the fact that both the antecedent moisture and the rainfall amounts determine whether recharge to the groundwater system will take place. Finally, the results of baseflow estimation indicated that the river is a gaining stream along the south-eastern reach while acting as a losing stream along the north-western reach.
Groundwater Monitoring: Typical Methods To Improve The Understanding Of Aquifer Potential And The Associated Vulnerabilities	Donovan Craig	Samuels	2019	Monitoring
Abstract In the wake of the ongoing water restrictions in South Africa, the issue of groundwater potential for drought relief has been debated on many environmental and socio-economic platforms, nationally. Consequently, the development of groundwater and its related vulnerabilities has become a key topic to the decision makers and stakeholders. Currently, the recruitment of water professionals into government and private water sectors adds substantial value to understanding the importance of protecting this precious resource. This has allowed the monitoring of groundwater to gain ever increasing momentum. Groundwater monitoring has become an essential scientific tool for role-players to achieve robust and verifiable data used for modelling aquifer potential and vulnerability to pollution and over-abstraction. The data is generally sourced from various hydrogeological and environmental investigations which include groundwater development, vulnerability assessment and remediation projects. Groundwater and environmental consulting firms are tasked with imperative roles for implementing groundwater monitoring programmes to the ever growing industrial, commercial, agricultural and public sectors in South Africa. However, groundwater monitoring data, especially in the private sector, are reliable but remains mostly inaccessible due to confidentiality clauses. This does limit our accuracy and comprehensive understanding for determining aquifer potential and vulnerability risks at large. The conceptualisation and modelling of vast monitoring datasets has been recognised as an important contributing factor to enhance groundwater sustainability. This research emphasises the significance of groundwater monitoring for development, protection and remediation of aquifers. Comparing monitoring results from typical sites and methods, provides scientific validation to support good governance of water. Deterioration of groundwater potability in the sight of an existing drought can have irreversible environmental and economic implications for South Africa.
Modelling recharge in an opencast coal mining environment, applying model parameters on a catchment scale.	Freek	van Devnter	2015
Abstract The provision, usage and discharge of water resources are major concerns for coal mines, both underground and opencast. Water resources in a coal mining environment will often account for a significant portion of the daily operational cost. In order to cut costs, the mine will often collect as much runoff as possible to recycle for future use. This on-going recycling of site water and management of the resource demands a complete site water balance model in order to understand the dynamics of the resource within the boundaries of the mine. To improve the understanding of the dynamics of the resource on a much larger scale, and the effect it will have on recharge in an open cast coal mine environment, one must consider alternative modelling approaches which can compensate for such conditions. This amounts to describing recharge as a modelling component in a physically based distributed model. The main goal of this project is to calculate recharge into the main pit at this specific colliery by applying parameters on a quaternary catchment scale. The colliery is located just west of the town of Ogies, Mpumalanga on the peripheral region of the quaternary catchment B20G. The physiography of the quaternary catchment B20F is described as a central Highveld region gently sloping to the north. The geohydrological modeling application MIKE SHE (developed by DHI) was used to develop a fully integrated catchment model. The model was created mainly to simulate the impact of human activities on the hydrological cycle and hence on water resource development and management. Different modules of MIKE SHE that was used during the modelling stage include saturated- and unsaturated flow and a small degree of overland flow. Key words: Mpumalanga, MIKE SHE, recharge
The use Vegetable Oil Substrate's in the treatment of contaminated groundwater	Michelle	Pienaar	2015
Abstract Edible vegetable oil (EVO) substrates have been successfully used to stimulate the in situ anaerobic biodegradation of groundwater contaminated chlorinated solvents as well as numerous other anaerobically biodegradable contaminants like nitrates and perchlorates at a many commercial, industrial and military sites throughout the United States of America and Europe. EVO substrates are classified as a slow release fluid substrate, and comprise of food grade vegetable oil such as canola or soya bean oil. The EVO substrate serves as an easily biodegradable source of carbon (energy) used to create a geochemically favorable environment for the anaerobic microbial communities to degrade specific contaminants of concern. EVO substrate's can either be introduced into the subsurface environment as pure oil, in the form of light non aqueous phase or as an oil/water emulsion. The emulsified vegetable oil substrates holds several benefits over non-emulsified vegetable oil as the fine oil droplet size of the commercially manufactured emulsified oils can more easily penetrate the heterogeneous pore and fracture spaces of the aquifer matrix. The use of this technology to stimulate in situ biodegradation of groundwater contaminants is still relatively unknown in South Africa. This paper will give an overview of the EVO technology and its application, specifically looking at the advantages of using this relatively inexpensive, innocuous substrate based technology to remediate contaminated groundwater within fractured rock environments commonly encountered in South Africa. {List only- not presented}
Performance Monitoring Of The Monitored Natural Attenuation Of Petroleum Hydrocarbons In Groundwater Using Geochemical Parameters	AR	Gemmell	2017	MNA, geochemical indicators, geochemical parameters, monitoring network
Abstract Monitored Natural Attenuation (MNA) refers to the monitoring of naturally occurring physical, chemical and biological processes. Three lines of evidence are commonly used to evaluate if MNA is occurring, and this paper focusses on the second line of evidence: The geochemical indicators of naturally occurring degradation processes and the site-specific estimation of attenuation rates. The MNA geochemical indicators include the microbial electron acceptors (e.g. dissolved oxygen, nitrate and sulphate) and the metabolic by-products (manganese (II), iron (II) and methane). In addition, redox and alkalinity are important groundwater indicators. So as to properly assess the geochemical trends a groundwater monitoring well network tailored to assessing and defining the contaminant plume is required. The expressed assimilative capacity (EAC) is used to estimate the capacity of the aquifer to degrade benzene, toluene, ethylbenzene and xylene (BTEX compounds) using the concentrations of geochemical indicators. Using the EAC, the groundwater flow through a perpendicular cross-section of the source area, and the source mass, the life of the contaminant source can be made. A practical example of the performance monitoring of MNA using geochemical parameters is described for a retail service station in KwaZulu-Natal, which has groundwater impacted by a petroleum hydrocarbon plume. This includes a description of the monitoring well network, the geochemical measurements, the calculation of the EAC, and the estimated life of the contaminant source.
Hydrocarbon plume delineation using a Hydrogeological and Geophysical approach	Albert	Kruger	2015
Abstract Simple and cost-effective techniques are needed for land managers to assess and quantify the environmental impacts of hydrocarbon contamination. During the case study, hydrocarbon plume delineation was carried out using hydrogeological and geophysical techniques at a retail filling station located in Gauteng. Laboratory and controlled spill experiments, using fresh hydrocarbon product, indicate that fresh hydrocarbons generally have a high electrical resistivity, whilst biodegraded hydrocarbons have a lower resistivity. This is attributed to the changes from electrically resistive to conductive behaviour with time due to biodegradation. As such, it should be possible to effectively delineate the subsurface hydrocarbon plume using two-dimensional (2D) Electrical Resistivity Tomography (ERT). As part of the case study, two traverses were conducted using an Electric Resistivity Tomography (ERT) survey with an ABEM SAS1000 Lund imaging system. The resultant 2D tomographs were interpreted based on the resistivity characteristics and subsurface material properties to delineate the plume. Localised resistivity highs were measured in both models and are representative of fresh hydrocarbons whereas areas of low resistivity represented areas of biodegraded hydrocarbons. More conventional plume delineation techniques in the form of intrusive soil vapour and groundwater vapour surveys as well as hydrochemical anlayses of the on-site monitoring wells were used to compare the results and to construct the detailed Conceptual Site Model. During the investigation, four existing monitoring wells located on the site and additional two wells were installed downgradient of the Underground Storage Tanks (USTs) in order to determine the extent of the plume. In conclusion, a comparison was found between the groundwater results and geophysical data obtained during the case study and it was concluded that ERT added a significant contribution to the Conceptual Site Model.
Investigating the impact of fertilizer spills on groundwater quality	Jacobus Wilhelmus	Haumann	2015
Abstract A groundwater assessment was conducted to identify and predict the contamination and transport properties of a groundwater system. The motivation for the study was the rising concern of a farm owner about the deteriorating water quality of the aquifer system. An investigation of the surface and groundwater quality indicated that two fertilizer dumpsites were the sources of pollution. Water analyses revealed elevated concentrations of Ca, Mg, K, F, NO3, SO4, Mn and NH4 within boreholes near the pollution sources. The NH4 and NO3 concentrations were exceptionally high: 11 941 mg/L and 12 689 mg/L, respectively. These high concentrations were the direct result of the dumping of fertilizer. The rise in these concentrations may also have been catalysed by the nitrogen cycle and the presence of the Nitrosomonas bacterium species. Due to the high solubility of NO3, and because soils are largely unable to retain anions, NO3 may enter groundwater with ease, and could migrate over large distances from the source. Elevated NO3 in groundwater is a concern for drinking water because it can interfere with blood-oxygen levels in infants and cause methemoglobinemia (blue-baby syndrome). A geophysical study was undertaken within the area of investigation to gain insight on the underlying geological structures. The survey indicated preferential flow paths within the aquifer system along which rapid transport of contaminant is likely to occur. Key words: aquifer system, groundwater quality analyses, fertilizer, nitrogen cycle, Nitrosomonas species, geophysics.
Water Monitoring in the Mining Industry: An Overview	Callie	Pickering	2015
Abstract Water monitoring is a key aspect in the mining industry, in terms of gathering baseline data during the pre-construction stage, identifying potential areas of concern and mitigating source pollutants during the operational stage. A proper water monitoring program assists in the monitoring of plume development and water level rebound during the closure phase. The data made available through consistent long term monitoring should not be underestimated. Monitoring the effect that coal mine operations have on the water quality and quantity of surface and groundwater resources is a complex and multidisciplinary task. Numerous methodologies exist for monitoring of this kind. This paper will supply an overview of the water- rock chemistry associated with coal mine environments and the key indicator elements that should be focused on for water monitoring as well a review of the Best Practice Guidelines requirements in terms of water monitoring. Two case studies of coal mines in KwaZulu Natal will be reviewed, the key challenges outlined and mitigation measures implemented. The impact of requirements such as those set out by the Department of Water and Sanitation in terms of strict water quality limits for water containment and waste facilities as specified by Water Use Licences has also created unrealistic non-compliance conditions. The initial approach to creating a water monitoring programme should involve first identifying gaps in previous datasets and delineating potential sources of contamination. The sampling frequency will depend primarily on the water resource being monitored and the water quality analysis will depend on the type of facility. The facilities required for a specific situation will depend on the type and amount of waste generated, potential for leachate formation, vulnerability of groundwater resources and potential for water usage or resource sensitivity.
Groundwater transport modelling: A fractional/fractal perspective	Amy	Allwright	2019	modelling
Abstract The complexity of real world systems inspire scientists to continually advance methods used to represent these systems as knowledge and technology advances. This fundamental principle has been applied to groundwater transport, a real world problem where the current understanding often cannot describe what is observed in nature. There are two main approaches to improve the simulation of groundwater transport in heterogeneous systems, namely 1) improve the physical characterisation of the heterogeneous system, or 2) improve the formulation of the governing equations used to simulate the system. The latter approach has been pursued by incorporating fractal and fractional derivatives into the governing equation formulation, as well as combining fractional and fractal derivatives. A fractal advection-dispersion equation, with numerical integration and approximation methods for solution, is explored to simulate anomalous transport in fractured aquifer systems. The fractal advection-dispersion equation has been proven to simulate superdiffusion and subdiffusion by varying the fractal dimension, without explicit characterisation of fractures or preferential pathways. A fractional-fractal advection-dispersion equation has also been developed to provide an efficient non-local modelling tool. The fractional-fractal model provides a flexible tool to model anomalous diffusion, where the fractional order controls the breakthrough curve peak, and the fractal dimension controls the position of the peak and tailing effect. These two controls potentially provide the tools to improve the representation of anomalous breakthrough curves that cannot be described by the classical-equation model. In conclusion, the use of fractional calculus and fractal geometry to achieve the collective mission of resolving the difference between modelled and observed is explored for the better understanding and management of fractured systems.
Groundwater fingerprinting for identifying potential project risks	Meris	Mills	2015
Abstract Implementation of a mining project in South Africa involved dewatering of a fractured rock aquifer at considerable depth below ground level. Groundwater quality within this aquifer is not suitable for domestic use due to high levels of salinity. Numerous geological investigations in the area indicate that the target aquifer is confined, with a different piezometric head to the shallower aquifers. However, regulators and other interested and affected parties expressed concern regarding the potential mixing of more saline groundwater from the deeper aquifer to be dewatered with groundwater from shallower aquifers, which are extensively used for farming and domestic purposes. A large database of groundwater quality monitoring data collected over 16 years was available to investigate the degree of mixing between the deeper more saline and shallower freshwater aquifers. The groundwater chemistry of selected boreholes with known geological profile, depth and construction was used to develop groundwater fingerprinting criteria for each of the aquifers in the area. These fingerprinting criteria were then applied to private and exploration boreholes in the area in order to identify the main aquifer from which groundwater was being sourced. Once the boreholes were classified in terms of groundwater origin, an attempt was made to identify indicators of mixing with deeper, more saline groundwater from the aquifer being dewatered. Groundwater fingerprinting allowed identification of impacts related to the mining operations. The data showed that there was no upward mixing of water related to dewatering operations, but rather that surface spillages and disposal schemes may have resulted in minor changes in shallow groundwater quality. {List only- not presented}
Remediation of Groundwater at AngloGold Ashanti South Africa	Gawie	van Dyk	2015
Abstract Gold Mining activities the past 60 years at AngloGold Ashanti polluted the groundwater underlain by 4000 ha of land at the Vaal River and West Wits operations in South Africa. Sulphide material in Tailings Storage Facilities, Waste Rock Dumps and extraction plants produce Saline Mine Drainage with Sulphate, minor salts and metals that seep to the groundwater and ultimately into surface water resources. Water regulation requires mines to prevent, minimise/ reduce or eliminate pollution of water resources. The waste philosophy has matured from tolerate and transfer to treat and termination of pollution sources. The impact of the pollution was determined and possible technologies to treat the impact were evaluated. Source controls of proper water management by storm water management, clean dirty water separation, lined water conveyance structures and reduced deposition of water on waste facilities is crucial. The aquifer character determines the possible remediation technology. From the possible technologies phytoremediation, physical interception and re-use of this water was selected. In future possible treatment of the water would be considered. This paper explain the strategy and report on the phased implementation of these plans and the expected results. The establishment of 750 ha of woodlands as phytoremediation, interception trenches of 1250 m, 38 interception boreholes and infrastructure to re-use this water in 10 water management areas is planned. The total volume of 15 Ml/day would be abstracted for re-use from the boreholes and trenches. The woodlands can potentially attenuate and treat 5 ml/day. The established woodlands of 150 ha proof successful to intercept diffused seep over the area of establishment and reduce the water level and base flow. The 2 implemented trenches of 1000 m indicate a local decline in the water level with interception of shallow groundwater within 1-2 m from surface. The 2 production interception well fields abstracting 50 and 30 l/s respectively indicate a water level decline of between 2 to 14 m with regional cones of depression of a few hundred meters to intercept groundwater flow up to 20 meter. Predictions from groundwater modelling indicate that these schemes can minimise pollution during the operational phase and protect downstream water resources. Predictions from modelling indicate that the pollution sources need to be removed to ensure long term clean-up to return the land to save use. The gold and uranium prize is securing the removal of the sources through re-processing of the tailings and waste rock dumps. After removal of the sources of pollution the remediation schemes would have to be operated for 20 years to return the groundwater to an acceptable standard of stock watering and industrial water use. The water quality is observed by a monitoring network of approximately 100 observation boreholes.